六氟乙酰丙酮化钇

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

六氟乙酰丙酮化钇 基本信息

中文名称:
六氟乙酰丙酮化钇 
中文别名:
六氟乙酰丙酮化钇;
六氟-乙酰丙酮钇;
六氟-乙酰丙酮钇(III) 
英文名称:
Yttrium,tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-kO2,kO4)-, (OC-6-11)-
英文别名:
1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,yttrium(3+);
YTTRIUM(III) HEXAFLUORO-2,4-PENTANEDIONATE;
YTTRIUM(III)HEXAFLUOROACETYLACETONATE;
YTTRIUM HEXAFLUOROPENTANEDIONATE;
YTTRIUM HEXAFLUOROACETYLACETONATE;
Yttrium(III)hexafluoroacetylacetonate(99.9%-Y)(REO);
Yttrium(lll) hexafluoroacetylacetonate;
Yttrium hexafluoroacetylacetonate 98%;
Yttriumhexafluoroacetylacetonate98% 
CAS No.:
18911-76-7
分 子 式:
C15H3F18O6Y
分 子 量:
710.06
精确分子量:
709.87000
PSA:
78.90000
MDL:
MFCD00064764
危险品标志:
IrritantXi
风险术语:
R36/37/38
安全术语:
S26;S36/37/39
分子结构式:
SDS:
查看

六氟乙酰丙酮化钇 制备方法及用途

制备方法

将按反应摩尔比计算量的六氟乙酰丙酮铵的乙醚溶液与氯化钇的水溶液混合并搅拌。得到的六氟乙酰丙酮钇螯合物进入乙醚层中。乙醚溶液用无水硫酸钠干燥后,蒸去乙醚,得到粗产品。可用水 甲醇(9∶1)混合溶剂重结晶纯化。得到的纯品很可能是六氟乙酰丙酮钇的二水合物。若将上述产品在P2O5存在下,于室温及3Pa压力下干燥72h,可得到无水的六氟乙酰丙酮钇。

合成制备方法

将按反应摩尔比计算量的六氟乙酰丙酮铵的乙醚溶液与氯化钇的水溶液混合并搅拌。得到的六氟乙酰丙酮钇螯合物进入乙醚层中。乙醚溶液用无水硫酸钠干燥后,蒸去乙醚,得到粗产品。可用水甲醇(9∶1)混合溶剂重结晶纯化。得到的纯品很可能是六氟乙酰丙酮钇的二水合物。若将上述产品在P2O5存在下,于室温及3Pa压力下干燥72h,可得到无水的六氟乙酰丙酮钇。

用途简介

六氟乙酰丙酮化钇 物化性质

熔点:
166-170ºC
沸点:
240ºC
闪点:
22.8ºC
蒸汽压:
10.3mmHg at 25°C
存储条件/存储方法:

常温密闭避光,通风干燥

稳定性相关:

常温常压下稳定

避免的物料:氧化物。溶于乙醚、甲醇中。

其它信息:

1.       性状:白色晶体。

2.       密度(g/mL,25/4℃):不确定

3.       相对蒸汽密度(g/mL,空气=1):不确定

4.       熔点(ºC):142~144

5.       沸点(ºC,常压):240

6.       沸点(ºC, 5.2kPa):不确定

7.       折射率:不确定

8.       闪点(ºC):不确定

9.       比旋光度(º):不确定

10.    自燃点或引燃温度(ºC):不确定

11.    蒸气压(kPa,25ºC):不确定

12.    饱和蒸气压(kPa,60ºC):不确定

13.    燃烧热(KJ/mol):不确定

14.    临界温度(ºC):不确定

15.    临界压力(KPa):不确定

16.    油水(辛醇/水)分配系数的对数值:不确定

17.    爆炸上限(%,V/V):不确定

18.    爆炸下限(%,V/V):不确定

19.    溶解性:不确定

六氟乙酰丙酮化钇 安全信息

危险类别码:
R36/37/38
安全说明:
S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi:Irritant;

六氟乙酰丙酮化钇 毒理性

生态数据:

通常对水体是稍微有害的,不要将未稀释或大量产品接触地下水,水道或污水系统,未经政府许可勿将材料排入周围环境。

六氟乙酰丙酮化钇 MSDS


Section 1: Product Identification
   Chemical Name:       Yttrium hexafluoroacetylacetonate, hydrate (99.9%-Y) (REO)    
   CAS Registry Number:       18911-76-7    
   Formula:       Y(CF3COCHCOCF3)3.XH2O    
   EINECS Number:       none    
   Chemical Family:       metal fluorobeta-diketonate complexes    
   Synonym:       Yttrium(III) hexafluoro 2,4-pentanedionate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       18911-76-7       100%       1mg/m3 as Y       1mg/m3 as Y    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes slight to mild irritation of the eyes    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate
   Chronic Health Affects:       fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth    
   structure, kidney and liver damage.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a sealed container. Keep away from heat and moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl    
   Molecular Weight:       710.1    
   Melting Point:       166-170°    
   Boiling Point:       240°Cdec(subl.100°/.2mm)    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       halogens and oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide, yttrium oxide, fluorinated organics and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available.    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

六氟乙酰丙酮化钇 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:24

4.可旋转化学键数量:3

5.互变异构体数量:无

6.拓扑分子极性表面积120

7.重原子数量:40

8.表面电荷:0

9.复杂度:210

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:3

15.共价键单元数量:4

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