1-甲基吡咯-2-羰酰氯

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

1-甲基吡咯-2-羰酰氯 基本信息

中文名称:
1-甲基吡咯-2-羰酰氯 
中文别名:
1-甲基-1H-吡咯-2-羰酰氯;
1-甲基吡咯-2-羰酰氯 
英文名称:
1H-Pyrrole-2-carbonylchloride, 1-methyl-
英文别名:
1-METHYLPYRROLE-2-CARBONYL CHLORIDE;
1-methylpyrrol-2-carboxylic acid chloride;
1-methyl-pyrrole-2-carboxylic acid chloride;
N-methylpyrrole-2-carbonyl chloride;
1-methyl-2-pyrrole-carbonyl chloride;
1-methy-1H-pyrrole-2-carbonyl chloride;
1-methyl-2-pyrrolecarboxylic acid chloride;
1-methyl-1H-pyrrole-2-carbonyl chloride 
CAS No.:
26214-68-6
分 子 式:
C6H6ClNO
分 子 量:
143.57
精确分子量:
143.01400
PSA:
22.00000
MDL:
MFCD02094021
BRN:
472022
InChI:
InChI=1/C6H6ClNO/c1-8-4-2-3-5(8)6(7)9/h2-4H,1H3
危险品标志:
C:Corrosive
风险术语:
R34;
安全术语:
S26; S36/37/39; S45;
分子结构式:
SDS:
查看

1-甲基吡咯-2-羰酰氯 物化性质

密度:
1.22g/cm3
沸点:
78ºC (15 mmHg)
闪点:
79ºC
折射率:
1.544
蒸汽压:
0.231mmHg at 25°C
存储条件/存储方法:

干性的保护气体下处置,

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方
稳定性相关:

如果遵照规格使用和储存则不会分解

避免接触氧化物,水分/潮湿,碱,热

其它信息:

1.       性状: 未确定

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):78

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):72-74

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

1-甲基吡咯-2-羰酰氯 安全信息

包装等级:
II
海关代码:
2933990090
危险类别码:
R14;R29;R34
安全说明:
S23-S26-S30-S36/37/39-S45-S8
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
C:Corrosive;

1-甲基吡咯-2-羰酰氯 毒理性

生态数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境

1-甲基吡咯-2-羰酰氯 MSDS

Name: 1-Methyl-1H-pyrrole-2-carbonyl chloride 97% Material Safety Data Sheet
Synonym:
CAS: 26214-68-6
Section 1 - Chemical Product   MSDS Name:1-Methyl-1H-pyrrole-2-carbonyl chloride 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
26214-68-6 1-Methyl-1H-pyrrole-2-carbonyl chlorid 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area. Store under an inert atmosphere.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 26214-68-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 84 deg C @15mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H6ClNO
Molecular Weight: 143.57

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 26214-68-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methyl-1H-pyrrole-2-carbonyl chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 26214-68-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 26214-68-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 26214-68-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

1-甲基吡咯-2-羰酰氯 海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

1-甲基吡咯-2-羰酰氯 分子结构与计算化学数据

分子结构数据

1   摩尔折射率:36.86

2   摩尔体积m3/mol116.8

3   等张比容(90.2K):292.3

4   表面张力dyne/cm39.1

5   极化率10-24cm314.61

 

计算化学数据

1.疏水参数计算参考值(XlogP):1.5

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:1

5.互变异构体数量:无

6.拓扑分子极性表面积22

7.重原子数量:9

8.表面电荷:0

9.复杂度:126

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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产品介绍:
产品名称:1-甲基-1H-吡咯-2-羰酰氯 Cas号:26214-68-6 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶 价格:1.0元 - 25.0元
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产品名称:1-甲基-1H-吡咯-2-酰氯 Cas号:26214-68-6 纯度: 包装信息:洽谈 价格:洽谈
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