苯肼,盐酸盐

外观与性状：

白色至棕色结晶粉末

密度：

1.125g/cm3

熔点：

250-254 °C (dec.)(lit.)

沸点：

243ºC at 760 mmHg

闪点：

115.4ºC

水溶解性：

50 g/L (20 ºC)

存储条件/存储方法：

库房通风低温干燥,与食品原料分开储运

其它信息：

1.       性状：白色叶片状结晶。对光和湿敏感。能升华。

2.       密度（g/mL,25/4℃）： 未确定

3.       相对蒸汽密度（g/mL,空气=1）：未确定

4.       熔点（ºC）：243～246

5.       沸点（ºC,常压）：未确定

6.       沸点（ºC,5.2kPa）：未确定

7.       折射率：未确定

8.       闪点（ºC）：未确定

9.       比旋光度（º）：未确定

10.    自燃点或引燃温度（ºC）：未确定

11.    蒸气压（kPa,25ºC）：未确定

12.    饱和蒸气压（kPa,60ºC）：未确定

13.    燃烧热（KJ/mol）：未确定

14.    临界温度（ºC）：未确定

15.    临界压力（KPa）：未确定

16.    油水（辛醇/水）分配系数的对数值：未确定

17.    爆炸上限（%,V/V）：未确定

18.    爆炸下限（%,V/V）：未确定

19.    溶解性：易溶于水，溶于乙醇，几乎不溶于乙醚。加入浓盐酸则从溶液中析出沉淀。

包装等级：

III

风险类别：

6.1

海关代码：

29280090

WGK_Germany：

3
德国有关水污染物质的分类清单

危险类别码：

R23/24/25;R36/38;R43;R45;R48/23/24/25;R50;R68

安全说明：

S53-S45-S61

RTECS号：

MV9000000

安全标志：

S53:避免暴露——使用前先阅读专门的说明。
S45:出现意外或者感到不适，立刻到医生那里寻求帮助（最好带去产品容器标签）。
S61:避免排放到环境中。参考专门的说明/安全数据表。

危险标志：

T:Toxic

CHEMICAL IDENTIFICATION

RTECS NUMBER :

MV9000000

CHEMICAL NAME :

Hydrazine, phenyl-, hydrochloride

CAS REGISTRY NUMBER :

59-88-1

LAST UPDATED :

199710

DATA ITEMS CITED :

21

MOLECULAR FORMULA :

C6-H8-N2.Cl-H

MOLECULAR WEIGHT :

144.62

WISWESSER LINE NOTATION :

ZMR &GH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

161 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

2100 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

89 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intravenous

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

900 ug/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

25 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

500 mg/kg

TOXIC EFFECTS :

Lungs, Thorax, or Respiration - cyanosis Skin and Appendages - corrosive (after topical exposure) Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

25 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

8000 mg/kg/42W-I

TOXIC EFFECTS :

Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

464 mg/kg/8W-I

TOXIC EFFECTS :

Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :

TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

10 gm/kg/58W-C

TOXIC EFFECTS :

Tumorigenic - neoplastic by RTECS criteria Vascular - tumors Blood - lymphoma, including Hodgkin's disease

TYPE OF TEST :

TD - Toxic dose (other than lowest)

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

928 mg/kg/8W-I

TOXIC EFFECTS :

Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Intraperitoneal

DOSE :

30 mg/kg

SEX/DURATION :

female 17-19 day(s) after conception

TOXIC EFFECTS :

Reproductive - Effects on Newborn - behavioral

MUTATION DATA

TYPE OF TEST :

DNA repair

TEST SYSTEM :

Rodent - mouse Liver

REFERENCE :

JJCREP Japanese Journal of Cancer Research. (Elsevier Science Pub. BV, POB 211, 1000 AE Amsterdam, Netherlands) V.76- 1985- Volume(issue)/page/year: 79,204,1988 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO HYDRAZINES-air:CA CL 0.03 ppm/120M REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81928 No. of Facilities: 115 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 1708 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81928 No. of Facilities: 63 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 645 (estimated) No. of Female Employees: 445 (estimated)

分子结构数据

        1、   摩尔折射率：34.76

2、   摩尔体积（m³/mol）：96.0

3、   等张比容（90.2K）：255.4

4、   表面张力（dyne/cm）：49.9

5、   极化率（10^-24cm³）：13.78

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:3

3.氢键受体数量:2

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积38

7.重原子数量:9

8.表面电荷:0

9.复杂度:57.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

• 
  苯肼盐酸盐红外图谱(IR1)
• 
  苯肼盐酸盐红外图谱(IR2)
• 
  苯肼盐酸盐核磁图(¹³CNMR)
• 
  苯肼盐酸盐Raman光谱
• 
  苯肼盐酸盐核磁图(¹HNMR)