碳酸锌

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

碳酸锌 基本信息

中文名称:
碳酸锌 
中文别名:
碳酸锌;
菱锌矿 
英文名称:
Carbonic acid, zinc salt (1:1)
英文别名:
Carbonic acid, zinc salt (1:1);
Zinc carbonate (6CI,7CI);
Bayoxide Z Transparent;
C.I. 77950;
Transparent Zinc White;
Zinc Oxide Transparent;
Zinc carbonate (1:1);
Zinc carbonate (ZnCO3);
Zinc monocarbonate 
CAS No.:
3486-35-9
分 子 式:
CO3Zn
分 子 量:
125.42
精确分子量:
125.92954
PSA:
214.51000
EINECS:
222-477-6
安全术语:
S24/25;
分子结构式:
SDS:
查看

碳酸锌 制备方法及用途

制备方法

复分解法

合成制备方法

复分解法

用途简介

1.用作轻型收敛剂和乳胶制品原料。用于配制炉甘石洗剂,用作皮肤保护剂。还可用于生产人造丝和催化脱硫剂。 2.饲料添加剂,在饲料中用于补锌剂。在医药上用作皮肤保护剂;化肥工业的脱硫剂;工业上还用作轻型收敛剂和乳胶制品以及配制炉甘石洗剂

用途

1.用作轻型收敛剂和乳胶制品原料。用于配制炉甘石洗剂,用作皮肤保护剂。还可用于生产人造丝和催化脱硫剂。

2.饲料添加剂,在饲料中用于补锌剂。在医药上用作皮肤保护剂;化肥工业的脱硫剂;工业上还用作轻型收敛剂和乳胶制品以及配制炉甘石洗剂


碳酸锌 物化性质

外观与性状:
白色粉末
密度:
4,398 g/cm3
沸点:
333.6ºC at 760 mmHg
闪点:
169.8ºC
存储条件/存储方法:

1.贮存于阴凉、通风、干燥的库房中。不可与酸碱类物品共贮混运。注意防潮。运输过程中要防雨淋、受潮,防日晒、受热。

2.失火时可用水浇救。沙土、灭火器扑救。

稳定性相关:

与30%双氧水作用,释出二氧化碳,形成过氧化物。当温度达到140℃左右时,开始分解。难溶于水,在沸水中加热变成碱式盐。

其它信息:

1.       性状:白色细微无定形粉末。无臭、无味。

2.       密度(g/mL,25/4℃):4.42~4.45

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:不溶于水和乙醇,,微溶于氨

碳酸锌 安全信息

风险类别:
9.2
海关代码:
2836999000
WGK_Germany:
1
德国有关水污染物质的分类清单
安全说明:
S22-S24/25

碳酸锌 毒理性

毒理学数据:

 

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

碳酸锌 MSDS

Name: Zinc Carbonate Material Safety Data Sheet
Synonym: Zinc carbonate (1:1); Zinc Monocarbonate; Carbonic acid, zinc salt
CAS: 3486-35-9
Section 1 - Chemical Product   MSDS Name:Zinc Carbonate Material Safety Data Sheet
Synonym:Zinc carbonate (1:1); Zinc Monocarbonate; Carbonic acid, zinc salt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
3486-35-9 Zinc carbonate 90-100 222-477-6
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep containers tightly closed.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 3486-35-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: odorless
pH: Not applicable.
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: Not applicable.
Freezing/Melting Point: Decomposes.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 300 deg C
Solubility in water: Insoluble in water.
Specific Gravity/Density: 4.398
Molecular Formula: ZnCO3
Molecular Weight: 125.3782

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures. Decomposed by acids with effervescence, evolution of carbon dioxide.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Carbon dioxide, zinc oxides.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 3486-35-9: FG3375000 LD50/LC50:
Not available.
Carcinogenicity:
Zinc carbonate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 3486-35-9: 1000 lb final RQ; 454 kg final RQ

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 3486-35-9: 0
Canada
CAS# 3486-35-9 is listed on Canada's DSL List.
CAS# 3486-35-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3486-35-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

碳酸锌 分子结构与计算化学数据

分子结构数据

 

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积63.2

7.重原子数量:5

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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