二硝酸钯

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 表征图谱

二硝酸钯 基本信息

中文名称:
二硝酸钯 
中文别名:
硝酸钯;
硝酸亚钯;
二硝酸钯;
硝酸钯(2+);
硝酸钯,二水;
硝酸钯(II)水合物;
硝酸钯二水合物;
硝酸钯(II)溶液 
英文名称:
Nitricacid, palladium(2+) salt (2:1)
英文别名:
Palladium nitrate;
Palladium(II) nitrate dihydrate;
PALLADIUM STANDARD SOLUTION;
Pa Nitrate;
palladiumdinitrate;
PALLACIUM(II)NITRATE;
PALLADIUM(II) NITRATE 2 H2O;
Palladium(II) nitrate solution;
Palladous nitrate;
Palladium nitrate di;
Palladium(II) nitrate;
PaladiumNitrate;
PALLADIUM(II) NITRATE 
CAS No.:
10102-05-3
分 子 式:
HNO3.1/2Pd
分 子 量:
230.43
精确分子量:
229.87900
PSA:
137.76000
MDL:
MFCD00011169
EINECS:
233-265-8
InChI:
InChI=1/NO3.Pd/c2-1(3)4;/q-1;+2
风险术语:
34-36/37/38-8
分子结构式:
SDS:
查看

二硝酸钯 制备方法及用途

制备方法

将金属钯粉或新制备的氢氧化钯加入浓硝酸中,水浴加热。过滤,所得滤液减压蒸馏浓缩后,放入干燥器中冷却结晶。抽滤。产品密封保存。

合成制备方法

将金属钯粉或新制备的氢氧化钯加入浓硝酸中,水浴加热。过滤,所得滤液减压蒸馏浓缩后,放入干燥器中冷却结晶。抽滤。产品密封保存。

用途简介

用作分析试剂,分离氯和碘,用作有机合成催化剂。

用途

用作分析试剂,分离氯和碘,用作有机合成催化剂。[12]

二硝酸钯 物化性质

外观与性状:
黄色或橙色棕色液体,酸味
密度:
1.118 g/mL at 25 °C
熔点:
>100ºC
沸点:
83ºC at 760 mmHg
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物分开存放
稳定性相关:

1.稳定性[6]  稳定

2.禁配物[7]  还原剂、易燃或可燃物、活性金属粉末、硫、磷

3.避免接触的条件[8]  受热

4.聚合危害[9]  不聚合

5.分解产物[10]  氮氧化物

其它信息:

1.性状:棕黄色结晶或粉末,有潮解性。[1]

2.熔点(℃):分解[2]

3.相对密度(水=1):1.118[3]

4.溶解性:溶于水,溶于稀硝酸。[4]

二硝酸钯 安全信息

包装等级:
II
风险类别:
5.1
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R34
安全说明:
S26-S36/37/39-S45-S17
RTECS号:
QV0560000
危险标志:
Xi: Irritant;C: Corrosive;O: Oxidizing agent;

二硝酸钯 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QV0560000
CHEMICAL NAME :
Nitric acid, palladium(2+) salt
CAS REGISTRY NUMBER :
10102-05-3
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
N2-O6.Pd
MOLECULAR WEIGHT :
230.42

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :
Rodent - rat
DOSE/DURATION :
56 umol/kg
REFERENCE :
EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 12,57,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1001 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 140 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1001 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1445 (estimated) No. of Female Employees: 230 (estimated)
毒理学数据:

1.急性毒性  暂无资料

2.刺激性  暂无资料

生态数据:

1.生态毒性  暂无资料

2.生物降解性  暂无资料

3.非生物降解性  暂无资料

4.其他有害作用[5]  该物质对环境有危害,应特别注意对水体的污染。

二硝酸钯 MSDS


Section 1: Product Identification
   Chemical Name:       Palladium (II) nitrate hydrate(Pd approx. 40%) (99.9%-Pd)    
   CAS Registry Number:       10102-05-3    
   Formula:       Pd(NO3)2.XH2O    
   EINECS Number:       233-265-8    
   Chemical Family:       metal nitrate salts    
   Synonym:       Palladium dinitrate, Nitric acid, palladium (+2) salt    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10102-05-3       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       brown xtl.    
   Molecular Weight:       230.72    
   Melting Point:       dec.    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
   Conditions to Avoid:
   temperatures.
   Incompatibility:       reducing agents, organic matter, phosphorus and sulfur    
   Decomposition Products:       nitrogen oxides and palladium salts    

SECTION 11: Toxicological Information
   RTECS Data:       Intraperitoneal (rat); DNA inhibition: 56 umol/kg.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       Possible mutagenic effects reported in RTECS    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1477    
   Shipping Name (IATA):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1477    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title Compound: See Category Code N511 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

二硝酸钯 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:229.879119 Da

8、标称质量:230 Da

9、平均质量:230.4298 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积126

7.重原子数量:9

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

二硝酸钯 表征图谱

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