Fmoc-D-烯丙基甘氨酸

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品

Fmoc-D-烯丙基甘氨酸 基本信息

中文名称:
Fmoc-D-烯丙基甘氨酸 
中文别名:
Fmoc-D-烯丙基甘氨酸;
2-烯丙基-N-Fmoc-D-氨基乙酸;
2-烯丙基-N-FMOC-D-氨基乙酸;
(R)-2-(芴甲氧羰基-氨基)-4-戊烯酸;
N-芴甲氧羰基-D-烯丙基甘氨酸 
英文名称:
4-Pentenoic acid,2-[[(9H-fluoren-9-ylmethoxy)carbonyl]amino]-, (2R)-
英文别名:
(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)pent-4-enoic acid;
Fmoc-D-allyl-Gly-OH;
2-Allyl-N-Fmoc-D-glycine;
(2R)-2-(9H-fluoren-9-ylmethoxycarbonylamino)pent-4-enoic acid 
CAS No.:
170642-28-1
分 子 式:
C20H19NO4
分 子 量:
337.37
精确分子量:
337.13100
PSA:
66.84000
MDL:
MFCD01311776
BRN:
7389283
InChI:
InChI=1/C20H19NO4/c1-2-7-18(19(22)23)21-20(24)25-12-17-15-10-5-3-8-13(15)14-9-4-6-11-16(14)17/h2-6,8-11,17-18H,1,7,12H2,(H,21,24)(H,22,23)/p-1/t18-/m1/s1
危险品标志:
Xi
风险术语:
 Xi:;
安全术语:
S24/25;S22
分子结构式:
SDS:
查看

Fmoc-D-烯丙基甘氨酸 物化性质

外观与性状:
白色粒状的粉末
密度:
1.245g/cm3
熔点:
134 °C
沸点:
563ºC at 760mmHg
闪点:
294.3ºC
蒸汽压:
1.64E-13mmHg at 25°C
存储条件/存储方法:

 

密闭于0 ºC阴凉干燥环境中

稳定性相关:

 

遵照规定使用和储存则不会分解。

其它信息:

1.       性状:无可用

2.       密度(g/mL,25/4):无可用

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):134

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa):无可用

7.       折射率:无可用

8.       闪点(ºC):无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V):无可用

19.    溶解性:无可用

Fmoc-D-烯丙基甘氨酸 安全信息

安全说明:
S24/25-S22
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。
危险标志:
Xi

Fmoc-D-烯丙基甘氨酸 毒理性

生态数据:

 

该物质对环境可能有危害,对水体应给予特别注意。

Fmoc-D-烯丙基甘氨酸 MSDS

Name: (R)-N-FMOC-Allylglycine 95% (98% E.E.) Material Safety Data Sheet
Synonym: (R)-N-(9-Fluorenylmethoxycarbonyl)-2-Amino-4-Pentenoic Acid
CAS: 170642-28-1
Section 1 - Chemical Product   MSDS Name:(R)-N-FMOC-Allylglycine 95% (98% E.E.) Material Safety Data Sheet
Synonym:(R)-N-(9-Fluorenylmethoxycarbonyl)-2-Amino-4-Pentenoic Acid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
170642-28-1 (R)-N-FMOC-Allylglycine 95% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 170642-28-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 134 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C20H19NO4
Molecular Weight: 337.37

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 170642-28-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(R)-N-FMOC-Allylglycine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 170642-28-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 170642-28-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 170642-28-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

Fmoc-D-烯丙基甘氨酸 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:92.90

2、   摩尔体积(m3/mol):270.8

3、   等张比容(90.2K):730.6

4、   表面张力(dyne/cm):52.9

5、   极化率10-24cm3):36.83

计算化学数据

1、   疏水参数计算参考值(XlogP):4.4

2、   氢键供体数量:1

3、   氢键受体数量:4

4、   可旋转化学键数量:6

5、   拓扑分子极性表面积(TPSA):78.5

6、   重原子数量:25

7、   表面电荷:-1

8、   复杂度:478

9、   同位素原子数量:0

10、   确定原子立构中心数量:1

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

推荐供应商更多供应商>>

湖北齐飞医药化工有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:汪经理 电话:027-59322506 手机:18071128683

湖北云镁科技有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

湖北信康医药化工有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北广奥生物科技有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:孙经理 电话:027-59223056 手机:15271829679

湖北永阔科技有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:徐 电话:027-59223108 手机:15107166787

湖北实顺生物科技有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张经理 电话:027-59223025 手机:15172526927

天门恒昌化工有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄经理 电话:027-59322316 手机:15827039378

山东默派生物科技有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:谭经理 电话:13070690626 手机:13070690626

湖北万得化工有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北鑫红利化工有限公司

产品介绍:
产品名称:Fmoc-D-烯丙基甘氨酸 Cas号:170642-28-1 纯度:99% 包装信息:1t吨袋,200kg镀锌铁桶/塑料桶,25kg纸板桶/编织袋/塑料桶,10kg铝听/纸箱,1kg铝箔袋/氟化瓶 价格:1.0元 - 1,000.0元
联系方式:
联系人:周女士 电话:027-59503710 手机:18871490254