正-十碳醇

外观与性状：

琥珀色液体

密度：

0.829 g/mL at 25 °C(lit.)

熔点：

5-7 °C(lit.)

沸点：

231 °C(lit.)

闪点：

180 °F

水溶解性：

insoluble

折射率：

n20/D 1.437(lit.)

蒸汽密度：

4.5 (vs air)

存储条件/存储方法：

库房通风低温干燥

稳定性相关：

1.避免与强氧化物接触。对金属无腐蚀性，具高级伯醇的化学反应性。

2.几乎无毒。大白鼠经口LD506400~12800mg/kg,小鼠12800~25600mg/kg。小鼠腹腔注射LD508800~1600mg/kg。

3. 存在于烤烟烟叶中。

4. 天然存在于甜橙油等精油里。
　

其它信息：

1.      性状：无色或浅黄色黏稠液体，略有玫瑰和橙花气味，并有油脂和蜡般气息。

2.      相对密度（g/mL,20/4℃）：0.8297

3.      相对蒸汽密度（g/mL,空气=1）：5.3

4.      凝固点（ºC）：6.9

5.      沸点（ºC,常压）：232.9

6.      折射率（n20ºC）：1.4371

7.      闪点（ºC,开口）：82

8.   蒸气压（mmHg,70ºC）：1

9.   饱和蒸气压（kPa, 69.5ºC）：0.13

10.   燃烧热（KJ/g）：41.7

11.   比热容（KJ/(kg·K),20~30ºC,定压）：2.24

12.   体膨胀系数（K^-1）：0.00086

13.   溶解性：能与醇、醚、丙酮、苯、冰乙酸、环己烷、四氯化碳等混溶。20℃时在水中溶解0.02%；水在癸醇中溶解3%。

14.  相对密度（25℃，4℃）：0.8263

15.  常温折射率（n²⁵）：1.4353

16.   临界温度（ºC）：405.15

17.   临界压力（MPa）：2.315

18.   临界密度（g·cm^-3）：0.244

19.   临界体积（cm³·mol^-1）：649

20.   临界压缩因子：0.263

21.   偏心因子：0.613

22.   溶度参数(J·cm^-3)^0.5：20.012

23.   van der Waals面积（cm²·mol^-1）：1.573×10¹⁰

24.   van der Waals体积（cm³·mol^-1）：113.780

25.   气相标准燃烧热(焓)(kJ·mol^-1)：6681.97

26.   气相标准声称热(焓)( kJ·mol^-1) ：-397.23

27.   液相标准燃烧热(焓)(kJ·mol^-1)：-6600.47

28.   液相标准声称热(焓)( kJ·mol^-1)：-478.73

29.   液相标准热熔(J·mol^-1·K^-1)：419.1

包装等级：

III

风险类别：

9

海关代码：

29051900

WGK_Germany：

1
德国有关水污染物质的分类清单

危险类别码：

R20;R36/38;R51/53

安全说明：

S26-S60-S61-S37/39-S29

RTECS号：

HE4375000

安全标志：

S26:万一接触眼睛，立即使用大量清水冲洗并送医诊治。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。
S29:不要将残余物倾入排水口。
S36:穿戴合适的防护服装。
:

危险标志：

Xn:Harmful;N:Dangerousfortheenvironment;

CHEMICAL IDENTIFICATION

RTECS NUMBER :

HE4375000

CHEMICAL NAME :

Decyl alcohol

CAS REGISTRY NUMBER :

112-30-1

BEILSTEIN REFERENCE NO. :

1735221

LAST UPDATED :

199803

DATA ITEMS CITED :

23

MOLECULAR FORMULA :

C10-H22-O

MOLECULAR WEIGHT :

158.32

WISWESSER LINE NOTATION :

Q10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Human

REFERENCE :

85DKA8 "Cutaneous Toxicity, Proceedings of the 3rd Conference, 1976," Drill, V.A., and P. Lazar, eds., New York, Academic Press, Inc. 1977 Volume(issue)/page/year: -,127,1977

