双(醋酸二甲基锡)氧化物

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

双(醋酸二甲基锡)氧化物 基本信息

中文名称:
双(醋酸二甲基锡)氧化物 
中文别名:
双(醋酸二甲基锡)氧化物 
英文名称:
Distannoxane,1,3-bis(acetyloxy)-1,1,3,3-tetramethyl- (9CI)
英文别名:
Bis(acetoxydimethyltin)oxide;
2,4-Dimethyl-2,4-bis(acetyloxy)-2,4-distanna-3-oxapentane;
1,3-diacetoxy-1,1,3,3-tetramethyldistannoxane;
TETRAMETHYLDIACETOXYSTANNOXANE;
1,3-Bis-(acetyloxy)-1,1,3,3-tetramethyldistannoxane;
1,3-Diacetoxy-tetramethyl-distannoxan;
1,1,3,3-tetramethyl-1,3-diacetoxydistannoxane;
Bis--aether;
Bis--aether (Tetramethyl-1.3-diacetoxy-distannoxan);
2,4-Dimethyl-2,4-diacetoxy-2,4-distanna-3-oxapentane;
Tetramethyl-1.3-diacetoxy-distannoxan 
CAS No.:
5926-79-4
分 子 式:
C8H18O5Sn2
分 子 量:
431.65
精确分子量:
433.92000
PSA:
61.83000
MDL:
MFCD00070453
EINECS:
227-660-4
InChI:
The Key: VNRQFTQKKOQJIA-UHFFFAOYSA-L
分子结构式:
SDS:
查看

双(醋酸二甲基锡)氧化物 物化性质

熔点:
240ºC
沸点:
117.1ºC at 760 mmHg
闪点:
40ºC
存储条件/存储方法:

 常温,避光,阴凉干燥处,密封保存

稳定性相关:

常温常压下稳定

其它信息:

1.       性状:未确定

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):240

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.     溶解性:未确定

双(醋酸二甲基锡)氧化物 安全信息

包装等级:
III
风险类别:
6.1

双(醋酸二甲基锡)氧化物 毒理性

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境

双(醋酸二甲基锡)氧化物 MSDS


Section 1: Product Identification
   Chemical Name:       Tetramethyldiacetoxystannoxane    
   CAS Registry Number:       5926-79-4    
   Formula:       [(CH3)2(CH3CO2)Sn]2O    
   EINECS Number:       227-660-4    
   Chemical Family:       organotin compound    
   Synonym:       1,1,3,3-Tetramethyl-1,3-bis(acetyloxy)distannoxane    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       5926-79-4       100%       2mg/m3 (as Sn)       2mg/m3 (as Sn)    

Section 3: Hazards Identification
   Organo tin compounds may act as delayed poisons, causing headache, dizziness; psycho-neurologic
   Emergency Overview:
   disturbances; sore throat, vomiting; urine retention; vision impairment; skin burns, liver and kidney damage.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes severe irritation of the eyes.    
   Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
   Skin Contact:
   severe irritation.
   Irritating to the nose, mucous membranes and respiratory tract. High doses may cause long term neurological
   Inhalation:
   damage.
   Delayed and permanent psycho-neurologic disturbances; impairment of vision, unsteadiness, nausea and
   Ingestion:
   vomiting.
   Irritating to skin, eyes and respiratory tract.Ingestion of certain organotin compounds may cause delayed
   Acute Health Affects:
   poisoning (4 days) with cerebral edema causing damage to the central nervous system.
   Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory
   Chronic Health Affects:
   system, central nervous system, liver, kidneys, urinary tract, and blood.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       carbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, ground limestone, sodium carbonate or other suitable
   Spill and Leak Procedures:
   noncombustible adsorbent and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.    
   Molecular Weight:       431.61    
   Melting Point:       240°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, tin oxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

双(醋酸二甲基锡)氧化物 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:0

3、   氢键受体数量:5

4、   可旋转化学键数量:6

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA):61.8

7、   重原子数量:15

8、   表面电荷:0

9、   复杂度:236

10、   同位素原子数量:0

11、   确定原子立构中心数量:0

12、   不确定原子立构中心数量:0

13、   确定化学键立构中心数量:0

14、   不确定化学键立构中心数量:0

15、   共价键单元数量:1

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