4-溴-2,5-二氯噻酚-3-磺酰氯

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

4-溴-2,5-二氯噻酚-3-磺酰氯 基本信息

中文名称:
4-溴-2,5-二氯噻酚-3-磺酰氯 
中文别名:
4-溴-2,5-二氯噻酚-3-磺酰氯;
4-溴-2,5-二氯噻吩-3-磺酰氯;
4-溴-2,5-二氯硫代苯-3-磺酰氯 
英文名称:
3-Thiophenesulfonylchloride, 4-bromo-2,5-dichloro-
英文别名:
4-BROMO-2,5-DICHLOROTHIOPHENE-3-SULFONYL CHLORIDE;
4-Bromo-2,5-dichloro-3-thiophenesulfonyl chloride;
4-Bromo-2,5-dichlorothiophene-3-sulfonyl chloride;
4-Bromo-2,5-dichlorothiophene-3-sulphonyl chloride 
CAS No.:
166964-36-9
分 子 式:

C4BrCl3O2S2

分 子 量:
330.44
精确分子量:
327.75900
PSA:
70.76000
MDL:
MFCD00051664
危险品标志:


CorrosiveC

风险术语:

R14;R34;

安全术语:
S8;S20;S26;S30;S36/37/39;S45;S60;
分子结构式:
SDS:
查看

4-溴-2,5-二氯噻酚-3-磺酰氯 物化性质

密度:
2.122g/cm3
熔点:
70-72ºC
沸点:
119-121ºC 1mm
闪点:
119-121°C/1mm
折射率:
1.637
蒸汽压:
1.81E-05mmHg at 25°C
存储条件/存储方法:

保存方法:密闭,阴凉,通风干燥处

稳定性相关:

避氧化物、水分

其它信息:

1.      性状:白色晶体状的粉末

2.      密度(g/mL,20):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):66-71

5.      沸点(ºC,常压):未确定

6.      沸点(ºC  mm):119-121

7.      折射率:未确定

8.      闪点(ºC):119-121

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

4-溴-2,5-二氯噻酚-3-磺酰氯 安全信息

包装等级:
II
海关代码:
2934999090
危险类别码:
R14
安全说明:
S8
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S30:千万不可将水加入此产品。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
S60:本物质残余物和容器必须作为危险废物处理。
:
危险标志:
C:Corrosive;

4-溴-2,5-二氯噻酚-3-磺酰氯 毒理性

生态数据:

1、其它有害作用:通常对水稍微危害的,若无政府许可,勿将材料排入周围环境。

4-溴-2,5-二氯噻酚-3-磺酰氯 MSDS

Name: 4-Bromo-2 5-dichlorothiophene-3-sulfonyl chloride 97% Material Safety Data Sheet
Synonym:
CAS: 166964-36-9
Section 1 - Chemical Product   MSDS Name:4-Bromo-2 5-dichlorothiophene-3-sulfonyl chloride 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
166964-36-9 4-Bromo-2,5-dichlorothiophene-3-sulfon 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 166964-36-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 115 deg C @0.6mmHg
Freezing/Melting Point: 70 - 72 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4BrCl3O2S2
Molecular Weight: 330

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 166964-36-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Bromo-2,5-dichlorothiophene-3-sulfonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 166964-36-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 166964-36-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 166964-36-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-溴-2,5-二氯噻酚-3-磺酰氯 海关数据

中国海关编码:2934999090

概述:
2934999090. 其他杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-溴-2,5-二氯噻酚-3-磺酰氯 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):4.2

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积70.8

7.重原子数量:12

8.表面电荷:0

9.复杂度:264

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:4-溴-2,5-二氯噻吩-3-磺酰氯 Cas号:166964-36-9 纯度:97% 包装信息:1g 价格:239.0元
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