磷酸氢钠铵

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS

磷酸氢钠铵 基本信息

中文名称:
磷酸氢钠铵 
中文别名:
磷酸氢钠铵;
四水磷酸氢铵钠;
相关CAS号:13011-54-6 
英文名称:
Ammonium sodium phosphate tetrahydrate
英文别名:
SODIUM AMMONIUM HYDROGEN PHOSPHATE TETRAHYDRATE;
MICROCOSMIC SALT;
sodium ammonium biphosphate;
AMMONIUM SODIUM PHOSPHATE;
SODIUM AMMONIUM PHOSPHATE;
SODIUM AMMONIUM PHOSPHATE REAGENT;
MicrocosMic salt tetrahydrate;
SALT OF PHOSPHORUS;
SODIUM AMMONIUM HYDROGEN PHOSPHATE;
SODIUM AMMONIUM PHOSPHATE TETRAHYDRATE;
SODIUM AMMONIUM PHOSPHATE,4-HYDRATE 
CAS No.:
7783-13-3
分 子 式:
H5NNaO4P
分 子 量:
209.07
精确分子量:
209.02800
PSA:
130.15000
MDL:
MFCD00066970
EINECS:
235-860-8
安全术语:
S24/25;
分子结构式:
SDS:
查看

磷酸氢钠铵 制备方法及用途

制备方法

1.按理论量将化学纯十二水合磷酸氢二钠与氯化铵溶于沸水,即反应生成磷酸氢铵钠: 然后冷却、结晶,滤干后用相同质量的热水溶解结晶,趁热滤去不溶物,所得滤液在不断搅拌下冷却至110℃,析出的结晶经真空吸滤后于室温下干燥至不粘玻棒为止,即得试剂级磷酸氢钠铵。也可采用饱和磷酸二氢钠溶液和氨水反应,经蒸发结晶得到:

合成制备方法

1. 按理论量将化学纯十二水合磷酸氢二钠与氯化铵溶于沸水,即反应生成磷酸氢铵钠:

然后冷却、结晶,滤干后用相同质量的热水溶解结晶,趁热滤去不溶物,所得滤液在不断搅拌下冷却至110℃,析出的结晶经真空吸滤后于室温下干燥至不粘玻棒为止,即得试剂级磷酸氢钠铵。也可采用饱和磷酸二氢钠溶液和氨水反应,经蒸发结晶得到:

用途简介

用作分析试剂,如作镁的沉淀剂。用于铀、锌、锰的化学分析。

用途

1.用作分析试剂,如作镁的沉淀剂。

2.用于铀、锌、锰的化学分析。

磷酸氢钠铵 物化性质

外观与性状:
无色至白色晶体或结晶粉末
密度:
1.54
熔点:
80ºC
存储条件/存储方法:

保持贮藏器密封

放入紧密的贮藏器内,储存在阴凉,干燥的地方

稳定性相关:

如果遵照规格使用和储存则不会分解

其它信息:

1.      性状:无色透明结晶或白色颗粒。在空气中风化并失去部分铵。

2.      密度(g/mL 25ºC):1.54

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):97

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,5.2kPa):未确定

7.      折射率(n20/D):未确定

8.      闪点(ºC,):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值(25℃):未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性(mg/mL):易溶于水,水溶液呈碱性。不溶于乙醇。

磷酸氢钠铵 安全信息

安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

磷酸氢钠铵 毒理性

生态数据:

对水是稍微危害的,若无政府许可,勿将材料排入周围环境

磷酸氢钠铵 MSDS

Name: Sodium Ammonium Phosphate Tetrahydrate Material Safety Data Sheet
Synonym: Ammonium sodium phosphate tetrahydrate
CAS: 7783-13-3
Section 1 - Chemical Product   MSDS Name:Sodium Ammonium Phosphate Tetrahydrate Material Safety Data Sheet
Synonym:Ammonium sodium phosphate tetrahydrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7783-13-3 Sodium ammonium phosphate tetrahydrate >99 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 7783-13-3: CAS# 13011-54-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: colorless
Odor: odorless
pH: 8 (5% solution)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point: 79 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: soluble in water
Specific Gravity/Density: 1.54
Molecular Formula: H5NNaO4P.4H2O
Molecular Weight: 209.07

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, dust generation.
Incompatibilities with Other Materials:
No significant incompatibilities identified with common materials and contaminants..
Hazardous Decomposition Products:
Oxides of nitrogen, oxides of phosphorus, ammonia and/or derivatives.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 7783-13-3 unlisted.
CAS# 13011-54-6 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Sodium ammonium phosphate tetrahydrate - Not listed by ACGIH, IARC, or NTP.
Phosphoric acid, monoammonium monosodium salt anhydrous - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
  Other When too many nutrients such as phosphorus are in the water, algae grows maniacally. Algae blooms are followed by a die-off, and as material decays, it consumes oxygen like a forest fire. No fish, plants or insects can live in oxygen-free zones.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7783-13-3: No information available.
CAS# 13011-54-6: No information available.
Canada
CAS# 13011-54-6 is listed on Canada's DSL List.
CAS# 7783-13-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 13011-54-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7783-13-3 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 13011-54-6 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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