过氯酸镱(III)

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

过氯酸镱(III) 基本信息

中文名称:
过氯酸镱(III) 
中文别名:
过氯酸镱(III);
高氯酸镱(III);
高氯酸镱 
英文名称:
Ytterbium(iii) perchlorate
英文别名:
ytterbium(3+),triperchlorate;
Ytterbium perchlorate;
YTTERBIUM(III) PERCHLORATE;
Ytterbium(III) perchlorate solution;
Ytterbium triperchlorate;
Ytterbiumperchlorate (Yb(ClO4)3) (7CI) 
CAS No.:
13498-08-3
分 子 式:
ClHO4.1/3Yb
分 子 量:
471.39
精确分子量:
470.78400
PSA:
222.81000
MDL:
MFCD00049612
EINECS:
236-823-9
风险术语:
R8R34
安全术语:
S17S26S45S36/S37/S39
分子结构式:
SDS:
查看

过氯酸镱(III) 物化性质

密度:
1.474 g/mL at 25 °C
存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料 还原剂 易氧化材料 水溶液与碱金属 碱土金属和许多有机无机的活性化学药品是不相溶的

其它信息:

1.       性状:无色无味溶液

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:完全可拌和的

过氯酸镱(III) 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
R8
安全说明:
17-26-36/37/39-45
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
O: Oxidizing agent;C: Corrosive;

过氯酸镱(III) 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

过氯酸镱(III) MSDS


Section 1: Product Identification
   Chemical Name:       Ytterbium (III) perchlorate, 50% aqueous solution (99.9%-Yb) (REO)    
   CAS Registry Number:       13498-08-3    
   Formula:       Yb(ClO4)3    
   EINECS Number:       none    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, Ytterbium(III) salt, aqueous solution    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13498-08-3       50%       no data       no data    
   water       7732-18-5       50%       no data       no data    

Section 3: Hazards Identification
   Irritating to eyes, skin and respiratory tract. May be harmful if swallowed. May affect thyroid and kidney
   Emergency Overview:
   functions
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes moderate irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
   Ingestion:
   irritation, nausea, and vomiting.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Keep sample area wet until fire is completely out. Once dry, product becomes a powerful oxidant, and will act
   Special Fire Fighting Procedures:
   as a source of oxygen to support combustion.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: May decompose explosively if allowed to dry under fire fighting conditions. Do not mix with combustibles.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Adsorb the liquid into vermiculite or other non combustible adsorbent.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container in a cool place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liq.    
   Molecular Weight:       471.39    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       Air and moisture stable liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter, followed by evaporation of water.    
   None as aqueous solution. If dried, avoid reducing agents, organic matter, active metals, hydrazine, and
   Incompatibility:
   strong acids
   Decomposition Products:       Oxygen, Ytterbium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 3211    
   Shipping Name (IATA):       Perchlorates, Inorganic, Aqueous solution, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 3211    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

过氯酸镱(III) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:470.784434 Da

8、标称质量:471 Da

9、平均质量:471.3918 Da

计算化学数据

1、   氢键供体数量:1

2、   氢键受体数量:13

3、   可旋转化学键数量:0

4、   拓扑分子极性表面积(TPSA):224

5、   重原子数量:17

6、   表面电荷:0

7、   复杂度:95.8

8、   同位素原子数量:0

9、   确定原子立构中心数量:0

10、   不确定原子立构中心数量:0

11、   确定化学键立构中心数量:0

12、   不确定化学键立构中心数量:0

13、   共价键单元数量:5

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产品介绍:
产品名称:高氯酸镱 Cas号:13498-08-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
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阿法埃莎(天津)化学有限公司

产品介绍:
产品名称:过氯酸镱(III) Cas号:13498-08-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
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