3,4-二氢-2H-1,5-苯并二氧-7-胺

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

3,4-二氢-2H-1,5-苯并二氧-7-胺 基本信息

中文名称:
3,4-二氢-2H-1,5-苯并二氧-7-胺 
中文别名:
3,4-二氢-2H-1,5-苯并二氧-7-胺;
7-氨基-3,4-二氢-2H-1,5-苯并二氧杂环庚;
3,4-二氢-7-氨基-2H-苯并[1,4]二氧庚烷;
3,4-二氢--1,5-苯并二氧-EPIN-7-胺;
3,4-二氢-2H-1,5-苯并二氧环丙-7-胺;
7-氨基-3,4-二氢-2H-1,5-苯并二氧杂卓 
英文名称:
2H-1,5-Benzodioxepin-7-amine,3,4-dihydro-
英文别名:
3,4-DIHYDRO-2H-1,5-BENZODIOXEPIN-7-AMINE;
3,4-dihydro-7-amino-2H-1,5-benzo[b][1,4]dioxepin;
2H,3H,4H-benzo[b]1,4-dioxepin-7-ylamine;
3,4-Dihydro-2H-benzo[b][1,4]dioxepin-7-ylamin;
7-Amino-3,4-dihydro 2H-1,5-benzodioxepin;
3,4-dihydro-2H-benzo[b][1,4]dioxepin-7-ylamine 
CAS No.:
175136-34-2
分 子 式:
C9H11NO2
分 子 量:
165.19
精确分子量:
165.07900
PSA:
44.48000
InChI:
InChI=1/C9H11NO2/c10-7-2-3-8-9(6-7)12-5-1-4-11-8/h2-3,6H,1,4-5,10H2
危险品标志:
Xi:Irritant
风险术语:
R36/37/38
安全术语:
S26;S36/37/39
分子结构式:
SDS:
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3,4-二氢-2H-1,5-苯并二氧-7-胺 物化性质

密度:
1.193g/cm3
熔点:
81ºC
沸点:
123-128ºC/0.2mm
闪点:
152.4°C
折射率:
1.577
蒸汽压:
0.000728mmHg at 25°C
存储条件/存储方法:

保存方法:密闭,阴凉,通风干燥处

稳定性相关:

避氧化物

其它信息:

1.      性状:白色或黄色的晶体

3,4-二氢-2H-1,5-苯并二氧-7-胺 安全信息

海关代码:
2932999099
危险类别码:
R36/37/38
安全说明:
S26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi:Irritant;

3,4-二氢-2H-1,5-苯并二氧-7-胺 毒理性

生态数据:

1、其它有害作用:通常对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

3,4-二氢-2H-1,5-苯并二氧-7-胺 MSDS

Name: 3 4-Dihydro-2H-1 5-benzodioxepin-7-amine 97% Material Safety Data Sheet
Synonym: 3,4-Trimethylenedioxyanilin
CAS: 175136-34-2
Section 1 - Chemical Product   MSDS Name:3 4-Dihydro-2H-1 5-benzodioxepin-7-amine 97% Material Safety Data Sheet
Synonym:3,4-Trimethylenedioxyanilin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
175136-34-2 3,4-Dihydro-2H-1,5-benzodioxepin-7-ami 97% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 175136-34-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 76 - 78 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H11NO2
Molecular Weight: 165

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, acid chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 175136-34-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,4-Dihydro-2H-1,5-benzodioxepin-7-amine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 175136-34-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 175136-34-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 175136-34-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3,4-二氢-2H-1,5-苯并二氧-7-胺 海关数据

中国海关编码:2932999099

概述:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

3,4-二氢-2H-1,5-苯并二氧-7-胺 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:1

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积44.5

7.重原子数量:12

8.表面电荷:0

9.复杂度:152

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

3,4-二氢-2H-1,5-苯并二氧-7-胺 上游产品

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产品名称:3,4-二氢-2H-1,5-苯并二氧环丙-7-胺 Cas号:175136-34-2 纯度:98% 包装信息:250mgea 价格:1,262.0元
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