硝酸钙

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

硝酸钙 基本信息

中文名称:
硝酸钙 
中文别名:
硝酸钙;
无水硝酸钙;
Minocycline;
米诺环素;
sulfurous acid, monopotassium salt;
4-[(E)-{3-[(Z)-(2,4-diaminophenyl)diazenyl]phenyl}diazenyl]benzene-1,3-diamine dihydrochloride;
Basic Brown1;
Basic Brown 1;
Bismarck brown Y;
Kadmiumchlorid [German];
NSC 51148;
UNII-J6K4F9V3BA;
VI-Cad;
Cadmium chloride (CdCl2);
Cadmium chloride [Cadmium and cadmium compounds];
Cadmium chloride;
ammonium iron(2+) sulfate (2:1:2);
iron - sulfuric acid ammoniate (1:1:1);
 
英文名称:
Calcium(II) nitrate (1:2)
英文别名:
Nitric acid, calcium salt (2:1);
Nitric acid, calcium salt (8CI,9CI);
Calcium dinitrate;
Calcium nitrate;
Calcium nitrate (Ca(NO3)2);
Norge saltpeter;
Norway saltpeter;
Norwegian saltpeter;
Nutriox;
Synfat 1006 
CAS No.:
10124-37-5
分 子 式:

Ca.2HNO3

分 子 量:
164.09
精确分子量:
165.95388
PSA:
137.76000
EINECS:
233-332-1
InChI:
InChI:1S/Ca.2NO3/c;2*2-1(3)4/q+2;2*-1
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

硝酸钙 制备方法及用途

制备方法

用于冷冻剂、水泥防冻剂、橡胶工业絮凝剂,也用于制造烟火、电子管、速效肥料等。储运时需加注意,应密封储存。

用途简介

用途

用于制造烟火、炸药、火柴、肥料等。[13]

硝酸钙 物化性质

密度:
2.36
熔点:
561°C
沸点:
83ºC at 760 mmHg
水溶解性:
Soluble
存储条件/存储方法:
库房通风,轻装轻卸,与有机物、还原剂、木炭、硫磷易燃物,食品原料分开存放
稳定性相关:

1.稳定性[7]  稳定

2.禁配物[8]  强还原剂、强酸、磷、铝、硫

3.避免接触的条件[9]  受热

4.聚合危害[10]  不聚合

5.分解产物[11]  氮氧化物

其它信息:

1.性状:无色透明单斜结晶或粉末[1]

2.熔点(℃):561[2]

3.相对密度(水=1):2.36[3]

4.溶解性:易溶于水、液氨、丙酮、甲醇、乙醇,不溶于浓硝酸。[4]

硝酸钙 安全信息

包装等级:
III
风险类别:
5.1
海关代码:
2834299090
WGK_Germany:
-
德国有关水污染物质的分类清单
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

硝酸钙 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EW2985000
CAS REGISTRY NUMBER :
10124-37-5
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
N2-O6.Ca
MOLECULAR WEIGHT :
164.10
WISWESSER LINE NOTATION :
.CA..NO3*2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
302 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(12),66,1981 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81753 No. of Facilities: 252 (estimated) No. of Industries: 12 No. of Occupations: 12 No. of Employees: 2102 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81753 No. of Facilities: 350 (estimated) No. of Industries: 13 No. of Occupations: 21 No. of Employees: 19867 (estimated) No. of Female Employees: 10730 (estimated)
毒理学数据:

1.急性毒性[5]  LD50:3900mg/kg(大鼠经口)

2.刺激性  暂无资料

生态数据:

1.生态毒性  暂无资料

2.生物降解性  暂无资料

3.非生物降解性  暂无资料

4.其他有害作用[6]  该物质对环境有危害,应特别注意对水体的污染。

硝酸钙 MSDS

Name: Calcium nitrate trihydrate 99.999% Material Safety Data Sheet
Synonym: Nitric acid, calcium salt, trihydrate; Norwegian saltpeter trihydrate; Calcium dinitrate trihydrate; Lime nitrate trihydrate; Nitrocalcite trihydrate; Lime saltpeter trihydrate
CAS: 10124-37-5
Section 1 - Chemical Product   MSDS Name:Calcium nitrate trihydrate 99.999% Material Safety Data Sheet
Synonym:Nitric acid, calcium salt, trihydrate; Norwegian saltpeter trihydrate; Calcium dinitrate trihydrate; Lime nitrate trihydrate; Nitrocalcite trihydrate; Lime saltpeter trihydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10124-37-5 Calcium nitrate trihydrate 99.999 unlisted
Hazard Symbols: XI O
Risk Phrases: 36 8

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes. Contact with combustible material may cause fire.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause digestive tract disturbances. Ingestion of nitrate containing compounds can lead to methemoglobinemia.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia.
Chronic:
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis (bluish skin due to deficient oxygenation of blood), rapid heart rate, unconsciousness and possible death.

Section 4 - FIRST AID MEASURES
  Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene Blue depending on the methemoglobin concentration in the blood.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire. Containers may explode in the heat of a fire. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.
Extinguishing Media:
Cool containers with flooding quantities of water until well after fire is out. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.
Keep combustibles (wood, paper, oil, etc.,) away from spilled material.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep from contact with clothing and other combustible materials. Avoid breathing dust. Inform laundry personnel of contaminant's hazards.
Storage:
Do not store near combustible materials. Keep away from reducing agents. Keep containers tightly closed. Avoid storage on wood floors.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 10124-37-5: CAS# 15842-29-2: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white to pale yellow
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 51.1 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: CaN2O6.3H2O
Molecular Weight: 218.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Deliquescent (tending to absorb atmospheric water vapor and become liquid).
Conditions to Avoid:
Mechanical shock, dust generation, moisture, excess heat.
Incompatibilities with Other Materials:
Strong reducing agents, ammonia, finely powdered metals, hydrazine, organic materials, combustible materials.
Hazardous Decomposition Products:
Oxides of nitrogen, calcium oxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10124-37-5: EW2985000 CAS# 15842-29-2 unlisted.
LD50/LC50:
CAS# 10124-37-5: Oral, rat: LD50 = 302 mg/kg.
CAS# 15842-29-2.
Carcinogenicity:
Calcium nitrate anhydrous - Not listed by ACGIH, IARC, or NTP.
Calcium nitrate trihydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CALCIUM NITRATE
Hazard Class: 5.1
UN Number: 1454
Packing Group: III
IMO
Shipping Name: CALCIUM NITRATE
Hazard Class: 5.1
UN Number: 1454
Packing Group: III
RID/ADR
Shipping Name: CALCIUM NITRATE
Hazard Class: 5.1
UN Number: 1454
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36 Irritating to eyes.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 10124-37-5: 1
CAS# 15842-29-2: No information available.
Canada
CAS# 10124-37-5 is listed on Canada's DSL List.
CAS# 10124-37-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 15842-29-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10124-37-5 is listed on the TSCA inventory.
CAS# 15842-29-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

硝酸钙 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:163.938227 Da

8、标称质量:164 Da

9、平均质量:164.0878 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:6

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积126

7.重原子数量:9

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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