4,4-二甲基-2-戊炔

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

4,4-二甲基-2-戊炔 基本信息

中文名称:
4,4-二甲基-2-戊炔 
中文别名:
4,4-二甲基-2-戊炔;
4,4-二甲基-2-戊炔,97+% 
英文名称:
2-Pentyne,4,4-dimethyl-
英文别名:
4,4-dimethylpent-2-yne;
4,4-Dimethyl-2-pentyne;
1-tert-butyl-2-methylacetylene;
TERT-BUTYLMETHYLACETYLENE;
2-Pentyne,4,4-dimethyl;
2,2-dimethyl-3-pentyne;
methyl-t-Bu-acetylene;
4,4-dimethyl-pent-2-yne;
4,4-dimethyl-1-pentyne 
CAS No.:
999-78-0
分 子 式:
C7H12
分 子 量:
96.17
精确分子量:
96.09390
PSA:
0.00000
MDL:
MFCD00041613
EINECS:
000-000-0
BRN:
1733540
风险术语:
R11; R65;
安全术语:
S16; S23; S33;
SDS:
查看

4,4-二甲基-2-戊炔 物化性质

密度:
0.718
熔点:
-82.4ºC
沸点:
83ºC
折射率:
1.4071
存储条件/存储方法:

保持容器密封,储存在阴凉,干燥的地方 

稳定性相关:

常温常压下稳定,避免强氧化剂接触

其它信息:

1.       性状:未确定

2.       密度(g/cm3,25):0.718

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):83

6.       沸点(ºC,40mm):未确定

7.       折射率:1.4071

8.       闪点(ºC):-10

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

4,4-二甲基-2-戊炔 安全信息

包装等级:
II
风险类别:
3
海关代码:
2901299090
危险类别码:
R11;R65
安全说明:
S16-S23-S33-S62
安全标志:
S9:保持容器在一个有良好通风放的场所。
S16:远离火源。
S33:采取防护措施防止静电发生。

4,4-二甲基-2-戊炔 毒理性

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

4,4-二甲基-2-戊炔 MSDS


Section 1: Product Identification
   Chemical Name:       t-Butylmethylacetylene, min. 98%    
   CAS Registry Number:       999-78-0    
   Formula:       C4H9C=C(CH3)    
   EINECS Number:       none    
   Chemical Family:       organic compound    
   Synonym:       4,4-Dimethyl-pent-2-yne    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       999-78-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, skin, eyes    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       May be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract. May be harmful if swallowed.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       14°F    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Highly flammable liquid. Formation of explosive air/vapor mixtures is possible.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a cool, dry, well ventilated place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       Colorless liquid    
   Molecular Weight:       96.17    
   Melting Point:       no data    
   Boiling Point:       83°C    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       No hazardous polymerization    
   Conditions to Avoid:       contact with ignition sources including open flame and electrostatic discharge.    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide and organic fumes    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquid, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1993    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

4,4-二甲基-2-戊炔 海关数据

中国海关编码:2901299090

概述:
2901299090 其他不饱和无环烃。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:2.0%。普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 用作气体燃料的应报明包装容器容积, 散装货物应报明
摘要/Summary:
2901299090 unsaturated acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

4,4-二甲基-2-戊炔 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:32.44

2、   摩尔体积(m3/mol):127.4

3、   等张比容(90.2K):283.4

4、   表面张力(dyne/cm):24.6

5、   介电常数(F/m):2.18

6、   极化率10-24cm3):12.86

计算化学数据

1.疏水参数计算参考值(XlogP):2.7

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:7

8.表面电荷:0

9.复杂度:101

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:4,4-二甲基-2-戊炔 Cas号:999-78-0 纯度: 包装信息:洽谈 价格:洽谈
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产品介绍:
产品名称:4,4-二甲基-2-戊炔 Cas号:999-78-0 纯度: 包装信息:洽谈 价格:洽谈
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