除虫菊素

密度：

1.12 g/cm3

沸点：

473.7ºC at 760 mmHg

闪点：

203.9ºC

折射率：

1.528

蒸汽压：

3.84E-09mmHg at 25°C

存储条件/存储方法：

密封保存。

稳定性相关：

1.对光、热、酸、碱均不稳定，易分解，在空气中也不稳定，加入抗氧化剂可缓解其氧化作用。

其它信息：

1.性状：浅黄色油状粘稠物。

2.溶解性：不溶于水，易溶于有机溶剂。

包装等级：

III

风险类别：

6.1(b)

危险类别码：

R20/21/22

安全标志：

S13:远离食品、饮料和动物饲料。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。

危险标志：

Xn: Harmful;N: Dangerous for the environment;

CHEMICAL IDENTIFICATION

RTECS NUMBER :

GZ0700000

CHEMICAL NAME :

Cyclopropaneacrylic acid, 3-carboxy-alpha,2,2-trimethyl-, 1-methyl ester, ester with 4- hydroxy-3-methyl-2-(2,4-pentadienyl)-2-cyclopenten-1- one

CAS REGISTRY NUMBER :

121-29-9

LAST UPDATED :

199701

DATA ITEMS CITED :

9

MOLECULAR FORMULA :

C22-H28-O5

MOLECULAR WEIGHT :

372.50

WISWESSER LINE NOTATION :

L5V BUTJ B2U2U1 C1 DOV- BL3TJ A1 A1 C1UY1&VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Unreported

SPECIES OBSERVED :

Human - man

DOSE/DURATION :

1029 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970 Volume(issue)/page/year: 2,73,1970

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

200 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

ARSIM* Agricultural Research Service, USDA Information Memorandum. (Beltsville, MD 20705) Volume(issue)/page/year: 20,17,1966

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intravenous

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

1 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Behavioral - tremor Behavioral - convulsions or effect on seizure threshold

REFERENCE :

PCBPBS Pesticide Biochemistry and Physiology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1971- Volume(issue)/page/year: 2,308,1972

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

130 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

ABCHA6 Agricultural and Biological Chemistry. (Maruzen Co. Ltd., POB 5050, Tokyo International, Tokyo 100-31, Japan) V.25- 1961- Volume(issue)/page/year: 37,2681,1973 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-FINLAND:TWA 5 mg/m3;STEL 10 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg/m3;STEL 10 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83467 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 17 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83467 No. of Facilities: 241 (estimated) No. of Industries: 6 No. of Occupations: 8 No. of Employees: 5966 (estimated) No. of Female Employees: 390 (estimated)

分子结构数据

1、   摩尔折射率：102.41

2、   摩尔体积（cm³/mol）：332.3

3、   等张比容（90.2K）：839.4

4、   表面张力（dyne/cm）：40.7

5、   介电常数（F/m）：

6、   偶极距（D）：

7、   极化率（10^-24cm³）：40.59

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  除虫菊素 II质谱(MS)