三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 基本信息

中文名称:
三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 
中文别名:
三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕;
三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕(III)水合物;
三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕(III) 
英文名称:
Europium thenoyltrifluoroacetonate
英文别名:
TRIS(4,4,4-TRIFLUORO-1-(2-THIENYL)-1,3-BUTANEDIONO)EUROPIUM (III);
europium(III) thenyltrifluoroacetonate;
Tris(2-thenoyltrifluoroacetonate)europium;
Europium trifluorothenoylacetonate;
Tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium(III) hydrate;
Europiumtris(thenoyltrifluoroacetonate);
Europium thenoyltrifluoroacetonate;
EUROPIUM III THENOYLTRIFLUOROACETONATE;
Europium tris(thienoyltrifluoroacetonate) 
CAS No.:
14054-87-6
分 子 式:

C24H18EuF9O6S3

分 子 量:
821.54
精确分子量:
821.93300
PSA:
173.10000
MDL:
MFCD00041948
EINECS:
237-892-8
危险品标志:

 

风险术语:

R36/37/38

安全术语:

S22;S26;S36/37/39

分子结构式:
SDS:
查看

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 物化性质

熔点:
134-140ºC
沸点:
247.4ºC at 760 mmHg
闪点:
103.4ºC
蒸汽压:
0.0136mmHg at 25°C
存储条件/存储方法:

常温密闭避光,通风干燥

稳定性相关:

常温常压下稳定

避免的物料:氧化物

其它信息:

1.       性状:浅黄色粉末

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):134-140

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 安全信息

危险类别码:
36/37/38
安全说明:
22-26-36/37/39
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;     

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 MSDS

Name: Europium (III) Thenoyltrifluoroacetonate Trihydrate Material Safety Data Sheet
Synonym: None
CAS: 14054-87-6
Section 1 - Chemical Product   MSDS Name:Europium (III) Thenoyltrifluoroacetonate Trihydrate Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
14054-87-6 Europium,tris4,4,4-trifluoro-1-(2-thie 100 237-892-8
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14054-87-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: yellow
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C24H12EuF9O6S3.3H2O
Molecular Weight: 869.54

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 14054-87-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Europium,tris4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedioato- - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14054-87-6: No information available.
Canada
CAS# 14054-87-6 is listed on Canada's DSL List.
CAS# 14054-87-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14054-87-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

三(4,4,4-三氟-1-(2-噻吩)-1,3-丁二酮)铕 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:821.933377 Da

8、标称质量:822 Da

9、平均质量:821.5407 Da

计算化学数据

1、   氢键供体数量:0

2、   氢键受体数量:15

3、   可旋转化学键数量:9

4、   互变异构体数量:10

5、   拓扑分子极性表面积(TPSA):102

6、   重原子数量:43

7、   表面电荷:0

8、   复杂度:250

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:4

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