烯丙基甲基二氯硅烷,95%

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

烯丙基甲基二氯硅烷,95% 基本信息

中文名称:
烯丙基甲基二氯硅烷,95% 
中文别名:
烯丙基二氯甲基硅烷;
丙烯基甲基二氯硅烷;
烯丙基甲基二氯硅烷 
英文名称:
Silane,dichloromethyl-2-propen-1-yl-
英文别名:
ALLYLDICHLOROMETHYLSILANE;
dichloromethyl-2-propenyl-silan;
dichloromethylallylsilane;
Allyldichloromethylsilane;
Silane,allyldichloromethyl;
allyl (methyl)-dichlorosilane;
(ALLYL)DICHLORO(METHYL)SILANE PURUM;
ALLYLMETHYLSILYLDICHLORID;
Dichloromethyl 2-propenylsilane;
dichloroallylmethylsilane;
allyl(dichloro)methylsilane 
CAS No.:
1873-92-3
分 子 式:

C4H8Cl2Si

分 子 量:
155.1
精确分子量:
153.97700
PSA:
0.00000
MDL:
MFCD00045141
EINECS:
217-498-2
BRN:
1740877
InChI:
InChI=1/C4H8Cl2Si/c1-3-4-7(2,5)6/h3H,1,4H2,2H3
危险品标志:

F,C

风险术语:

R11R14R34

安全术语:

S16S26S45S36/S37/S39

分子结构式:
SDS:
查看

烯丙基甲基二氯硅烷,95% 制备方法及用途

制备方法

可由甲基三氯硅烷与烯丙基溴化镁反应来制取。

合成制备方法

 可由甲基三氯硅烷与烯丙基溴化镁反应来制取。

用途简介

用来合成有机硅中间体及高分子聚合物。

用途

用来合成有机硅中间体及高分子聚合物。

烯丙基甲基二氯硅烷,95% 物化性质

外观与性状:
透明无色至淡黄色液体
密度:
1.067 g/mL at 25 °C(lit.)
沸点:
119.5 °C(lit.)
闪点:
57 °F
折射率:
n20/D 1.440(lit.)
蒸汽压:
18.8mmHg at 25°C
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房,避免与湿气,水源接触。干爽的惰性气体保护。

稳定性相关:

常温常压下稳定,避免与不相容材料,火源,湿空气,水接触。

与潮湿的空气,水,酸,碱,醇,胺,氨,过氧化物,醛类(如乙醛,丙烯醛,三氯乙醛,甲醛),酮类(如丙酮,苯乙酮,丁酮,甲基异丁基酮)反应。

其它信息:

1.      性状:无色或浅黄色透明液体

2.      密度(g/mL,25):1.067

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):119.5

6.      沸点(ºC,11mmHg):未确定

7.      折射率(n20/D)1.440

8.      闪点(ºC):20

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):13

11.   蒸气压(mmHg,20ºC):未确定

12.   饱和蒸气压(kPa,25ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:与水反应

烯丙基甲基二氯硅烷,95% 安全信息

包装等级:
II
风险类别:
3
海关代码:
2931900090
WGK_Germany:
1
德国有关水污染物质的分类清单
危险类别码:
R11
安全说明:
S16-S26-S36/37/39-S45
安全标志:
S16:远离火源。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
F: Flammable;C: Corrosive;

烯丙基甲基二氯硅烷,95% 毒理性

生态数据:

对水稍微危害,避免未稀释或大量的产品接触地下水、水道或污水系统。

烯丙基甲基二氯硅烷,95% MSDS

Name: Allyldichloromethylsilane 97% Material Safety Data Sheet
Synonym:
CAS: 1873-92-3
Section 1 - Chemical Product   MSDS Name:Allyldichloromethylsilane 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1873-92-3 Allyldichloromethylsilane 97 217-498-2
Hazard Symbols: F C
Risk Phrases: 11 14 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Highly flammable. Reacts violently with water. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Do not expose spill to water.

Section 7 - HANDLING and STORAGE
  Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep away from water.
Flammables-area. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1873-92-3: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 119-120 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 20 deg C ( 68.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts with water
Specific Gravity/Density: 1.0670g/cm3
Molecular Formula: CH2CHCH2Si(CH3)Cl2
Molecular Weight: 155.10

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, alcohols, amines, ammonia, peroxides, aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), ketones (e.g. acetone, acetophenone, MEK, MIBK).
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 1873-92-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Allyldichloromethylsilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S.
Hazard Class: 3
UN Number: 2985
Packing Group: II
IMO
Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S.
Hazard Class: 3
UN Number: 2985
Packing Group: II
RID/ADR
Shipping Name: Chlorosilanes, Flammable, Corrosive, N.O.S.
Hazard Class: 3
UN Number: 2985
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1873-92-3: No information available.
Canada
CAS# 1873-92-3 is listed on Canada's NDSL List.
CAS# 1873-92-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1873-92-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

烯丙基甲基二氯硅烷,95% 海关数据

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

烯丙基甲基二氯硅烷,95% 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:0

3、   氢键受体数量:0

4、   可旋转化学键数量:2

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA):0

7、   重原子数量:7

8、   表面电荷:0

9、   复杂度:70.1

10、同位素原子数量:0

11、确定原子立构中心数量:0

12、不确定原子立构中心数量:0

13、确定化学键立构中心数量:0

14、不确定化学键立构中心数量:0

15、共价键单元数量:1

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