环己二烯三羰基铁

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

环己二烯三羰基铁 基本信息

中文名称:
环己二烯三羰基铁 
中文别名:
三羰基环己二烯基铁;
环己二烯三羰基铁 
英文名称:
cyclohexadiene iron tricarbonyl
英文别名:
Iron, tricarbonyl[(1,2,3,4-η)-1,3-cyclohexadiene]-;
Cyclohexadieneiron tricarbonyl (6CI);
Iron, tricarbonyl(1,3-cyclohexadiene)- (7CI,8CI);
1,3-Cyclohexadiene, iron complex;
Tricarbonyl[(1,2,3,4-η)-1,3-cyclohexadiene]iron;
1,3-Cyclohexadieneiron tricarbonyl;
Cyclohexadienetricarbonyliron;
Tricarbonyl(1,3-cyclohexadiene)iron;
Tricarbonyl(η4-1,3-cyclohexadiene)iron 
CAS No.:
12152-72-6
分 子 式:

C9H8FeO3

分 子 量:
220.01
精确分子量:
219.98228
PSA:
0.00000
MDL:
MFCD00070435
InChI:
The Key: OVNCEUCQDGRASI-UHFFFAOYSA-N
危险品标志:

 

风险术语:

 

安全术语:

 

分子结构式:
SDS:
查看

环己二烯三羰基铁 物化性质

熔点:
8ºC
存储条件/存储方法:

常温密闭避光,通风干燥处

稳定性相关:

常温常压下稳定

避免的物料 氧化物 卤素 空气热

其它信息:

1.       性状:黄色液体

2.       密度(g/mL,20):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):8

5.       沸点(ºC,常压):未确定

6.       沸点(ºC1mmHg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

环己二烯三羰基铁 安全信息

包装等级:
II
风险类别:
6.1
危险类别码:
11-36/37/38
安全说明:
16-26-36

环己二烯三羰基铁 毒理性

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

环己二烯三羰基铁 MSDS


Section 1: Product Identification
   Chemical Name:       Cyclohexadiene iron tricarbonyl, 98%    
   CAS Registry Number:       12152-72-6    
   Formula:       C6H8Fe(CO)3    
   EINECS Number:       None    
   Chemical Family:       metal carbonyl complexes    
   Synonym:       1,4-Cyclohexadiene iron tricarbonyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12152-72-6       100%       no data       no data    

Section 3: Hazards Identification
   Harmful by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory
   Emergency Overview:
   tract.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes.    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin. Harmful in contact with skin.    
   Inhalation:       Harmful by inhalation. may be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       harmful if swallowed.    
   Acute Health Affects:       Harmful by inhalation, in contact with skin and if swallowed.    
   The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
   Chronic Health Affects:
   may be present.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Keep material in a tightly sealed container. Prolonged exposure to the air will result in degradation of the
   Handling and Storage:
   product. Handle and store material under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       yellow to orange liq.    
   Molecular Weight:       220.01    
   Melting Point:       8°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air sensitive, (store cold)    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Contact with air    
   Incompatibility:       Oxidizing agents and halogens    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and iron oxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Flammable liquids, N.O.S.    
   Hazard Class (CFR):       3    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1993    
   Shipping Name (IATA):       Flammable liquids, N.O.S.    
   Hazard Class (IATA):       3    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1993    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

环己二烯三羰基铁 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:219.982286 Da

8、标称质量:220 Da

9、平均质量:220.003 Da

推荐供应商更多供应商>>

湖北万得化工有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:库薇 电话:027-59210159 手机:15172311821

湖北巨胜科技有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:孙敏 电话:027-59599240 手机:18702754003

湖北广奥生物科技有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:李经理 电话:027-59223056 手机:15271829679

湖北信康医药化工有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:张欢 电话:027-59308705 手机:18827031272

湖北摆渡化学有限公司

产品介绍:
产品名称:环己二烯三羰基铁 Cas号:12152-72-6 纯度:99% 包装信息:25kg 价格:1.0元
联系方式:
联系人:陈经理 电话:027-59223020 手机:18871490324

郑州杰克斯化工有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:许伟伟 电话:0371-86259281 15981966935 手机:15981966935

阿法埃莎(天津)化学有限公司

产品介绍:
产品名称:三羰基环己二烯基铁 Cas号:12152-72-6 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:张海滨 电话:800-810-6000 手机: