萘酸钇

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

萘酸钇 基本信息

中文名称:
萘酸钇 
中文别名:
萘酸钇;
环烷酸稀土 
英文名称:
Yttrium (III) naphthenate
英文别名:
Yttrium tri(2-naphthoate);
naphthalene-2-carboxylate;
Samarium (III) naphthenate (12-15% Sm);
yttrium(+3) cation;
Coating drying agent LC802;
Yttrium (III) naphthenate 
CAS No.:
61790-20-3
分 子 式:
3(C11H7O2).Re
分 子 量:
0
精确分子量:
602.04000
PSA:
120.39000
MDL:
MFCD00148830
EINECS:
263-114-1
InChI:
InChI=1/3C11H8O2.Y/c3*12-11(13)10-6-5-8-3-1-2-4-9(8)7-10;/h3*1-7H,(H,12,13);/q;;;+3/p-3
风险术语:
R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
查看

萘酸钇 制备方法及用途

用途

作油基系涂料的催干剂替代铅、锰、锌等环烷酸盐系催化剂,通过输氧和催化聚合作用,加速油基性涂料化成膜。若与环烷酸钴、锰配合使用效果更佳,涂膜性能均有明显提高。

萘酸钇 物化性质

存储条件/存储方法:

指定条件下稳定,远离氧化物。

稳定性相关:

远离氧化物

其它信息:

1.       性状:棕褐色粘稠均匀液体。

2.       密度(g/mL,25/4):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):未确定

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:可与200号溶剂油混溶。

萘酸钇 安全信息

危险类别码:
36/37/38
安全说明:
S26-S36-S37-S39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

萘酸钇 毒理性

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

萘酸钇 MSDS


Section 1: Product Identification
   Chemical Name:       Yttrium naphthenate, approx. 60% in toluene (7-13% Y) (99.9%-Y) (REO)    
   CAS Registry Number:       61790-20-3    
   Formula:       Y salt of napthenic acid    
   EINECS Number:       none    
   Chemical Family:       metal carboxylate    
   Synonym:       Naphthenic acid, yttrium salt, in methyl benzene    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       61790-20-3       60%       1mg/m3 (as Y)       1mg/m3 (as Y)    
   toluene       108-88-3       40%       50ppm       300ppm (clg lmt)    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, eyes, inhalation, skin    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes mild irritation of the skin.    
   Irritating to the nose, mucous membranes and respiratory tract and cause headache, dizziness, and
   Inhalation:
   drowsiness.
   Ingestion:       Ingestion may cause gastrointestinal distress, dizziness, weakness, and drowsiness.    
   Acute Health Affects:       Toluene is a skin and eye irritant. Exposure may cause impairment of coordination and reaction time.    
   Chronic Health Affects:       Chronic toluene poisoning may result in bone marrow or liver injury.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Do not induce vomiting as serious lung damage
   Ingestion:
   can result if aspirated.

SECTION 5: Fire Fighting Measures
   Flash Point:       40°F (toluene)    
   Autoignition Temperature:       997°F (toluene)    
   Explosion Limits:       1-7% in air (toluene)    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Flammable material at elevated temperatures. Formation of explosive air/ vapor mixtures is possible.

SECTION 6: Accidental Release Measures
   Eliminate all ignition sources. Small spills may be adsorbed into diatomaceous earth, sand, or other suitable
   Spill and Leak Procedures:
   adsorbent, and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container and store in a cool place. Handle in a well ventilated area.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a vapor. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       viscous liq.    
   Molecular Weight:       not applicable    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       organic odor    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable liquid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Keep away from heat and ignition sources including open flame and electrostatic discharge.    
   Incompatibility:       Oxidizing agents    
   Decomposition Products:       Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.    

SECTION 11: Toxicological Information
   No information available in the RTECS files for title compound. Toluene: Oral (human) LDLo: 50 mg/kg;
   RTECS Data:       Inhalation (human) TCLo: 200 ppm; Inhalation (human) TCLo 100 ppm; Oral (rat) LD50: 636 mg/Kg; Inhalation    
   (rat) LC50:49gm/m3/4H; Intraperitoneal (rat) LD50:1332mg/Kg; Oral (rat) TDLo(reproductive): 7280 mg/Kg.
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       Toluene (CAS# 108-88-3): listed TSCA: Listed on SARA 313    


SECTION 16 - ADDITIONAL INFORMATION
N/A

萘酸钇 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:

3、   氢键受体数量:

4、   可旋转化学键数量:

5、   拓扑分子极性表面积(TPSA):

6、   重原子数量:

7、   表面电荷:

8、   复杂度:

9、   同位素原子数量:0

10、   确定原子立构中心数量:0

11、   不确定原子立构中心数量:0

12、   确定化学键立构中心数量:0

13、   不确定化学键立构中心数量:0

14、   共价键单元数量:1

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