亚硒酸钾

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学
  • 上游产品

亚硒酸钾 基本信息

中文名称:
亚硒酸钾 
中文别名:
亚硒酸钾;
亚晒酸钾 
英文名称:
Selenious acid,potassium salt (1:2)
英文别名:
dipotassium,selenite;
EINECS 233-909-8;
Potassium selenite;
Dipotassium selenite;
Selenious acid,dipotassium salt;
dipotassium ion selenit 
CAS No.:
10431-47-7
分 子 式:

H2O3Se.2K

分 子 量:
205.15
精确分子量:
205.82900
PSA:
63.19000
MDL:
MFCD00049663
EINECS:
233-909-8
InChI:
The Key: MJJJGABWCTXFHB-UHFFFAOYSA-N
危险品标志:

 

风险术语:

R33;R23/24/25;R23/25;R36/37/38;R50/53

安全术语:
S22;S26;S28;S45;S36/37/39
分子结构式:
SDS:
查看

亚硒酸钾 制备方法及用途

制备方法

将等物质量的碳酸钾和亚硒酸溶液混合后煮沸以除去二氧化碳,然后将其放在浓硫酸上于室温下进行蒸发浓缩,可以得到一水合物的结晶K2SeO3·H2O。

合成制备方法

将等物质量的碳酸钾和亚硒酸溶液混合后煮沸以除去二氧化碳,然后将其放在浓硫酸上于室温下进行蒸发浓缩,可以得到一水合物的结晶K2SeO3·H2O。

用途简介

用作分析试剂。

用途

用作分析试剂。

亚硒酸钾 物化性质

熔点:
875ºC
存储条件/存储方法:
库房通风低温干燥,防潮,与食品分开储运
稳定性相关:

遵照规格使用和储存则不会分解。

极易潮解,易溶于水。

其它信息:

1.       性状:白色晶体状粉末。

2.       密度(g/mL,25/4℃): 2.851

3.       相对蒸汽密度(g/mL,空气=1):无可用

4.       熔点(ºC):875

5.       沸点(ºC,常压):无可用

6.       沸点(ºC,5.2kPa): 无可用

7.       折射率: 无可用

8.       闪点(ºC): 无可用

9.       比旋光度(º):无可用

10.    自燃点或引燃温度(ºC):无可用

11.    蒸气压(kPa,25ºC):无可用

12.    饱和蒸气压(kPa,60ºC):无可用

13.    燃烧热(KJ/mol):无可用

14.    临界温度(ºC):无可用

15.    临界压力(KPa):无可用

16.    油水(辛醇/水)分配系数的对数值:无可用

17.    爆炸上限(%,V/V):无可用

18.    爆炸下限(%,V/V): 无可用

19.    溶解性:可溶于水。

亚硒酸钾 安全信息

包装等级:
I
风险类别:
6.1
危险类别码:
23/25-33-50/53-36/37/38-23/24/25
RTECS号:
VS7200000
安全标志:
S22:不要吸入粉尘。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S28:接触皮肤之后,立即使用大量皂液洗涤。
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
:
危险标志:
T: Toxic;

亚硒酸钾 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VS7200000
CHEMICAL NAME :
Selenious acid, dipotassium salt (9CI)
CAS REGISTRY NUMBER :
10431-47-7
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
O3-Se.2K
MOLECULAR WEIGHT :
205.16
生态数据:

该物质对环境可能有危害,对水体应给予特别注意。

亚硒酸钾 MSDS


Section 1: Product Identification
   Chemical Name:       Potassium selenite    
   CAS Registry Number:       10431-47-7    
   Formula:       K2SeO3    
   EINECS Number:       233-909-8    
   Chemical Family:       inorganic compound    
   Synonym:       Dipotassium selenite    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       10431-47-7       100%       0.2mg/m3 (as Se)       0.2mg/m3 (as Se)    

Section 3: Hazards Identification
   Poison. Ingestion may be fatal at low doses. Inhalation may cause shortness of breath, garlic odor, chills and
   Emergency Overview:
   headache. Chronic exposure may result in nervous disorders, liver and kidney disease.
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes.    
   Eye Contact:       May cause severe irritation, redness, pain.    
   Skin Contact:       May causes severe irritation. Symptoms include redness, itching and pain.    
   Inhalation can cause garlic odor and shortness of breath, chills, headache, and delayed pulmonary edema.
   Inhalation:
   Toxic by inhalation.
   Ingestion:       Toxic. May be fatal if swallowed. May cause gastrointestinal irritation, nausea and vomiting.    
   May be irritating to skin, eyes and respiratory tract, and cause nausea, vomiting, bloody diarrhea, weakness,
   Acute Health Affects:
   chills, headache, and delayed pulmonary edema.
   Prolonged exposure to selenium compounds may cause dermatitis, diarrhea, liver damage, nervous disorders,
   Chronic Health Affects:
   lameness and loss of vitality.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area immediately with water. Remove contaminated clothing if necessary. Seek medical
   Skin Exposure:
   assistance if irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self- contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire, toxic oxidation or decomposition products may form.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Non-flammable. No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Sweep up the solid and dispose of properly.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry place in a tightly sealed container.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       205.16    
   Melting Point:       875° dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       active metals and oxidizing agents    
   Decomposition Products:       potassium oxide and selenium oxide    

SECTION 11: Toxicological Information
   RTECS Data:       Status: EPA Genetox Program 1988: negative B subtilis rec. assay.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       Negative data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Selenates or Selenites    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       I    
   UN ID Number (CFR):       UN# 2630    
   Shipping Name (IATA):       Selenates or Selenites    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       I    
   UN ID Number (IATA):       UN# 2630    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       See Category Code N725 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

亚硒酸钾 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用

2、   摩尔体积(cm3/mol): 无可用

3、   等张比容(90.2K):无可用

4、   表面张力(dyne/cm):无可用

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积63.2

7.重原子数量:6

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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