顺-双(2,2-二吡啶基)二氯化钌

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

顺-双(2,2-二吡啶基)二氯化钌 基本信息

中文名称:
顺-双(2,2-二吡啶基)二氯化钌 
中文别名:
顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物;
顺-双(2;
顺-双(2,2-二吡啶基)二氯化钌(II)二水合物;
顺-双(2,2'-二吡啶基)二氯化钌(II),二水合物;
顺式-二氯二(2,2'-二吡啶)合钌(II)二水合物;
顺-双(2,2'-二吡啶基)二氯化钌(II),二水 
英文名称:
cis-Bis-(2,2'-bipyridine)dichlororuthenium(II) dihydrate
英文别名:
cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate;
cis-Bis-(2,2′-bipyridine)dichlororuthenium(II) dihydrate;
cis-Bis-(2,2'-bipyridine)dichlororuthenium(II) dehydrate;
cis-Dichlorobis(2,2‘-bipyridine)ruthenium(II) dihydrate;
cis-Bis-(2,2'-bipyridine)dichlororuthenium(II) dihydrate 
CAS No.:
15746-57-3
分 子 式:

C20H16Cl2N4Ru

分 子 量:
520.38
精确分子量:
504.13600
PSA:
12.96000
MDL:
MFCD00012040
InChI:
The Key: MGAJEYXQYJBLQL-UHFFFAOYSA-L
危险品标志:

 

风险术语:

R36/37/38

安全术语:

S24/25

分子结构式:
SDS:
查看

顺-双(2,2-二吡啶基)二氯化钌 物化性质

熔点:
198-200℃
沸点:
254.8ºC at 760mmHg
闪点:
126.5ºC
存储条件/存储方法:

常温密闭避光,通风干燥

稳定性相关:

常温常压下稳定

避免的物料: 氧化物

其它信息:

1. 性状:未确定

2. 密度(g/mL,25/4℃<

顺-双(2,2-二吡啶基)二氯化钌 安全信息

安全说明:
S24/25

顺-双(2,2-二吡啶基)二氯化钌 毒理性

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

顺-双(2,2-二吡啶基)二氯化钌 MSDS

Name: cis-Dichlorobis(2 2 -bipyridine)ruthenium(II) dihydrate Material Safety Data Sheet
Synonym: None Known
CAS: 15746-57-3
Section 1 - Chemical Product   MSDS Name:cis-Dichlorobis(2 2 -bipyridine)ruthenium(II) dihydrate Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
15746-57-3 cis-Dichlorobis(2,2'-bipyridine)ruthen ca. 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 15746-57-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: black
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C20H16Cl2N4Ru.2H2O
Molecular Weight: 520.38

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not currently available.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 15746-57-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 15746-57-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 15746-57-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 15746-57-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

顺-双(2,2-二吡啶基)二氯化钌 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积4

7.重原子数量:27

8.表面电荷:-4

9.复杂度:301

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:4

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

推荐供应商更多供应商>>

湖北万得化工有限公司

产品介绍:
产品名称:顺-双(2 Cas号:15746-57-3 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北巨胜科技有限公司

产品介绍:
产品名称:顺-双(2 Cas号:15746-57-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:孙敏 电话:027-59599240 手机:18702754003

湖北信康医药化工有限公司

产品介绍:
产品名称:cis-二氯双(2,2''-二吡啶)钌二水合物 Cas号:15746-57-3 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北广奥生物科技有限公司

产品介绍:
产品名称:顺-双(2 Cas号:15746-57-3 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:孙经理 电话:027-59223056 手机:15271829679

湖北摆渡化学有限公司

产品介绍:
产品名称:顺式-二氯双(2,2'-联吡啶)钌二水合物 Cas号:15746-57-3 纯度:99% 包装信息:25kg 价格:1.0元
联系方式:
联系人:邹经理 电话:027-59223020 手机:18871490324

湖北鑫红利化工有限公司

产品介绍:
产品名称:顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 Cas号:15746-57-3 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:周女士 电话:027-59503710 手机:18871490254

上海吉至生化科技有限公司

产品介绍:
产品名称:顺-双(2,2'-二吡啶基)二氯化钌(II),二水合物 Cas号:15746-57-3 纯度:98% 包装信息:1gea,200mgea 价格:238.0元 - 798.0元
联系方式:
联系人:江珊 电话:021-57520831 手机:15316869680

上海源叶生物科技有限公司

产品介绍:
产品名称:顺-双(2,2-二吡啶基)二氯化钌(II)二水合物 Cas号:15746-57-3 纯度:99% 包装信息:1g 价格:990.0元
联系方式:
联系人:Yuki 电话:021-61845781 手机:13585604150

湖北军瑞生物科技有限公司

产品介绍:
产品名称:顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 Cas号:15746-57-3 纯度:99% 包装信息:1铝箔袋/氟化瓶kg,10铝听/纸箱kg,25纸板桶/编织袋/塑料桶kg,200镀锌铁桶/塑料桶kg 价格:1.0元 - 25.0元
联系方式:
联系人:向 电话:13971166412 手机:13971166412

山东默派生物科技有限公司

产品介绍:
产品名称:顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 Cas号:15746-57-3 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:张经理 电话:13070690626 手机:13070690626