羰基(五甲基环茂二烯基)钼二聚合物

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

羰基(五甲基环茂二烯基)钼二聚合物 基本信息

中文名称:
羰基(五甲基环茂二烯基)钼二聚合物 
中文别名:
羰基(五甲基环茂二烯基)钼二聚合物;
二羰基(五甲基环戊二烯基)钼二聚物 
英文名称:
Molybdenum,tetracarbonylbis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-
英文别名:
DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL)MOLYBDENUM DIMER;
DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL);
dicarbonyl(pentamethylcyclopentadienyl)molybdenum(v) dimer;
PENTAMETHYLCYCLOPENTADIENYLMOLYBDENUM DICARBONYL DIMER;
Pentamethylcyclopentadienylmolybdenumdicarbonyldimerredxtl 
CAS No.:
12132-04-6
分 子 式:
C24H30Mo2O4
分 子 量:
574.38
精确分子量:
289.01300
PSA:
0.00000
MDL:
MFCD00058846
危险品标志:
VeryT+
风险术语:
R26/27/28
安全术语:
S53;S36/37/39;S45
分子结构式:
SDS:
查看

羰基(五甲基环茂二烯基)钼二聚合物 物化性质

熔点:
188-194ºC
存储条件/存储方法:

常温密闭避光,通风干燥处

稳定性相关:

常温常压下稳定

避免的物料 氧化物 空气
其它信息:

1.       性状:灰色晶体

2.       密度(g/mL,25):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):219

5.       沸点(ºC,常压):未确定

6.       沸点(ºC1mmHg):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(20ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:未确定

羰基(五甲基环茂二烯基)钼二聚合物 安全信息

包装等级:
II
风险类别:
6.1
危险类别码:
26/27/28
安全说明:
53-36/37/39-45
危险标志:
T+: Very toxic;

羰基(五甲基环茂二烯基)钼二聚合物 毒理性

毒理学数据:

主要的刺激性影响:

在皮肤上面:刺激皮肤和粘膜

在眼睛上面:刺激的影响

致敏作用:没有已知的敏化现象

生态数据:

对水是危害的即使小量的产品渗入地下水也会对饮水造成危害,若无政府许可,勿将材料排入周围环境。

羰基(五甲基环茂二烯基)钼二聚合物 MSDS


Section 1: Product Identification
   Chemical Name:       Pentamethylcyclopentadienylmolybdenum dicarbonyl dimer, 99%    
   CAS Registry Number:       12132-04-6    
   Formula:       [(CH3)5C5Mo(CO)2]2    
   EINECS Number:       none    
   Chemical Family:       metallocene    
   Synonym:       Permethylcyclopentadienylmolybdenum dicarbonyl dimer    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       12132-04-6       100%       10mg/m3( as Mo)       15mg/m3 (as Mo)    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes slight or mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam.    
   If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red xtl.    
   Molecular Weight:       574.38    
   Melting Point:       219° dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       No hazardous polymerization.    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, reducing agents, strong acids and bases.    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes and molybdenum oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

羰基(五甲基环茂二烯基)钼二聚合物 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:289.012612 Da

8、标称质量:289 Da

9、平均质量:287.1863 Da

计算化学数据

1、   疏水参数计算参考值(XlogP):0

2、   氢键供体数量:2

3、   氢键受体数量:2

4、   可旋转化学键数量:3

5、   互变异构体数量:4

6、   拓扑分子极性表面积(TPSA):58.2

7、   重原子数量:13

8、   表面电荷:0

9、   复杂度:177

10、   同位素原子数量:0

11、   确定原子立构中心数量: 0

12、   不确定原子立构中心数量:0

13、   确定化学键立构中心数量:0

14、   不确定化学键立构中心数量:0

15、   共价键单元数量:1

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产品介绍:
产品名称:羰基(五甲基环茂二烯基)钼二聚合物, 99% Cas号:12132-04-6 纯度:99% 包装信息:100kg 价格:100.0元
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产品名称:羰基(五甲基环茂二烯基)钼二聚合物 Cas号:12132-04-6 纯度: 包装信息:洽谈 价格:洽谈
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