4-苯甲氧基苯基乙腈

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

4-苯甲氧基苯基乙腈 基本信息

中文名称:
4-苯甲氧基苯基乙腈 
中文别名:
4-苄氧基苯基乙腈;
4-苯甲氧基苯基乙腈 
英文名称:
Benzeneacetonitrile,4-(phenylmethoxy)-
英文别名:
4-Benzyloxyphenylacetonitrile;
2-(4-phenylmethoxyphenyl)acetonitrile 
CAS No.:
838-96-0
分 子 式:
C15H13NO
分 子 量:
223.27
精确分子量:
223.10000
PSA:
33.02000
MDL:
MFCD00016400
EINECS:
000-000-0
BRN:
2377584
InChI:
InChI=1/C15H13NO/c16-11-10-13-6-8-15(9-7-13)17-12-14-4-2-1-3-5-14/h1-9H,10,12H2
风险术语:
R22;
安全术语:
S22; S36/37;
分子结构式:
SDS:
查看

4-苯甲氧基苯基乙腈 物化性质

外观与性状:
奶油色粉末
密度:
1.114g/cm3
熔点:
65 °C
沸点:
170-173°C 0,1mm
闪点:
170-173°C/0.1mm
折射率:
1.582
存储条件/存储方法:

保持容器密封,储存在阴凉,干燥的地方 

稳定性相关:

 常温常压下稳定,避免氧化剂  酸接触

其它信息:

1.      性状:未确定

2.      密度(g/mL,25/4):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):65 °C

5.      沸点(ºC,常压):未确定

6.      沸点(ºC, 0,1mmHg):170-173°C

7.      折射率:未确定

8.      闪点(ºC0,1mmHg):170-173°C

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

4-苯甲氧基苯基乙腈 安全信息

包装等级:
III
风险类别:
6.1
海关代码:
2926909090
危险类别码:
R22
安全说明:
S26-S36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S36:穿戴合适的防护服装。
:
危险标志:
Xi: Irritant;

4-苯甲氧基苯基乙腈 毒理性

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

4-苯甲氧基苯基乙腈 MSDS

  Material Safety Data Sheet

Section 1. Identification of the substance
    Product Name:      4-Benzyloxyphenylacetonitrile    
    Synonyms:

Section 2. Hazards identification
    Harmful by inhalation, in contact with skin, and if swallowed.
    H302:        Harmful if swallowed    
    H312:        Harmful in contact with skin    

Section 3. Composition/information on ingredients.
    Ingredient name:        4-Benzyloxyphenylacetonitrile    
    CAS number:        838-96-0    

Section 4. First aid measures
    Immediately wash skin with copious amounts of water for at least 15 minutes while removing
    Skin contact:
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate    
    flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.    
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.    

Section 5. Fire fighting measures
    In the event of a fire involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator    
    Hand precaution:        Wear suitable gloves/gauntlets    
    Skin protection:        Wear suitable protective clothing    
    Eye protection:        Wear suitable eye protection    
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly qualified    
    in the handling and use of potentially hazardous chemicals, who should take into account the fire,
    health and chemical hazard data given on this sheet.
    Storage:        Store in closed vessels.    

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Not specified
    Appearance:
    Boiling point:        No data    
    Melting point:        No data    
    Flash point:        No data    
    Density:        No data    
    Molecular formula:        C15H13NO    
    Molecular weight:        223.3    

Section 10. Stability and reactivity
    Conditions to avoid: Heat, flames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section 11. Toxicological information
    No data.

Section 12. Ecological information
    No data.

Section 13. Disposal consideration
    Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
    disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
    Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-苯甲氧基苯基乙腈 海关数据

中国海关编码:2926909090

概述:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

4-苯甲氧基苯基乙腈 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:66.88

2、   摩尔体积(m3/mol):200.3

3、   等张比容(90.2K):520.9

4、   表面张力(dyne/cm):45.7

5、   介电常数(F/m):

6、   偶极距(D):

7、   极化率10-24cm3):26.51

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:4

5.互变异构体数量:无

6.拓扑分子极性表面积33

7.重原子数量:17

8.表面电荷:0

9.复杂度:253

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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