2,6-二氯苯硫酚

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品
  • 表征图谱

2,6-二氯苯硫酚 基本信息

中文名称:
2,6-二氯苯硫酚 
中文别名:
2,6-二氯苯硫酚;
2,6-二氯硫酚 
英文名称:
2,6-Dichlorothiophenol
英文别名:
2,6-dichlorobenzenethiol;
2,6-dichlorobenzene-1-thiol;
2,6-dichlorothiphenol;
2,6-dichlorophenylthiol;
2,6-dichlorthiophenol;
2,6-Dichlorothiophenol 
CAS No.:
24966-39-0
分 子 式:

C6H4Cl2S

分 子 量:
179.07
精确分子量:
177.94100
PSA:
38.80000
EINECS:
416-720-7
InChI:
InChI=1/C6H4Cl2S/c7-4-2-1-3-5(8)6(4)9/h1-3,9H/p-1
危险品标志:

IrritantXi

风险术语:

R36/37/38 

安全术语:
S26;S37/39
分子结构式:
SDS:
查看

2,6-二氯苯硫酚 物化性质

外观与性状:
黄色晶体或大块
密度:
1.421 g/cm3
熔点:
48-50 °C(lit.)
沸点:
119-120 °C (10 mmHg)
闪点:
>230 °F
蒸汽压:
0.0434mmHg at 25°C
存储条件/存储方法:

 

 密闭,阴凉,通风干燥处,

稳定性相关:

 

遵照规定使用和储存则不会分解。未有已知的危险反应

避免氧化剂

其它信息:

1.       性状:白色或黄色还有恶臭味的晶体

2.       密度(g/mL,25):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC,常压):46-48

5.       沸点(ºC,12mmHg):99-101

6.       沸点(ºC,5.2kPa):未确定

7.       折射率(n20/D):未确定

8.       闪点(ºC):112

9.       比旋光度([α]20/Dº):未确定

10.    自燃点或引燃温度(ºC):未确定

11.    蒸气压(mmHg,78ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(oC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性(g/l,水,at 20 ºC):未确定

2,6-二氯苯硫酚 安全信息

包装等级:
III
海关代码:
2930909090
WGK_Germany:
3
德国有关水污染物质的分类清单
危险类别码:
R36/37/38
安全说明:
S26-S37/39
危险标志:
Xi:Irritant;

2,6-二氯苯硫酚 毒理性

毒理学数据:

急性毒性:大鼠经口LD502400 mg/kg

生态数据:

 

对水是稍微危害的,不要让未稀释或大量的产品接触地下水、水稻或污水系统体

2,6-二氯苯硫酚 MSDS

Name: 2 6-Dichlorobenzenethiol 97% Material Safety Data Sheet
Synonym:
CAS: 24966-39-0
Section 1 - Chemical Product   MSDS Name:2 6-Dichlorobenzenethiol 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
24966-39-0 2,6-dichlorobenzenethiol, 97% 97 unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Stench.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
No information regarding eye irritation and other potential effects was found.
Skin:
No information regarding skin irritation and other potential effects was found.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 24966-39-0: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystals
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 95.0 - 100.0 deg C @ 3.00mm H
Freezing/Melting Point: 48.00 - 50.00 deg C
Autoignition Temperature: Not available.
Flash Point: 112 deg C ( 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H4Cl2S
Molecular Weight: 179.06

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 24966-39-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,6-dichlorobenzenethiol, 97% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 24966-39-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 24966-39-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 24966-39-0 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2,6-二氯苯硫酚 海关数据

中国海关编码:2930909090

概述:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
摘要/Summary:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

2,6-二氯苯硫酚 分子结构与计算化学数据

分子结构数据

1摩尔折射率:不确定

2、   摩尔体积(cm3/mol):不确定      

3、   等张比容(90.2K):不确定

4、   表面张力(dyne/cm):不确定

5、   极化率:不确定

计算化学数据

1.疏水参数计算参考值(XlogP):3.3

2.氢键供体数量:1

3.氢键受体数量:1

4.可旋转化学键数量:0

5.互变异构体数量:2

6.拓扑分子极性表面积1

7.重原子数量:9

8.表面电荷:0

9.复杂度:87.1

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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