3 -氮杂双环[3.2.2]壬烷

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 上游产品
  • 下游产品

3 -氮杂双环[3.2.2]壬烷 基本信息

中文名称:
3 -氮杂双环[3.2.2]壬烷 
中文别名:
3-氮杂双环(3.2.2)壬烷;
3-氮杂双环[3.2.2]壬烷 
英文名称:
3-Azabicyclo[3.2.2]nonane
英文别名:
3-azabicyclo[3.2.2]nonane;
3-AZABICYCLO(3.2.2)NONANE;
Adamantane;
1,4-Diazabicyclo(2.2.2)octane;
Diazabicyclooctane;
Triethylene Diamine;
1-cyclooctyl-1,4-diazocane;
1,4-Diazabicyclo[2,2,2]-octane;
1,4-Diazabicyclo[2.2.2]octane;
三乙基二胺;
1,4-二氮杂二环[2.2.2]辛烷;
benzoxazol;
benzoxazole;
Phenoxathrin;
Phenoxthin;
USAF DO-17;
Dibenzooxathiane;
phenoxathiine;
vulkacitzm;
zenite;
zenitespecial;
zinc2-benzothiazolethiolate;
zincbenzothiazol-2-ylthiolate;
zinc bis(1,3-benzothiazole-2-thiolate);
2-benzothiazolethiol, zinc salt (1:1);
Rubber Accelerator ZMBT;
Rubber Accelerator MZ;
Accelerator MZ;
ACCELERATOR ZMBT;
ACCELERATOR ZMBT(MZ);
zinc di(benzothiazol-2-yl) disulphide;
Solfametopirazina;
Solfametopirazina [DCIT];
Sulfalen;
Sulfaleno;
Sulfaleno [INN-Spanish];
Sulfalenum;
Sulfalenum [INN-Latin];
Sulfamethopyrazine;
Sulfamethox;
Sulfalene;
Daltolite fast blue B;
Duratint blue 1001;
EM blue NCB;
eta-Copper phthalocyanine;
Euvinyl blue 702;
Fast;
Pigment Blue 15:3;
Erythromycin 
CAS No.:
283-24-9
分 子 式:
C8H15N
分 子 量:
125.24
精确分子量:
125.12000
PSA:
12.03000
InChI:
InChI=1/C8H15N/c1-2-8-4-3-7(1)5-9-6-8/h7-9H,1-6H2
安全术语:
Poison by intravenous route. When heated to decomposition it emits toxic vapors of NOx.
分子结构式:
SDS:
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3 -氮杂双环[3.2.2]壬烷 物化性质

密度:
0.915g/cm3
沸点:
188.3ºC at 760mmHg
闪点:
60.8ºC
折射率:
1.472
蒸汽压:
0.604mmHg at 25°C

3 -氮杂双环[3.2.2]壬烷 安全信息

包装等级:
II
海关代码:
2933990090

3 -氮杂双环[3.2.2]壬烷 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CL5447500
CHEMICAL NAME :
3-Azabicyclo(3.2.2)nonane
CAS REGISTRY NUMBER :
283-24-9
BEILSTEIN REFERENCE NO. :
0878218
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C8-H15-N
MOLECULAR WEIGHT :
125.24

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01357

3 -氮杂双环[3.2.2]壬烷 MSDS

Name: 3-Azabicyclo3.2.2nonane 99+% (gc) Material Safety Data Sheet
Synonym: None known
CAS: 283-24-9
Section 1 - Chemical Product   MSDS Name:3-Azabicyclo3.2.2nonane 99+% (gc) Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
283-24-9 3-Azabicyclo3.2.2-Nonane >99 unlisted
Hazard Symbols: None Listed.
Risk Phrases: 10

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression.
Inhalation:
The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable solid.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 283-24-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Sublimes
Freezing/Melting Point: 163 deg C
Autoignition Temperature: Not available.
Flash Point: 63 deg C ( 145.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H15N
Molecular Weight: 125.21

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 283-24-9: CL5447500 LD50/LC50:
Not available.
Carcinogenicity:
3-Azabicyclo3.2.2-Nonane - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 283-24-9: No information available.
Canada
CAS# 283-24-9 is listed on Canada's NDSL List.
CAS# 283-24-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 283-24-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3 -氮杂双环[3.2.2]壬烷 海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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