间-四苯基卟吩-Μ-氧化铁二聚体

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 下游产品

间-四苯基卟吩-Μ-氧化铁二聚体 基本信息

中文名称:
间-四苯基卟吩-Μ-氧化铁二聚体 
中文别名:
间-四苯基卟吩-Μ-氧化铁二聚体;
间-四苯基卟吩氧化铁(III)二聚体;
间-四苯基卟吩-氧化铁(III)二聚体;
间-四苯基卟吩-μ-氧化铁(III)二聚体 
英文名称:
iron (iii) meso-tetraphenylporphine-mu-oxo dimer
英文别名:
IRON (III) MESO-TETRAPHENYLPORPHINE-μ-OXO DIMER;
IRON(III) MESO-TETRAPHENYLPORPHINE-M-OXO DIMER;
Ironmesotetraphenylporphineoxodimerpurplextl;
[Fe(TPP)]2O;
iron(iii) meso-tetraphenylporphine-ae-oxo dimer;
meso-5,10,15,20-Tetraphenyl-21H,23H-porphine iron u-oxo dimer;
Iron(III)meso-tetraphenylporphine-oxodimer;
micro;
Iron(III) meso-tetraphenylporphine-mu-oxo dimer;
IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER 
CAS No.:
12582-61-5
分 子 式:

C88H56Fe2N8O

分 子 量:
1353.16
精确分子量:
1352.33000
PSA:
78.39000
MDL:
MFCD00058898
InChI:
The Key: WCKRZSMOZMPKRU-QJIBVACRSA-N
危险品标志:

 

风险术语:

 

安全术语:

S24/25

分子结构式:
SDS:
查看

间-四苯基卟吩-Μ-氧化铁二聚体 物化性质

存储条件/存储方法:

常温密闭避光,通风干燥处

稳定性相关:

常温常压下稳定

避免的物料 氧化物

其它信息:

1.      性状:紫色晶体

2.      密度(g/mL,25):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):未确定

6.      沸点(ºC0.05mmHg):未确定

7.      折射率:未确定

8.      闪点(ºC):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(20ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

间-四苯基卟吩-Μ-氧化铁二聚体 安全信息

安全说明:
24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

间-四苯基卟吩-Μ-氧化铁二聚体 毒理性

毒理学数据:

主要的刺激性影响:

在皮肤上面:可能引起发炎

在眼睛上面:可能引起发炎

致敏作用:没有已知的敏化现象

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

间-四苯基卟吩-Μ-氧化铁二聚体 MSDS


Section 1: Product Identification
   Chemical Name:       Iron (III) meso-tetraphenylporphine -|mu|-oxo dimer    
   CAS Registry Number:       12582-61-5    
   Formula:       [(C44H28N4)Fe]2O    
   EINECS Number:       None    
   Chemical Family:       metal porphine (porphyrin) complex    
   Synonym:       Ferric meso-tetraphenylporphine--oxo dimer    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12582-61-5       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       No particular hazard associated with this material. May be irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       May be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes and respiratory tract.    
   The toxicological properties of this compound have not been thoroughly investigated. Unrecognized hazards
   Chronic Health Affects:
   may be present.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       purple xtl.    
   Molecular Weight:       1353.16    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       Insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes, and iron oxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data    
   Mutagenic Effects:       No data    
   Tetratogenic Effects:       No data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       None    


SECTION 16 - ADDITIONAL INFORMATION
N/A

间-四苯基卟吩-Μ-氧化铁二聚体 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:1352.327592Da

8、标称质量:1352Da

9、平均质量:1353.1292Da

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