氯胺

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 上游产品
  • 下游产品
  • 表征图谱

氯胺 基本信息

中文名称:
氯胺 
中文别名:
氯胺T;
氯胺 T 
英文名称:
Benzenesulfonamide,N-chloro-4-methyl-, sodium salt (1:1)
英文别名:
chloramine T;
clorosan;
Chloramine T;
N-Chloro-4-toluenesulfonamide,sodium salt;
MeC6H4SO3NNaCl;
sodium N-chloro-p-toluenesulfonamide;
N-CHLORO-4-TOLUOLSULFONAMID SODIUM;
BENZENESULFONAMIDE,N-CHLORO-4-METHYL-, SODIUM SALT (1:1);
Sodium chloro(tosyl)amide;
aktivin;
CHLORAMINE-T, TRIHYDRATE OR - 250 G;
Chloramine-T;
CHLORAMINE T TRIHYDRATE;
clorina;
NF X;
halamid;
Aktiven;
Chloramine (T);
GANSIL;
anexol;
CHLORAMINE-T-TRIHYDRATE;
MIANINE;
MI 9 
CAS No.:
127-65-1
分 子 式:

C7H8ClNO2S.Na

分 子 量:
281.69
精确分子量:
226.97800
PSA:
42.52000
EINECS:
204-854-7
InChI:
InChI=1/C7H8ClNO2S.Na/c1-6-2-4-7(5-3-6)12(10,11)9-8;/h2-5,9H,1H3;/q;+1
危险品标志:


CorrosiveCHarmfulXn

风险术语:

R22;R31;R34;R42;

安全术语:

S1/2;S7;S22;S26;S36/37/39;S45;

分子结构式:
SDS:
查看

氯胺 制备方法及用途

制备方法

氯胺T为生产糖精时一种副产品,由对甲苯磺酰氯经氨水胺化、液碱成盐、氯气氯化而得。反应过程如下: 2.对甲基磺酰氯和氨水作用得到磺胺,再与次氯酸钠溶液作用而得。

合成制备方法

氯胺T为生产糖精时一种副产品,由对甲苯磺酰氯经氨水胺化、液碱成盐、氯气氯化而得。反应过程如下:

2.对甲基磺酰氯和氨水作用得到磺胺,再与次氯酸钠溶液作用而得。

用途简介

本品为外用广谱杀菌能力的消毒剂,含有效氯24-25%,性能稳定,对细菌、病毒、真菌、芽胞均有杀灭作用。常用于伤口与溃疡面冲洗消毒。适用于饮用水食具、食品、各种器具、水果蔬菜、养殖业消毒等,创面、粘膜冲洗。

用途

1.作自来水、游泳池水及创伤、器械、食具等的杀菌消毒剂。用于自来水及游泳池的灭菌剂量1∶300000,手指、器具消毒用0 . 3%~0 . 5%的溶液,创伤消毒用0 . 2%的溶液。

氯胺 物化性质

外观与性状:
白色或黄色粉末带有一种像氯一样的气味
密度:
1.36g/cm3
熔点:
167-170 °C(lit.)
沸点:
314.3ºC at 760mmHg
闪点:
143.9ºC
存储条件/存储方法:
库房低温通风干燥,与酸类分开存放
稳定性相关:

1.在乙醇中分解,受空气和光的作用亦会逐渐分解。有杀菌性能。对金色链霉菌、枯草杆菌、大肠杆菌、绿脓杆菌的抑制浓度为2 0 0 0 μ g·L-1,p H 呈酸性时的抗菌性比p H 呈碱性时大。主要通过对病菌体有效成分、酶蛋白的氧化分解而起抑菌作用。吸收后会使中枢神经机能受到抑制,产生气喘。

其它信息:

1. 性状:白色鳞片状固体或白色结晶粉末

2. 溶解性:易溶于水和甘油,不溶于乙醚、氯仿和苯。

氯胺 安全信息

海关代码:
2935009090
WGK_Germany:
2
德国有关水污染物质的分类清单
危险类别码:
R22;R31;R34;R42
安全说明:
S22-S26-S36/37/39-S45-S7-S1/2
安全标志:
S1/2:保持密封,保存在远离儿童的地点。
S22:不要吸入粉尘。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
C:Corrosive

氯胺 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XT5616800
CHEMICAL NAME :
p-Toluenesulfonamide, N-chloro-, sodium salt
CAS REGISTRY NUMBER :
127-65-1
LAST UPDATED :
199710
DATA ITEMS CITED :
11
MOLECULAR FORMULA :
C7-H8-Cl-N-O2-S.Na
MOLECULAR WEIGHT :
228.66
WISWESSER LINE NOTATION :
GMSWR DI &-NA-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
300 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - cyanosis Lungs, Thorax, or Respiration - respiratory depression
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
25 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - chronic pulmonary edema Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
900 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - excitement Behavioral - muscle weakness
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
200 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - spastic paralysis with or without sensory change Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Human Lymphocyte
DOSE/DURATION :
100 ppm/24H
REFERENCE :
ARMCAH Annual Review of Medicine. (Annual Reviews, Inc., POB 10139, Palo Alto, CA 94303) V.1- 1950- Volume(issue)/page/year: 21,409,1970 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83916 No. of Facilities: 93 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 378 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83916 No. of Facilities: 190 (estimated) No. of Industries: 7 No. of Occupations: 8 No. of Employees: 1829 (estimated) No. of Female Employees: 1284 (estimated)
毒理学数据:

