水合三氯化铊(III)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

水合三氯化铊(III) 基本信息

中文名称:
水合三氯化铊(III) 
中文别名:
水合三氯化铊(III);
三氯化铊 
英文名称:
Thallium chloride(TlCl3), tetrahydrate (9CI)
英文别名:
Thallium chloride (TlCl3), tetrahydrate (9CI) 
CAS No.:
13453-33-3
分 子 式:

Cl3Tl.4H2O

分 子 量:
310.74
精确分子量:
381.92323
PSA:
0.00000
MDL:
MFCD00049600
EINECS:
236-625-2
危险品标志:

 

风险术语:

R33R26/28R51/53

安全术语:
S13S28S45S61
分子结构式:
SDS:
查看

水合三氯化铊(III) 制备方法及用途

合成制备方法

把Cl2气通入近沸的TlCl在少量水中的悬浮液,形成固态的Tl(Ⅰ)-Tl(Ⅲ)氯化物,它随后又溶解,继续通入氯气并在约65℃蒸发浓缩,得到细的无色针状TlCl3·4H2O。

水合三氯化铊(III) 物化性质

外观与性状:
白色粉末
熔点:
37ºC
沸点:
100ºC at 760 mmHg
蒸汽压:
24.5mmHg at 25°C
存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料 氧化物。

它在干燥空气中是稳定的且易溶于水(86.2g/100g水,17℃)。

其它信息:

1.       性状:白色粉末,单斜晶体

2.       密度(g/mL,25/4℃):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):37

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:易溶于水

水合三氯化铊(III) 安全信息

包装等级:
II
风险类别:
6.1
危险类别码:
R26/28
安全说明:
13-28-45-61
安全标志:
S13:远离食品、饮料和动物饲料。
S28:接触皮肤之后,立即使用大量皂液洗涤。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
S61:避免排放到环境中。参考专门的说明/安全数据表。
危险标志:
N: Dangerous for the environment;T+: Very toxic;

水合三氯化铊(III) 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

   在眼睛上面:刺激的影响;没有已知的敏化影响。
生态数据:

对水体是极其有害的,即使小量产品也不能接触地下水,水道或污水系统, 若无政府许可,勿将材料排入周围环境

水合三氯化铊(III) MSDS


Section 1: Product Identification
   Chemical Name:       Thallium (III) chloride hydrate (8% H2O)    
   CAS Registry Number:       13453-33-3    
   Formula:       TlCl3.XH2O    
   EINECS Number:
   Chemical Family:       metal halide    
   Synonym:       Thallic chloride, hexahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13453-33-3       100%       0.1mg/m3       0.1mg/m3    

Section 3: Hazards Identification
   Toxic by inhalation and if swallowed. Irritating to skin, eyes and respiratory tract. Danger of cumulative effects.
   Emergency Overview:
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Contact with eyes causes irritation, redness, and pain.    
   Skin Contact:       Causes irritation to skin. Symptoms include redness, itching, and pain, pimples, boils, hives and blisters.    
   Inhalation:       Toxic by inhalation. Irritating to the nose, mucous membranes and respiratory tract.    
   Toxic if swallowed. Ingestion of small amounts results in swelling of the feet and legs, mental confusion, pain,
   Ingestion:
   paralysis, and death.
   Toxic by inhalation and if swallowed. Acute poisoning results in swelling of the feet and legs, mental confusion,
   Acute Health Affects:
   angina-like pains, paralysis, weakness, and death.
   Danger of cumulative effects. Prolonged exposure to thallium compounds causes discoloration of the hair,
   Chronic Health Affects:
   which later falls out, joint pain, loss of appetite, fatigue, severe pain in the legs, albuminuria, and optic neuritis.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       None. Material is non-flammable.    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       none    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
   Spill and Leak Procedures:
   inert material and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store solid in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       solid may form a toxic fine dust. If possible, handle the solid in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       solid may form a toxic fine dust. If possible, handle the solid in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       310.73    
   Melting Point:       37°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals    
   Decomposition Products:       water, metal chloride    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Avoid release to groundwater or waterways. Toxic to aquatic organisms. May cause long-term adverse effects.
   Ecological Information:

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Thallium compounds, N.O.S.    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1707    
   Shipping Name (IATA):       Thallium compound, N.O.S.    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1707    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound: See Category Code N760 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

水合三氯化铊(III) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:309.880958 Da

8、标称质量:310 Da

9、平均质量:310.7423 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:4

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积1

7.重原子数量:5

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:5

推荐供应商更多供应商>>

江苏从众化工股份有限公司

产品介绍:
产品名称:水合三氯化铊(III) Cas号:13453-33-3 纯度:99% 包装信息:100kg 价格:100.0元
联系方式:
联系人:王 电话:13862111431 手机:13862111431

豆城化学产品商贸(天津)有限公司

产品介绍:
产品名称:三氯化铊 Cas号:13453-33-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:吴经理 电话:400-652-9210; 800-818-0078 手机:

北京浩克科技有限公司

产品介绍:
产品名称:水合三氯化铊(III) Cas号:13453-33-3 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:zhang 电话:86-10-52725121 手机:13401075458
QQ: 2241752642
微信二维码
电话: 19906633110