3,4-二氨基三氟甲苯

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

3,4-二氨基三氟甲苯 基本信息

中文名称:
3,4-二氨基三氟甲苯 
中文别名:
3,4-二胺基苄氧基三氟化物;
4-三氟甲基邻苯二胺;
4-三氟甲基-1,2-苯二胺;
3,4-二氨基三氟甲苯 
英文名称:
1,2-Benzenediamine,4-(trifluoromethyl)-
英文别名:
3,4-DIAMINOBENZOTRIFLUORIDE;
4-(Trifluoromethyl)-1,2-phenylenediamine;
4-Trifluoromethyl-1,2-Phenylenediamine;
3,4-DIAMINOTRIFLUOROMETHYLBENZENE;
1,2-diamino-4-trifluoromethylbenzene;
5-trifluoromethyl-o-phenylenediamine;
4-Trifluoromethyl-o-phenylenediamine;
4-(Trifluoromethyl)benzene-1,2-diamine;
4-trifluoromethyl-1,2-diaminobenzene;
4-(Trifluoromethyl)-o-phenylenediamine;
Benzene-1,2-diami 
CAS No.:
368-71-8
分 子 式:
C7H7F3N2
分 子 量:
176.14
精确分子量:
176.05600
PSA:
52.04000
MDL:
MFCD00042456
BRN:
909258
InChI:
InChI=1/C7H7F3N2/c8-7(9,10)5-2-1-4(11)3-6(5)12/h1-3H,11-12H2
危险品标志:
Xn:Harmful
风险术语:
R20/21/22; R36/37/38;
安全术语:
S26; S36/37/39;
分子结构式:
SDS:
查看

3,4-二氨基三氟甲苯 制备方法及用途

制备方法

用作医药、农药中间体

用途简介

3,4-二氨基三氟甲苯 物化性质

外观与性状:
灰色至棕色固体
密度:
1.381 g/cm3
熔点:
56-58 °C
沸点:
252.7ºC at 760 mmHg
闪点:
111.1ºC
折射率:
1.535
其它信息:

一、物性数据

性状:不可用

密度(g/mL,25/4): 不可用

相对蒸汽密度(g/mL,空气=1)不可用

熔点(ºC):56-58

沸点(ºC,常压):不可用

沸点(ºC,5.2kPa): 不可用

折射率: 不可用

闪点(ºC): 不可用

比旋光度(º): 不可用

自燃点或引燃温度(ºC): 不可用

蒸气压(kPa,25ºC): 不可用

饱和蒸气压(kPa,60ºC): 不可用

燃烧热(KJ/mol):不可用

临界温度(ºC): 不可用

临界压力(KPa): 不可用

油水(辛醇/水)分配系数的对数值:不可用 

爆炸上限(%,V/V):不可用

爆炸下限(%,V/V): 不可用

溶解性:不可用

3,4-二氨基三氟甲苯 安全信息

海关代码:
2921590090
危险类别码:
R20/21/22;R36/37/38
安全说明:
S36/37/39-S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xn:Harmful;

3,4-二氨基三氟甲苯 毒理性

毒理学数据:

二、毒理学数据:

急性毒性:不可用 。

生态数据:

三、生态学数据:

1、其它有害作用:该物质对环境可能有危害,对水体应给予特别注意。

3,4-二氨基三氟甲苯 MSDS

Name: 4-(Trifluoromethyl)-1 2-phenylenediamine Material Safety Data Sheet
Synonym: None Known
CAS: 368-71-8
Section 1 - Chemical Product   MSDS Name:4-(Trifluoromethyl)-1 2-phenylenediamine Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
368-71-8 4-(Trifluoromethyl)-1,2-phenylenediami 99 unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 368-71-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: grey - brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 58 - 60 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H7F3N2
Molecular Weight: 176.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen fluoride gas, nitric acid.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 368-71-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-(Trifluoromethyl)-1,2-phenylenediamine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 368-71-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 368-71-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 368-71-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3,4-二氨基三氟甲苯 海关数据

中国海关编码:2921590090

概述:
2921590090. 其他芳香多胺及衍生物及它们的盐. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

3,4-二氨基三氟甲苯 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:39.70

2、   摩尔体积(m3/mol):127.5

3、   等张比容(90.2K):316.1

4、   表面张力(dyne/cm):37.7

5、   极化率10-24cm3):15.74

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:2

3.氢键受体数量:5

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积52

7.重原子数量:12

8.表面电荷:0

9.复杂度:157

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

湖北常鑫盛化工有限公司

产品介绍:
产品名称:3,4-二胺基苄氧基三氟化物 Cas号:368-71-8 纯度:98 包装信息:25kg,1kg 价格:5.0元 - 10.0元
联系方式:
联系人:黄 电话:18971203904 手机:18971203904

湖北云镁科技有限公司

产品介绍:
产品名称:4-三氟甲基邻苯二胺 Cas号:368-71-8 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

沧州恩科医药科技有限公司

产品介绍:
产品名称:3,4-二胺基苄氧基三氟化物 Cas号:368-71-8 纯度:98% 包装信息:100kg,200kg 价格:0.0元 - 100.0元
联系方式:
联系人:赵经理 电话:0317-5106598 手机:13323075105

武汉鑫伟烨化工有限公司

产品介绍:
产品名称:3,4-二氨基三氟甲苯 Cas号:368-71-8 纯度:98% 包装信息:25kg,25kg,25kg 价格:1.0元 - 1.0元
联系方式:
联系人:郭经理 电话:027-85953558 手机:13377862267

山东西亚化学有限公司

产品介绍:
产品名称:4-三氟甲基邻苯二胺 Cas号:368-71-8 纯度:98% 包装信息:5g 价格:188.0元
联系方式:
联系人:崔 电话:4009903999 手机:18053972095

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:3,4-二胺基三氟甲苯 Cas号:368-71-8 纯度:99% 包装信息:100kg,200kg 价格:1.0元 - 1.0元
联系方式:
联系人:黄 电话:027-50662354 手机:13264726139

湖北鑫鸣泰化学有限公司

产品介绍:
产品名称:4-三氟甲基邻苯二胺 Cas号:368-71-8 纯度:98% 包装信息:25kg/桶kg 价格:1.0元
联系方式:
联系人:黄经理 电话:027-51833411 手机:13237166274

山东默派生物科技有限公司

产品介绍:
产品名称:3,4-二胺基苄氧基三氟化物 Cas号:368-71-8 纯度:99% 包装信息:1kg 价格:洽谈
联系方式:
联系人:张经理 电话:13070690626 手机:13070690626

湖北江民泰华化工有限公司

产品介绍:
产品名称:3,4-二氨基三氟甲苯 Cas号:368-71-8 纯度:99% 包装信息:25kg,200kg 价格:洽谈
联系方式:
联系人:张经理 电话:13396038321 手机:13396038321

武汉琼格生物科技有限公司

产品介绍:
产品名称:4-三氟甲基邻苯二胺 Cas号:368-71-8 纯度:0.98 包装信息:100g,100g,100g,100g,100g 价格:2,129.0元 - 2,129.0元
联系方式:
联系人:时燕 电话:027-84235681 手机:13657207535