3-甲基-4-异丙氧基苯胺

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品

3-甲基-4-异丙氧基苯胺 基本信息

中文名称:
3-甲基-4-异丙氧基苯胺 
中文别名:
4-异丙基-3-甲基苯胺盐酸盐;
4-异丙基-3-甲基苯胺.盐酸盐 
英文名称:
Benzenamine,3-methyl-4-(1-methylethyl)-, hydrochloride (1:1)
英文别名:
4-Isopropyl-3-Methylaniline Hydrochloride;
3-methyl-4-propan-2-ylaniline,hydrochloride;
3-Methyl-4-isopropylaniline hydrochloride;
4-Isopropyl-3-methylaniline hydrochloride 
CAS No.:
4534-11-6
分 子 式:
C10H15N.ClH
分 子 量:
185.70
精确分子量:
185.09700
PSA:
26.02000
MDL:
MFCD00156562
EINECS:
224-876-0
InChI:
The Key: VPOAQDSAPBSOLW-UHFFFAOYSA-N
危险品标志:
IrritantXi
风险术语:
R20/21/22;R36/37/38;
安全术语:
S26;S36/37/39;
分子结构式:
SDS:
查看

3-甲基-4-异丙氧基苯胺 制备方法及用途

制备方法

常温,避光,通风干燥处,密封保存

合成制备方法

 常温,避光,通风干燥处,密封保存

用途简介

3-甲基-4-异丙氧基苯胺 物化性质

熔点:
223ºC
沸点:
247ºC at 760mmHg
闪点:
106ºC
折射率:
1.538
存储条件/存储方法:

常温常压下稳定

其它信息:

1.       性状:固体

2.       密度(g/mL,25 °C):不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):222-225

5.       沸点(ºC,常压):不确定

6.       沸点(ºC,50mmHg):不确定

7.       折射率:不确定

8.       闪点(ºF):不确定

9.       比旋光度(ºC=1, Toluene):不确定

10.    自燃点或引燃温度(ºC):不确定

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:不确定

3-甲基-4-异丙氧基苯胺 安全信息

海关代码:
2921430090
危险类别码:
R20/21/22
安全说明:
S36/37
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xn:Harmful;

3-甲基-4-异丙氧基苯胺 毒理性

毒理学数据:

主要的刺激性影响

在皮肤上面:刺激皮肤和粘膜

   在眼睛上面:刺激的影响

   致敏作用:没有已知的敏化影响

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

3-甲基-4-异丙氧基苯胺 MSDS

Name: 4-Isopropyl-3-methylaniline hydrochloride Material Safety Data Sheet
Synonym:
CAS: 4534-11-6
Section 1 - Chemical Product   MSDS Name:4-Isopropyl-3-methylaniline hydrochloride Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
4534-11-6 4-Isopropyl-3-methylaniline hydrochlor 224-876-0
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4534-11-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: grey
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H16ClN
Molecular Weight: 186

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 4534-11-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Isopropyl-3-methylaniline hydrochloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 4534-11-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4534-11-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4534-11-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3-甲基-4-异丙氧基苯胺 海关数据

中国海关编码:2921430090

概述:
2921430090 甲苯胺及其衍生物以及它们的盐. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 原产地证据文件及编号(例 附原产地证书, 原产于欧盟的
摘要/Summary:
HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

3-甲基-4-异丙氧基苯胺 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:49.49

2、   摩尔体积(m3/mol):158.0

3、   等张比容(90.2K):385.7

4、   表面张力(dyne/cm):35.4

5、   极化率10-24cm3):19.62

计算化学数据

1、   氢键供体数量:2

2、   氢键受体数量:1

3、   可旋转化学键数量:1

4、   拓扑分子极性表面积(TPSA):26

5、   重原子数量:12

6、   表面电荷:0

7、   复杂度:120

8、   同位素原子数量:0

9、   确定原子立构中心数量:0

10、   不确定原子立构中心数量:0

11、   确定化学键立构中心数量:0

12、   不确定化学键立构中心数量:0

13、   共价键单元数量:2

3-甲基-4-异丙氧基苯胺 上游产品

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阿法埃莎(天津)化学有限公司

产品介绍:
产品名称:4-异丙基-3-甲基苯胺.盐酸盐 Cas号:4534-11-6 纯度: 包装信息:洽谈 价格:洽谈
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