第威德合金

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS

第威德合金 基本信息

中文名称:
第威德合金 
中文别名:
德瓦达合金;
第威德合金 
英文名称:
alioy devarda's
英文别名:
Copper alloy, base, Cu,Al,Zn (Devarda's alloy);
Aluminum alloy, nonbase, Cu,Al,Zn (Devarda's alloy);
Zinc alloy, nonbase, Cu,Al,Zn (Devarda's alloy);
Devarda alloy;
Devardas alloy;
Devarda's Metal;
Devarda's alloy 
CAS No.:
8049-11-4
分 子 式:
Cu-Al-Zn
分 子 量:
155.92
精确分子量:
153.84029
PSA:
0.00000
MDL:
MFCD00198176
InChI:
InChI=1/Al.Cu.Zn
风险术语:
R10; R36/37/38;
安全术语:
S16S33
分子结构式:
SDS:
查看

第威德合金 制备方法及用途

合成制备方法

制法 以铜、铝、锌为原料,以铜∶铝∶锌=10∶ 9∶1( 质量) 的配比熔融而成。

 

用途

1.用作还原剂,可使硝酸原成铵离子用于硝态氮的测定.氯酸根离子还原为氯离子。用于高温、高压的安全装制。

第威德合金 物化性质

熔点:
550 °C(lit.)
稳定性相关:

1.在酸性或碱性溶液中具还原性。

2.本品粉尘吸入或口服有害。

其它信息:

1.      性状:灰白色颗粒或粉末。

2.      密度(g/mL 25ºC):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC常压):550

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,5.2kPa):未确定

7.      折射率(n20/D):未确定

8.      闪点(ºC,):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值(25℃):未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性(mg/mL) :微溶于盐酸。在酸性或碱性溶液中具还原性。

第威德合金 安全信息

危险类别码:
11
安全说明:
16-33-7/9
安全标志:
S16:远离火源。
S33:采取防护措施防止静电发生。

第威德合金 MSDS

Name: Devarda s Metal (Alloy) Material Safety Data Sheet
Synonym: Alloy with 50% copper, 45% aluminum, and 5% zinc
CAS: 8049-11-4
Section 1 - Chemical Product   MSDS Name:Devarda s Metal (Alloy) Material Safety Data Sheet
Synonym:Alloy with 50% copper, 45% aluminum, and 5% zinc

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
8049-11-4 Devarda's Metal (Alloy) 100 unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes eye irritation. Aluminum particles may cause corneal necrosis.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may cause irritation and/or dermatitis. May cause skin discoloration.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
May cause liver and kidney damage.
Inhalation:
Dust is irritating to the respiratory tract. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count.
Chronic:
May cause liver and kidney damage. Chronic inhalation of finely divided powder has been reported to cause pulmonary fibrosis and emphysema. Repeated skin contact has been associated with bleeding into the tissue, delayed hypersensitivity and granulomas.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. Dust can be an explosion hazard when exposed to heat or flame. Dousing metallic fires with water may generate hydrogen gas, an extremely dangerous explosion hazard.
Extinguishing Media:
Do NOT use water directly on fire. Use dry chemical to fight fire.
Use carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
  Handling:
Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits CAS# 8049-11-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: grey
Odor: none reported
pH: Not available.
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: 3092 deg F
Freezing/Melting Point: 550 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 5.8
Molecular Formula: Not applicable.
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, exposure to air, contact with water, combustible materials.
Incompatibilities with Other Materials:
Aluminum is incompatible with ammonium nitrate, ammonium persulfate, antimony trichloride, arsenic trichloride, barium bromate, barium chlorate, barium iodate, barium sulfate, bismuch trioxide, bromates, bromine, calcium bromate, calcium chlorate, calcium iodate, calcium sulfate, carbon disulfide, carbon tetrachloride, chlorates, chlorinated hydrocarbons, chlorine, chlorine trifluroride, chlorofluorohydrocarbons, chloroform, chromic anhydride, copper oxide, diborane, dichlorodifluoromethane, 1,2-dichloro-1,1,2,2,-tetrafluroethane, ethylene dichloride, propylenedichloride, and orthodichlorobenzene, fluorine, fluorochloro-libricants, iodates, iodine, iodine monochloride, iron oxide, lead oxides, magnesium and potassium perchlorate, magnesium bromate, magnesium chlorate, magnesium iodate, manganese and air, methyl bromide, methyl chloride, monobromotrifluoromethane, monochlorotrifluoro-methane, momofluorotrichloro-methane, niobium oxide and sulfur, nitrate-nitrite and organic matter, nitrates, nitric oxide, nitrogen peroxide, nitrosyl chloride, nitrous oxide, oxygen, palladium, performic acid, phosgene, phosphorus trichloride, potassium bromate, potassium chlorate, potassium iodate, potassium sulfate, propylene dichloride, silicon and lead oxide, silver chloride, sodium bromate, sodium carbide, sodium carbonate, sodium chlorate, sodium hydroxide, sodium iodate, sodium peroxide, sodium peroxide and carbon dioxide, sodium sulfate, sulfate, sulfur dichloride, sulfur dioxide, tetrafluoromethane, trichloroetylene, 1,1,2-trichloro-1,2,2-trifluoroethane, zinc bromate, zinc chlorate, zinc iodate, and zinc peroxide. Copper reacts violently with ammonium nitrate, bromates, iodates, chlorates, ethylene Hazardous Decomposition Products:
Aluminum oxide, toxic fumes of zinc oxide, oxides of copper.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 8049-11-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Devarda's Metal (Alloy) - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 8049-11-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 8049-11-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 8049-11-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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