氟硼酸锌

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

氟硼酸锌 基本信息

中文名称:
氟硼酸锌 
中文别名:
氟硼酸锌;
硼氟酸锌;
四氟硼酸(1-)锌(2:1) 
英文名称:
Borate(1-),tetrafluoro-, zinc (2:1)
英文别名:
Borate(1-), tetrafluoro-, zinc (2:1);
Borate(1-), tetrafluoro-, zinc (8CI);
Zinc fluoborate (Zn(BF4)) (6CI);
Zinc bis(tetrafluoroborate);
Zinc borofluoride;
Zinc borofluoride [Zn(BF4)2];
Zinc fluoroborate;
Zinc tetrafluoroborate;
Zinc tetrafluoroborate (Zn(BF4)2);
Zinc(2+) bis[tetrafluoroborate(1-)];
Zinc(II) fluoborate 
CAS No.:
13826-88-5
分 子 式:
BF4.1/2Zn
分 子 量:
238.98
精确分子量:
237.93498
PSA:
0.00000
EINECS:
237-534-0
InChI:
InChI=1/BFO2.Zn/c2-1(3)4;/q-2;+2
危险品标志:
C:Corrosive
风险术语:
R34;
安全术语:
S26; S36/37/39; S45;
分子结构式:
SDS:
查看

氟硼酸锌 制备方法及用途

制备方法

在耐洗和耐磨纺织品中用作树脂固化剂,织物树脂后整理及合成树脂生产的催化剂。也可作阻燃剂、杀虫剂、电焊材料、电镀液及钴的接合剂。

用途简介

氟硼酸锌 物化性质

外观与性状:
透明无色溶液
密度:
1.43
存储条件/存储方法:
库房通风低温干燥,与酸类、食品添加剂分开存放

氟硼酸锌 安全信息

危险类别码:
R34
安全说明:
S26-S36/37/39-S45
危险标志:
C:Corrosive;

氟硼酸锌 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED3170000
CHEMICAL NAME :
Borate(1-), tetrafluoro-, zinc
CAS REGISTRY NUMBER :
13826-88-5
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
B2-F8.Zn

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,28,1953 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1736 No. of Facilities: 11 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 11 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1736 No. of Facilities: 15 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 4757 (estimated) No. of Female Employees: 261 (estimated)

氟硼酸锌 MSDS

Name: Zinc tetrafluoroborate 50% solution Material Safety Data Sheet
Synonym:
CAS: 13826-88-5
Section 1 - Chemical Product   MSDS Name:Zinc tetrafluoroborate 50% solution Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13826-88-5 Zinc tetrafluoroborate 50% 237-534-0
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use dry chemical to fight fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 13826-88-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless
Odor: odorless
pH: 4.5 - 6.5
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.430
Molecular Formula: B2F8Zn
Molecular Weight: 238.9872

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 13826-88-5: ED3170000 LD50/LC50:
Not available.
Carcinogenicity:
Zinc tetrafluoroborate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13826-88-5: No information available.
Canada
CAS# 13826-88-5 is listed on Canada's NDSL List.
CAS# 13826-88-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13826-88-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氟硼酸锌 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:10

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积:0

7.重原子数量:11

8.表面电荷:0

9.复杂度:19.1

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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产品介绍:
产品名称:氟硼酸锌 Cas号:13826-88-5 纯度:0-99% 包装信息:1kg,25kg,200kg,400kg,500kg 价格:洽谈
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