4’-苯氧基苯乙酮

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

4’-苯氧基苯乙酮 基本信息

中文名称:
4’-苯氧基苯乙酮 
中文别名:
4'-苯氧基苯乙酮;
4’-苯氧基苯乙酮;
1-(4-苯氧基苯基)乙酮;
4-乙酰基二苯醚;
对苯氧基苯乙酮 
英文名称:
Ethanone,1-(4-phenoxyphenyl)-
英文别名:
4'-Phenoxyacetophenone;
1-(4-Phenoxyphenyl)ethanone;
4-Acetyldiphenyl Ether;
1-(4-phenoxyphenyl)ethanone;
4′-Phenoxyacetophenone;
4‘-Phenoxyacetophenone 
CAS No.:
5031-78-7
分 子 式:
C14H12O2
分 子 量:
212.24
精确分子量:
212.08400
PSA:
26.30000
MDL:
MFCD00008744
BRN:
2049295
InChI:
InChI=1/C14H12O2/c1-11(15)12-7-9-14(10-8-12)16-13-5-3-2-4-6-13/h2-10H,1H3
危险品标志:
风险术语:
R36/37/38   
安全术语:
S26;S37/39
分子结构式:
SDS:
查看

4’-苯氧基苯乙酮 物化性质

外观与性状:
淡黄色粉末
密度:
1.108g/cm3
熔点:
50-52 °C(lit.)
沸点:
200 °C12 mm Hg(lit.)
闪点:
>230 °F
水溶解性:
insoluble
折射率:
1.568
存储条件/存储方法:

 常温,避光,阴凉干燥处,密封保存

稳定性相关:

常温常压下稳定

其它信息:

1.       性状:白色固体

2.       密度:不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):50

5.       沸点(ºC):325

6.       沸点(ºC,10mmHg):不确定

7.       折射率(nD20):不确定

8.       闪点(ºC):>110

9.       比旋光度(º, C=0.4):不确定

10.    燃点(ºC): >110

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:不确定

4’-苯氧基苯乙酮 安全信息

海关代码:
2914509090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi:Irritant;

4’-苯氧基苯乙酮 毒理性

毒理学数据:

主要的刺激性影响

在皮肤上面:刺激皮肤和粘膜

   在眼睛上面:刺激的影响

   致敏作用:没有已知的敏化影响

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

4’-苯氧基苯乙酮 MSDS

Name: 4 -Phenoxyacetophenone 98% Material Safety Data Sheet
Synonym: None Known
CAS: 5031-78-7
Section 1 - Chemical Product   MSDS Name:4 -Phenoxyacetophenone 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5031-78-7 4'-Phenoxyacetophenone 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Dusts may be combustible when exposed to heat, flame, or oxidizing agents.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5031-78-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 200 deg C @ 12.00mmHg
Freezing/Melting Point: 52 - 54 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C14H12O2
Molecular Weight: 212.0828

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 5031-78-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4'-Phenoxyacetophenone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5031-78-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5031-78-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5031-78-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4’-苯氧基苯乙酮 海关数据

中国海关编码:2914509090

概述:
2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 丙酮报明包装
摘要/Summary:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

4’-苯氧基苯乙酮 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:62.72

2、   摩尔体积(m3/mol):191.5

3、   等张比容(90.2K):483.5

4、   表面张力(dyne/cm):40.6

5、   极化率10-24cm3):24.86

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:3

5.互变异构体数量:2

6.拓扑分子极性表面积26.3

7.重原子数量:16

8.表面电荷:0

9.复杂度:223

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

湖北万得化工有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北信康医药化工有限公司

产品介绍:
产品名称:4&#39-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北广奥生物科技有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:孙经理 电话:027-59223056 手机:15271829679

武汉卡诺斯科技有限公司

产品介绍:
产品名称:对苯氧基苯乙酮 Cas号:5031-78-7 纯度:99%以上 包装信息:50kg,25kg,15kg,5kg,1kg 价格:46.0元 - 154.0元
联系方式:
联系人:尚文 电话:153-37111468 手机:15337111468

湖北鑫红利化工有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:周女士 电话:027-59503710 手机:18871490254

宝鸡市国康海思化学技术有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:98 包装信息:1kg 价格:洽谈
联系方式:
联系人:杨经理 电话:0917-3909592 手机:13892490616

湖北摆渡化学有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:25kg 价格:1.0元
联系方式:
联系人:邹经理 电话:027-59223020 手机:18871490324

山东西亚化学有限公司

产品介绍:
产品名称:4-苯氧基苯乙酮 Cas号:5031-78-7 纯度:98% 包装信息:100g 价格:1,946.0元
联系方式:
联系人:崔 电话:4009903999 手机:18053972095

湖北齐飞医药化工有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:10kg 价格:洽谈
联系方式:
联系人:朱梦蝶 电话:027-59322506 手机:18071128683

湖北江民泰华化工有限公司

产品介绍:
产品名称:4'-苯氧基苯乙酮 Cas号:5031-78-7 纯度:99% 包装信息:200kg,25kg 价格:洽谈
联系方式:
联系人:张经理 电话:13396038321 手机:13396038321