丁二酸钠(六水)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

丁二酸钠(六水) 基本信息

中文名称:
丁二酸钠(六水) 
中文别名:
丁二酸二钠;
丁二酸钠;
琥珀酸二钠盐;
干贝素;
琥珀酸钠 
英文名称:
Butanedioic acid,sodium salt (1:2)
英文别名:
sodium succinate (anhydrous);
sodium 2-{1-[4-(3,5-difluorophenyl)semicarbazono]ethyl}nicotinate;
SAN 835H;
succinic acid sodium salt;
Disodium succinate;
Diflufenzopyr;
sodium salt of 2-acetylnicotinic acid 4-(3,5-difluorophenyl)semicarbazone;
3-Pyridinecarboxylicacid,2-[1-[2-[[(3,5-difluorophenyl)amino]carbonyl]hydrazinylidene]ethyl];
diflufenzopyr-Na;
BAS654H;
succinic acid disodium salt;
Disodium Succinate;
Sodium succinate dibasic;
Sodium succinate dibasic,Succinic acid disodium salt;
Succinic acid,disodium salt;
3-Pyridinecarboxylicacid,2-[1-[[[(3,5-difluorophenyl)amino]carbonyl]hydrazono]ethyl]-(9CI);
Succinic acid disodium salt;
Sodium succinate;
sodium acetate-acetic acid;
sodium 21-succinate;
succinic acid disodim salt 
CAS No.:
150-90-3
分 子 式:
C4H6O4.2Na
分 子 量:
162.05
精确分子量:
161.99000
PSA:
80.26000
MDL:
MFCD00002790
EINECS:
205-778-7
BRN:
3917246
InChI:
InChI=1/C4H6O4.2Na/c5-3(6)1-2-4(7)8;;/h1-2H2,(H,5,6)(H,7,8);;/q;2*+1/p-2
危险品标志:
IrritantXi
风险术语:
R36/37/38;
安全术语:
S26;S36;S24/25;
分子结构式:
SDS:
查看

丁二酸钠(六水) 制备方法及用途

制备方法

将琥珀酸与氢氧化钠中和,经120℃干燥、粉碎即可。

合成制备方法

将琥珀酸与氢氧化钠中和,经120℃干燥、粉碎即可。

用途简介

调味剂;酸味剂;缓冲剂。主要用于火腿、香肠、水产品、调味液等,一般用量为0.01%~0.05%。作为调味品使用,一般用粉状的无水物,以加速溶解。

用途

琥珀酸二钠溶解性好,渗透性强,主要用作调味剂,在具有调味效果的同时还能缓和其他调味料的刺激,提高调味效果。我国规定可用于调味料,最大使用量为200g/kg。调味剂;酸味剂;缓冲剂。主要用于火腿、香肠、水产品、调味液等。一般用量为0.01%~0.05%。作为调味品使用,一般用粉状的无水物,以加速溶解。

丁二酸钠(六水) 物化性质

外观与性状:
白色结晶粉末
沸点:
236.1°C at 760 mmHg
闪点:
110.9ºC
水溶解性:
300 g/L (25 ºC)
蒸汽压:
0.0165mmHg at 25°C
存储条件/存储方法:

应密封保存。

稳定性相关:

无臭,无酸味。有特殊贝类鲜味。在空气中稳定。六水物至120℃时失去结晶水而为无水物。

其它信息:

1.      性状:结晶品为白色结晶颗粒;无水物为结晶性粉末。

2.      溶解性:易溶于水,不溶于乙醇。

丁二酸钠(六水) 安全信息

海关代码:
2917190090
WGK_Germany:
1
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S36-S24/25
RTECS号:
WM7751000
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
危险标志:
Xi

丁二酸钠(六水) 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WM7751000
CHEMICAL NAME :
Succinic acid, disodium salt
CAS REGISTRY NUMBER :
150-90-3
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C4-H4-O4.2Na
MOLECULAR WEIGHT :
162.06

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85KYAH "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989 Volume(issue)/page/year: 11,1368,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 80528 No. of Facilities: 68 (estimated) No. of Industries: 1 No. of Occupations: 6 No. of Employees: 2770 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 80528 No. of Facilities: 159 (estimated) No. of Industries: 2 No. of Occupations: 6 No. of Employees: 2247 (estimated) No. of Female Employees: 1382 (estimated)
毒理学数据:

1、急性毒性:小鼠静脉LD50:4500 mg/kg。

2、青蛙皮下注射MID:1.8~2.0g/kg。

生态数据:

其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

丁二酸钠(六水) MSDS

Name: Succinic acid disodiumsalt anhydrous 99% Material Safety Data Sheet
Synonym: Disodium succinate, anhydrou
CAS: 150-90-3
Section 1 - Chemical Product   MSDS Name:Succinic acid disodiumsalt anhydrous 99% Material Safety Data Sheet
Synonym:Disodium succinate, anhydrou

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
150-90-3 Succinic acid, disodium salt, anhydrou 99.0 205-778-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Low hazard for usual industrial handling.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Antidote: None reported.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 150-90-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: 300 G/L (25C)
Specific Gravity/Density:
Molecular Formula: C4H4O4Na2
Molecular Weight: 162.05

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 150-90-3: WM7751000 LD50/LC50:
Not available.
Carcinogenicity:
Succinic acid, disodium salt, anhydrous - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 150-90-3: 0
Canada
CAS# 150-90-3 is listed on Canada's DSL List.
CAS# 150-90-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 150-90-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

丁二酸钠(六水) 海关数据

中国海关编码:2917190090

概述:
2917190090 其他无环多元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 对苯二甲酸请注明4-CBA值, 对苯二甲酸请注明P-TL酸值, 对苯二甲酸请注明色度, 对苯二甲酸请注明水分
摘要/Summary:
2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

丁二酸钠(六水) 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积80.3

7.重原子数量:10

8.表面电荷:0

9.复杂度:81.6

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

丁二酸钠(六水) 上游产品

推荐供应商更多供应商>>

湖北诺纳科技有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:张经理 电话:027-59209883 手机:17386169806

湖北万得化工有限公司

产品介绍:
产品名称:丁二酸钠 Cas号:150-90-3 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北齐飞医药化工有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:朱梦蝶 电话:027-59322506 手机:18071128683

山东丰泰生物科技有限公司

产品介绍:
产品名称:干贝素 Cas号:150-90-3 纯度:99% 包装信息:1kg,25kg 价格:28.0元 - 30.0元
联系方式:
联系人:靳 电话:0531-82066716 手机:15662658391

湖北实顺生物科技有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张经理 电话:027-59223025 手机:15172526927

湖北信康医药化工有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北永阔科技有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:徐 电话:027-59223108 手机:15107166787

天门恒昌化工有限公司

产品介绍:
产品名称:丁二酸二钠 Cas号:150-90-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄经理 电话:027-59322316 手机:15827039378

河北利华生物科技有限公司

产品介绍:
产品名称:干贝素 Cas号:150-90-3 纯度:99% 包装信息:1kg,25kg,1000kg 价格:14.0元 - 18.0元
联系方式:
联系人:刘经理 电话:15127018080 手机:15127018080

湖北云镁科技有限公司

产品介绍:
产品名称:丁二酸钠 Cas号:150-90-3 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871