碘化铷

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

碘化铷 基本信息

中文名称:
碘化铷 
中文别名:
碘化铷;
碘酸铷 
英文名称:
Rubidium iodide (RbI)
英文别名:
Rubidium iodide;
rubidium(1+),iodide 
CAS No.:
7790-29-6
分 子 式:
IRb
分 子 量:
212.37
精确分子量:
211.81600
PSA:
0.00000
MDL:
MFCD00011192
EINECS:
232-198-1
InChI:
InChI=1/HI.Rb/h1H;/q;+1/p-1
安全术语:
S22;S24/25
分子结构式:
SDS:
查看

碘化铷 制备方法及用途

制备方法

主要通过碳酸铷与纯氢碘酸反应或Rb2SO4和相当量Ba(OH)2作用,再用HI中和生成的RbOH,至无碱性反应。为了得到碳酸铷纯品,将纯RbCl加过量草酸,在铂皿中强热,转变成碳酸盐。将此残渣溶于HI中,蒸发溶液至干,熔体应不显碱性。

合成制备方法

主要通过碳酸铷与纯氢碘酸反应或Rb2SO4和相当量Ba(OH)2作用,再用HI中和生成的RbOH,至无碱性反应。

为了得到碳酸铷纯品,将纯RbCl加过量草酸,在铂皿中强热,转变成碳酸盐。将此残渣溶于HI中,蒸发溶液至干,熔体应不显碱性。

用途简介

制药。

用途

制药。

碘化铷 物化性质

外观与性状:
白色立方体晶体
密度:
3.55 g/mL at 25 °C(lit.)
熔点:
642 °C
沸点:
1300 °C
闪点:
1300°C
水溶解性:
152 g/100 mL (17 ºC)
折射率:
1.6474
存储条件/存储方法:

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

稳定性相关:

如果遵照规格使用和储存则不会分解

避免接触光,水分/潮湿。RbI在空气中稳定。易溶于水,100g水溶解152g(17.4℃)。吸水性强,在氢气氛下于120~130℃干燥,并保存于P2O5上。

其它信息:

1.      性状:白色结晶或结晶性粉末。

碘化铷 安全信息

WGK_Germany:
2
德国有关水污染物质的分类清单
安全说明:
S22-S24/25
RTECS号:
VL8925000
安全标志:
S22:不要吸入粉尘。
S24/25:防止皮肤和眼睛接触。

碘化铷 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VL8925000
CHEMICAL NAME :
Rubidium iodide
CAS REGISTRY NUMBER :
7790-29-6
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
I-Rb
MOLECULAR WEIGHT :
212.37

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4708 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: TR-74,1,1972 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4533 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 7 (estimated)
毒理学数据:

低毒,半数致死量(大鼠,经口)4708mg/kg。

生态数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境

碘化铷 MSDS

Name: Rubidium Iodide 99.9% Material Safety Data Sheet
Synonym: None known
CAS: 7790-29-6
Section 1 - Chemical Product   MSDS Name:Rubidium Iodide 99.9% Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7790-29-6 Rubidium iodide 99.9 232-198-1
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. May cause kidney damage. Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion of iodides during pregnancy has resulted in fetal death, severe goiter, and cretinoid appearance of the newborn..
Prolonged exposure to iodides may produce iodism in sensitive individuals. Symptoms could include skin rash, running nose and headache. May cause kidney damage.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture. Store protected from light.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7790-29-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 1 mm Hg @748C
Viscosity: Not available.
Boiling Point: 1300 deg C
Freezing/Melting Point: 642 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 3.55
Molecular Formula: IRb
Molecular Weight: 212.37

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, ammonia and/or derivatives, iodine, rubidium oxides.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7790-29-6: VL8925000 LD50/LC50:
CAS# 7790-29-6: Oral, rat: LD50 = 4708 mg/kg; Oral, rat: LD50 = 4708 mg/kg.
Carcinogenicity:
Rubidium iodide - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7790-29-6: 1
Canada
CAS# 7790-29-6 is listed on Canada's NDSL List.
CAS# 7790-29-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7790-29-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

碘化铷 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:2

8.表面电荷:0

9.复杂度:2

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:2

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