非肠-小鼠 LCL0: 300 毫克/公斤

氯胺 MSDS

Name: Chloramine T-Sodium Salt Material Safety Data Sheet
Synonym: Sodium N-chloro-4-toluene sulfonamide; chloramine-t
CAS: 127-65-1
Section 1 - Chemical Product   MSDS Name:Chloramine T-Sodium Salt Material Safety Data Sheet
Synonym:Sodium N-chloro-4-toluene sulfonamide; chloramine-t

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
127-65-1 Chloramine-t 100 % 204-854-7
Hazard Symbols: XN
Risk Phrases: 36/37/38 42

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Appearance: white.
Warning! May cause skin irritation. May cause allergic respiratory reaction. Air sensitive. The toxicological properties of this material have not been fully investigated. May cause severe eye irritation and possible injury. May cause severe respiratory and digestive tract irritation with possible burns.
Target Organs: None.
Potential Health Effects
Eye:
Causes eye irritation. May result in corneal injury.
Skin:
Causes skin irritation.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated exposure may cause allergic respiratory reaction (asthma).

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits +--------------------+-------------------+-------------------+-----------------+ | Chemical Name | ACGIH | NIOSH |OSHA - Final PELs| |--------------------|-------------------|-------------------|-----------------| | Chloramine-t |none listed |none listed |none listed | +--------------------+-------------------+-------------------+-----------------+ OSHA Vacated PELs: Chloramine-t: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: white
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 167-170 C (decomposes)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C7H7ClNO2SNa
Molecular Weight: 227.5573

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to air, acids.
Incompatibilities with Other Materials:
Strong oxidizing agents, air, and acids. May decompose violently if heated above 130 C. Explodes when heated to 175 C. Mixtures with calcium carbonate + isonitriles explode when warmed.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, toxic fumes of sodium oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 127-65-1: XT5616800 LD50/LC50:
Not available.
Carcinogenicity:
Chloramine-t - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Chemical waste generators must determine whether a discarded chemical is classif as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Part Additionally, waste generators must consult state and local hazardous waste regu ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - TRANSPORT INFORMATION
 
CDG/CPL
Not classified as hazardous for supply.
Canadian TDG
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42 May cause sensitization by inhalation.
Safety Phrases:
S 2 Keep out of reach of children.
S 7 Keep container tightly closed.
S 15 Keep away from heat.
S 22 Do not breathe dust.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 127-65-1: 2
United Kingdom Occupational Exposure Limits
Canada
CAS# 127-65-1 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 127-65-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 127-65-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 302 (RQ)
None of the chemicals in this material have an RQ.
Section 302 (TPQ)
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 127-65-1: acute, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氯胺 海关数据

中国海关编码:2935009090

概述:
2935009090 其他磺(酰)胺. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:35.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

氯胺 上游产品

推荐供应商更多供应商>>

湖北诺纳科技有限公司

产品介绍:
产品名称:氯胺 T Cas号:127-65-1 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
联系方式:
联系人:张经理 电话:027-59209883 手机:17386169806

湖北云镁科技有限公司

产品介绍:
产品名称:氯胺 T Cas号:127-65-1 纯度:99% 包装信息:328kg,1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 328.0元
联系方式:
联系人:方经理 电话:027-59206672 手机:18327059871

湖北帝柏化工有限公司

产品介绍:
产品名称:对甲苯磺酰氯胺钠 Cas号:127-65-1 纯度:99% 包装信息:25/桶kg 价格:洽谈
联系方式:
联系人:雷经理 电话:15872383390 手机:15872383390

特斯科化工(湖北)有限公司

产品介绍:
产品名称:氯胺T Cas号:127-65-1 纯度:99% 包装信息:1kg袋,25kg袋,1000kg袋 价格:洽谈
联系方式:
联系人:郑先生 电话:18971353902 手机:18971353902

武汉卡诺斯科技有限公司

产品介绍:
产品名称:氯胺T Cas号:127-65-1 纯度:99% 包装信息:25千克 价格:21.0元
联系方式:
联系人:尚文 电话:153-37111468 手机:15337111468

上海吉至生化科技有限公司

产品介绍:
产品名称:N-氯-4-甲苯磺酰胺钠盐 Cas号:127-65-1 纯度:98% 包装信息:100gea,1kgea,25gea,500gea 价格:29.0元 - 254.0元
联系方式:
联系人:江珊 电话:021-57520831 手机:15316869680

山东省百州医药科技有限公司

产品介绍:
产品名称:氯胺-t Cas号:127-65-1 纯度:99% 包装信息:25g,100g,1kg,5kg,10kg 价格:100.0元 - 10,000.0元
联系方式:
联系人:杨亚楼 电话:18105309898 手机:18105309898

上海源叶生物科技有限公司

产品介绍:
产品名称:氯胺 T Cas号:127-65-1 纯度:98% 包装信息:100g,500g 价格:98.0元 - 240.0元
联系方式:
联系人:Yuki 电话:021-61845781 手机:13585604150

北京百灵威科技有限公司

产品介绍:
产品名称:氯胺T 418594 Cas号:127-65-1 纯度:98% 包装信息:5g,25g 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

湖北楚烁生物科技有限公司

产品介绍:
产品名称:氯胺 T Cas号:127-65-1 纯度:99% 包装信息:25kg 价格:100.0元
联系方式:
联系人:彭 电话:19107272069 手机:19107272069