乙基橙

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

乙基橙 基本信息

中文名称:
乙基橙 
中文别名:
乙基橙;
5-Iodo-2,4-dichloropyrimidine;
6-(trifluoromethyl)-1H-indole;
6-Trifluoromethylindole;
6-(Trifluoromethyl)indole;
iron(3+) triperchlorate;
3-Amino-5-bromopyridine;
Methyl-3-(methylthio) propionate;
Methyl 3-(methylthio)propionate;
N-(2-Aminoethyl)-1,3-propanediamine;
5-21-03-00017 (Beilstein Handbook Reference);
BRN 1536506;
Betapindol;
Blocklin L;
CCRIS 9215;
Calvisken;
Carvisken;
Decreten;
Durapindol;
Glauco-Viskin;
HSDB  
英文名称:
Benzenesulfonic acid,4-[2-[4-(diethylamino)phenyl]diazenyl]-, potassium salt (1:1)
英文别名:
ETHYL ORANGE;
ethyloleyl ether;
1-ethoxy-octadec-9c-ene;
Aethyloleylaether;
Ethylorange 
CAS No.:
13545-67-0
分 子 式:
C16H19N3O3S.K
分 子 量:
371.50
精确分子量:
332.10700
PSA:
93.54000
MDL:
MFCD00007503
EINECS:
236-916-4
InChI:
InChI=1/C16H19N3O3S/c1-3-19(4-2)15-9-5-13(6-10-15)17-18-14-7-11-16(12-8-14)23(20,21)22/h5-12H,3-4H2,1-2H3,(H,20,21,22)/p-1/b18-17+
风险术语:
R36/37/38
安全术语:
S24/25;
分子结构式:
SDS:
查看

乙基橙 物化性质

存储条件/存储方法:

常温密闭,阴凉通风干燥

稳定性相关:

常温常压下稳定

避免的物料 氧化物
其它信息:

1.       性状:橙色固体

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):101-105

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

乙基橙 安全信息

海关代码:
2927000090
安全说明:
S24/25
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S37:使用合适的防护手套。

乙基橙 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜;

在眼睛上面:刺激的影响;没有已知的敏化影响。

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

乙基橙 MSDS

Name: Ethyl orange indicator grade Material Safety Data Sheet
Synonym: 4-[p-(Diethylamino)phenylazo]benzenesulfonic aci
CAS: 13545-67-0
Section 1 - Chemical Product   MSDS Name:Ethyl orange indicator grade Material Safety Data Sheet
Synonym:4-[p-(Diethylamino)phenylazo]benzenesulfonic aci

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
13545-67-0 Ethyl orange, indicator grade 236-916-4
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 13545-67-0: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: red to brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C16H19N3O3S
Molecular Weight: 333.39

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 13545-67-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl orange, indicator grade - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 13545-67-0: No information available.
Canada
CAS# 13545-67-0 is listed on Canada's NDSL List.
CAS# 13545-67-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13545-67-0 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

乙基橙 海关数据

中国海关编码:2927000090

概述:
2927000090 其他重氮化合物、偶氮化合物等(包括氧化偶氮化合物). 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

乙基橙 分子结构与计算化学数据

计算化学数据

1、   氢键供体数量:0

2、   氢键受体数量:6

3、   可旋转化学键数量:6

4、   拓扑分子极性表面积(TPSA):85.2

5、   重原子数量:24

6、   表面电荷:0

7、   复杂度:475

8、   同位素原子数量:0

9、   确定原子立构中心数量:0

10、   不确定原子立构中心数量:0

11、   确定化学键立构中心数量:0

12、   不确定化学键立构中心数量:0

13、   共价键单元数量:2

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