高氯酸铕

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

高氯酸铕 基本信息

中文名称:
高氯酸铕 
中文别名:
高氯酸铕;
高氯酸铕溶液 
英文名称:
Perchloric acid, europium(3+) salt (8CI,9CI)
英文别名:
EUROPIUM PERCHLORATE;
EUROPIUM PERCHLORATE,HYDRATED SOLUTION,REAGENT 
CAS No.:
13537-22-9
分 子 式:
ClHO4.1/3Eu
分 子 量:
450.32
精确分子量:
449.76700
PSA:
222.81000
MDL:
MFCD00016076
EINECS:
236-907-5
风险术语:
R8R34
安全术语:
S17S26S45S36/S37/S39
分子结构式:
SDS:
查看

高氯酸铕 物化性质

密度:
1.487 g/mL at 25 °C
其它信息:

1.性状:不可用

2.密度(g/mL,25/4): 1.487

3.相对蒸汽密度(g/mL,空气=1)不可用

4.熔点(ºC):不可用

5.沸点(ºC,常压):不可用

6.沸点(ºC,5.2kPa): 不可用

7.折射率: 不可用

8.闪点(ºC): 不可用

9.比旋光度(º): 不可用

10.自燃点或引燃温度(ºC): 不可用

11.蒸气压(kPa,25ºC): 不可用

12.饱和蒸气压(kPa,60ºC): 不可用

13.燃烧热(KJ/mol):不可用

14.临界温度(ºC): 不可用

15.临界压力(KPa): 不可用

16.油水(辛醇/水)分配系数的对数值:不可用 

17.爆炸上限(%,V/V):不可用

18.爆炸下限(%,V/V): 不可用

19.溶解性:不可用

高氯酸铕 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
R8
安全说明:
17-26-36/37/39-45
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
O: Oxidizing agent;C: Corrosive;

高氯酸铕 毒理性

毒理学数据:

急性毒性:不可用 。

生态数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

高氯酸铕 MSDS

    Version 1.2
    Regulation (EC) No 1907/2006

    1 - Product and Company Information

    Product Name        EUROPIUM(III) PERCHLORATE, 99.9%, 50    
    WT. % SOLUTION IN WATER

    2 - Hazards Identification

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Contact with combustible material may cause fire. Causes burns.

    3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I    
    Index Number
    EUROPIUM(III) PERCHLORATE, 99.9%, 13537-22-9 236-907-5 None
    40 WT. %SOLUTION IN WATER
    Formula        Eu(ClO4)3    
    Molecular Weight 450,3100 AMU

    4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER EYE CONTACT
    Assure adequate flushing of the eyes by separating the eyelids
    with fingers.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

    5 - Fire Fighting Measures

    CONDITIONS OF FLAMMABILITY
    May accelerate combustion.
    EXTINGUISHING MEDIA
    ALDRICH        www.molbase.com    
    Suitable: Water spray.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions. May
    accelerate combustion. Contact with other material may cause
    fire.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

    6 - Accidental Release Measures

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Cover with dry lime or soda ash, pick up, keep in a closed
    container, and hold for waste disposal. Ventilate area and wash
    spill site after material pickup is complete.

    7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe dust. Do not get in
    eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Store in a cool dry
    place.
    Unsuitable: Do not store near, nor allow contact with, clothing
    and other combustible material.

    8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Use only in a chemical fume hood. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Special Protective Measures: Wear appropriate government approved
    respirator, chemical-resistant gloves, safety goggles, other
    protective clothing. Faceshield (8-inch minimum).

    9 - Physical and Chemical Properties

    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        N/A    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    ALDRICH        www.molbase.com    
    Explosion Limits        N/A    
    Vapor Pressure        6,204000000 mmHg 20,00 °C    
    SG/Density        1,4870 g/cm3    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

    10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Materials to Avoid: Organic materials, Finely powdered metals,
    Strong reducing agents.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Chlorine.

    11 - Toxicological Information

    SIGNS AND SYMPTOMS OF EXPOSURE
    To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.
    Symptoms of exposure may include burning sensation, coughing,
    wheezing, laryngitis, shortness of breath, headache, nausea, and
    vomiting. Inhalation may result in spasm, inflammation and edema
    of the larynxand bronchi, chemical pneumonitis, and pulmonary
    edema. Material is extremely destructive to tissue of the mucous
    membranes and upper respiratory tract, eyes, and skin. Rare
    earth compounds may cause delayed blood clotting leading to
    hemorrhages. Inhalation of rare earths may cause sensitivity to
    heat, itching, and increased awareness of odor and taste.
    ROUTE OF EXPOSURE
    Multiple Routes: Harmful if swallowed, inhaled, or absorbed
    through skin.

    12 - Ecological Information

    No data available.

    13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Contact a licensed professional waste disposal service to dispose
    of this material. Observe all federal, state, and local
    environmental regulations.

    14 - Transport Information

    RID/ADR
    ALDRICH        www.molbase.com    
    UN#: 3098
    Class: 5.1
    PG: II
    Subrisk: 8
    Proper Shipping Name: Oxidizing liquid, corrosive,
    n.o.s.
    IMDG
    UN#: 3098
    Class: 5.1
    PG: II
    Subrisk: 8
    Proper Shipping Name: OXIDIZING LIQUID, CORROSIVE,
    N.O.S.
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3098
    Class: 5.1
    PG: II
    Subrisk: 8
    Proper Shipping Name: Oxidizing liquid, corrosive,
    n.o.s.
    Inhalation Packing Group I: No
    Technical Name: Required

    15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: O-C
    Oxidizing. Corrosive.
    R-PHRASES: 8-34
    Contact with combustible material may cause fire. Causes burns.
    S-PHRASES: 17-26-36/37/39-45
    Keep away from combustible material. In case of contact with
    eyes, rinse immediately with plenty of water and seek medical
    advice. Wear suitable protective clothing, gloves, and eye/face
    protection. In case of accident or if you feel unwell, seek
    medical advice immediately (show the label where possible).

    16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    


SECTION 16 - ADDITIONAL INFORMATION
N/A

高氯酸铕 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:449.766734Da

8、标称质量:450Da

9、平均质量:450.3158Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:12

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积223

7.重原子数量:16

8.表面电荷:0

9.复杂度:95.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

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产品介绍:
产品名称:高氯酸铕 Cas号:13537-22-9 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:张经理 电话:13070690626 手机:13070690626

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产品名称:高氯酸铕 Cas号:13537-22-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:吴征 电话:0797-8608546 手机:

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产品介绍:
产品名称:高氯酸铕 Cas号:13537-22-9 纯度:98%-99% 包装信息:2kg 价格:洽谈
联系方式:
联系人:耿美蓉 电话:0511-88561294 手机:013905284673