九水合草酸钇(III)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

九水合草酸钇(III) 基本信息

中文名称:
九水合草酸钇(III) 
中文别名:
九水合草酸钇(III);
草酸钇;
草酸钇(III)九水合物 
英文名称:
Yttrium, [m-[ethanedioato(2-)-O,O''':O',O'']]bis[ethanedioato(2-)-O,O']di-,nonahydrate (9CI)
英文别名:
oxalate,yttrium(3+),nonahydrate;
Yttrium(III)oxalatehydrate(99.9%-Y)(REO);
YTTRIUM(III) OXALATE NONAHYDRATE: (99.9% Y) (REO);
Yttrium(III) oxalate nonahydrate, 99.9% (REO);
YTTRIUM(III) OXALATE;
YTTRIUM(III) OXALATE NONAHYDRATE;
YTTRIUM OXALATE;
YTTRIUM OXALATE, HYDROUS;
YTTRIUM OXALATE NONAHYDRATE 
CAS No.:
13266-82-5
分 子 式:
C6O12Y2.9H2O
分 子 量:
604.00
精确分子量:
441.75100
PSA:
157.80000
MDL:
MFCD00150502
风险术语:
R36/37/38
安全术语:
S26;S36/37/39
分子结构式:
SDS:
查看

九水合草酸钇(III) 制备方法及用途

合成制备方法

将0.3g Y(NO3)3溶于200mL水中,加入2mL 6mol/L的硝酸,然后加入40mL溶有3g草酸甲酯的水溶液。充分混合后,回流3h,即析出草酸盐沉淀。室温放置过夜再进行过滤,依次用水、乙醇和乙醚洗涤,生成结晶在室温风干,得九水合物。

九水合草酸钇(III) 物化性质

沸点:
365.1ºC at 760 mmHg
闪点:
188.8ºC
蒸汽压:
2.51E-06mmHg at 25°C
存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料 水分/潮湿氧化物 酸。

水中溶解度为0.0001g。加热分解无熔点。

其它信息:

1.        性状:白色晶体。

2.        密度(g/mL,25℃):未确定

3.        相对蒸汽密度(g/mL,空气=1):未确定

4.        熔点(ºC):未确定

5.        沸点(ºC,常压):未确定

6.        沸点(ºC,4mmHg):未确定

7.        折射率:未确定

8.        闪点(ºC):未确定

9.        比旋光度(º):未确定

10.     自燃点或引燃温度(ºC):未确定

11.     蒸气压(20ºC):未确定

12.     饱和蒸气压(kPa,60ºC):未确定

13.     燃烧热(KJ/mol):未确定

14.     临界温度(ºC):未确定

15.     临界压力(KPa):未确定

16.     油水(辛醇/水)分配系数的对数值:未确定

17.     爆炸上限(%,V/V):未确定

18.     爆炸下限(%,V/V):未确定

19.     溶解性:未确定

九水合草酸钇(III) 安全信息

包装等级:
III
风险类别:
6.1
安全说明:
S26-S36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

九水合草酸钇(III) 毒理性

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

九水合草酸钇(III) MSDS


Section 1: Product Identification
   Chemical Name:       Yttrium (III) oxalate hydrate (99.9%-Y) (REO)    
   CAS Registry Number:       13266-82-5    
   Formula:       Y2(C2O4)3.xH2O    
   EINECS Number:       none    
   Chemical Family:       salt of an organic acid    
   Synonym:       Ethanedioic acid, yttrium salt; Oxalic acid, yttrium salt    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13266-82-5       100%       1mg/m3 (as Y)       1mg/m3 (as Y)    

Section 3: Hazards Identification
   Soluble oxalates are harmful if swallowed. They precipitate calcium from the bloodstream causing violent
   Emergency Overview:
   muscular stimulation, convulsions, collapse, and death.
   Primary Routes of Exposure:       Ingestion, Inhalation of dust.    
   Eye Contact:       May cause moderate to severe irritation of the eyes.    
   Skin Contact:       May cause moderate to severe irritation of the skin.    
   Inhalation:       Dust may be severely irritating to the nose, mucous membranes and respiratory tract.    
   Harmful if swallowed. Ingestion may cause vomiting, pain, violent muscular stimulation, convulsions, collapse
   Ingestion:
   and death.
   Soluble oxalates remove calcium from the bloodstream. This interferes with the central nervous system
   Acute Health Affects:
   causing violent convulsions and death.
   Prolonged exposure to oxalates can lead to kidney failure resulting from calcium oxalate precipitation in renal
   Chronic Health Affects:
   tubes
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Antidotes are said to be soluble calcium given orally, and calcium gluconate given intravenously, to be
   Ingestion:
   administered by trained medical personnel. Keep the victim calm. Give the victim water (only if conscious).

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes and carbon monoxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       441.87    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, concentrated sulfuric acid    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, soot, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

九水合草酸钇(III) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:441.750673 Da

8、标称质量:442 Da

9、平均质量:441.8687 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:9

3.氢键受体数量:21

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积250

7.重原子数量:29

8.表面电荷:0

9.复杂度:60.5

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:14

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