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 34,493,1973

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,202,1986

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 34,493,1973

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration into the eye

SPECIES OBSERVED :

Rodent - rabbit

REFERENCE :

85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,202,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

4720 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea

REFERENCE :

AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 34,493,1973

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

800 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4631,1982

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

6500 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C267,1991

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

4 gm/m3/2H

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,42,1982

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

800 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985. Volume(issue)/page/year: 2C,4631,1982

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

3560 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 11,95,1973

TYPE OF TEST :

LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Mammal - species unspecified

DOSE/DURATION :

3 gm/m3

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(5),61,1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :

TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :

Inhalation

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

200 mg/m3/2H/30D-I

TOXIC EFFECTS :

Sense Organs and Special Senses (Eye) - conjunctive irritation Sense Organs and Special Senses (Eye) - effect, not otherwise specified Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase

REFERENCE :

NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB234-882 ** TUMORIGENIC DATA **

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

12 gm/kg/25W-I

TOXIC EFFECTS :

Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors Tumorigenic - tumors at site of application

REFERENCE :

TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 9,70,1966 ** REPRODUCTIVE DATA **

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

DOSE :

35295 mg/kg

SEX/DURATION :

female 1-15 day(s) after conception

TOXIC EFFECTS :

Reproductive - Fertility - female fertility index (e.g. # females pregnant per # sperm positive females; # females pregnant per # females mated) Reproductive - Fertility - pre-implantation mortality (e.g. reduction in number of implants per female; total number of implants per corpora lutea) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

REFERENCE :

ONGZAC Ontogenez (Moscow). For English translation, see SJDBA9. (V/O Mezhdunarodnaya Kniga, 113095, Moscow, USSR) V.1- 1970- Volume(issue)/page/year: 22(1),71,1991

TYPE OF TEST :

TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :

Oral

DOSE :

35295 mg/kg

SEX/DURATION :

female 1-15 day(s) after conception

TOXIC EFFECTS :

Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Newborn - biochemical and metabolic

REFERENCE :

ONGZAC Ontogenez (Moscow). For English translation, see SJDBA9. (V/O Mezhdunarodnaya Kniga, 113095, Moscow, USSR) V.1- 1970- Volume(issue)/page/year: 22(1),71,1991 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 10 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83553 No. of Facilities: 219 (estimated) No. of Industries: 11 No. of Occupations: 26 No. of Employees: 5355 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83553 No. of Facilities: 6909 (estimated) No. of Industries: 116 No. of Occupations: 84 No. of Employees: 241397 (estimated) No. of Female Employees: 62584 (estimated)

毒理学数据：

1、急性毒性：小鼠经口Lc50：6400～12800 mg/kg；大鼠经口LD50：12800～25600 mg/kg小鼠吸入LC50：4000mg/m3，2小时。

2、刺激数据：皮肤- 兔子 20 毫克/ 24小时  中度; 眼睛 -兔子 83 毫克 重度。

3、属微毒类，对眼黏膜和皮肤有刺激作用。

生态数据：

对水体有轻微的危害。

分子结构数据

1、   摩尔折射率：49.91

2、   摩尔体积（cm³/mol）：191.1

3、   等张比容（90.2K）：446.7

4、   表面张力（dyne/cm）：29.8

5、   极化率（10^-24cm³）：19.78

计算化学数据

1.疏水参数计算参考值（XlogP）:无

2.氢键供体数量:1

3.氢键受体数量:1

4.可旋转化学键数量:8

5.互变异构体数量:无

6.拓扑分子极性表面积20.2

7.重原子数量:11

8.表面电荷:0

9.复杂度:61.9

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

• 
  正癸醇红外图谱(IR1)
• 
  正癸醇质谱(MS)
• 
  正癸醇核磁图(¹³CNMR)
• 
  正癸醇Raman光谱
• 
  正癸醇核磁图(¹HNMR)