氢氧化铋

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学
  • 表征图谱

氢氧化铋 基本信息

中文名称:
氢氧化铋 
中文别名:
氢氧化铋;
Barium Chloride Anhydrous;
Barium chloride;
Octyl dodecyl dmethyl ammonium chloride;
Stearyl Gallate;
Gallic acid stearyl ester;
FCdR;
Fluorodeoxycytidine;
NSC 48006;
Ro 5-1090;
Cytidine, 2'-deoxy-5-fluoro-;
4-amino-1-[(3xi)-2-deoxy-beta-D-glycero-pentofuranosyl]-5-fluoropyrimidin-2(1H)-one;
4-amino-1-(2-deoxypentofuranosyl)-5-fluoropyrimidin-2(1H)-one;
2'-deoxy-5-fluorocytidine;
5-Fluoro-2'-deoxycytidine;
(1R,2S,3R,4S,5S,6S)-6-methoxycyclohe 
英文名称:
Bismuth hydroxide
英文别名:
Bismuth hydroxide;
Bismuth Hydroxide;
bismuth,trihydroxide 
CAS No.:
10361-43-0
分 子 式:
BiH3O3
分 子 量:
260.00
精确分子量:
259.98900
PSA:
60.69000
EINECS:
233-790-2
InChI:
InChI=1/Bi.3H2O/h;3*1H2/q+3;;;/p-3
分子结构式:
SDS:
查看

氢氧化铋 制备方法及用途

制备方法

用于铋盐制造

用途简介

用途

芸香苷和栎精的吸收剂。从辐射后的铀中分离钚。核糖核酸的水解。铋盐的制备。

氢氧化铋 物化性质

外观与性状:
白色-黄色非晶形的粉末
密度:
4.4 g/cm3
沸点:
100ºC at 760 mmHg
蒸汽压:
24.5mmHg at 25°C
存储条件/存储方法:

本品应密封保存。

其它信息:

1.         性状:白色或浅黄色无定形粉末。100℃时失去一分子水成黄色的偏氢氧化铋,415℃时分解成氧化铋。

2.         密度(g/mL,25/4℃): 4.962

3.         相对蒸汽密度(g/mL,空气=1):未确定

4.         熔点(ºC): 未确定

5.         沸点(ºC,常压):未确定

6.         沸点(ºC,5.2kPa):未确定

7.         折射率:未确定

8.         闪点(ºC):未确定

9.         比旋光度(º):未确定

10.     自燃点或引燃温度(ºC):未确定

11.     蒸气压(kPa,25ºC):未确定

12.     饱和蒸气压(kPa,60ºC):未确定

13.     燃烧热(KJ/mol):未确定

14.     临界温度(ºC):未确定

15.     临界压力(KPa):未确定

16.     油水(辛醇/水)分配系数的对数值:未确定

17.     爆炸上限(%,V/V):未确定

18.     爆炸下限(%,V/V):未确定

19.     溶解性:溶于无机酸,几乎不溶于水。

氢氧化铋 安全信息

海关代码:
2825909000

氢氧化铋 MSDS


Section 1. Chemical Product and Company Identification
    Bismuth hydroxide        Catalog    
    Common Name/
    Number(s).
    Trade Name
    CAS#        10361-43-0    
    Manufacturer
    RTECS        Not available.    
    SPECTRUM QUALITY PRODUCTS INC.
    TSCA        TSCA 8(b) inventory: Bismuth    
    hydroxide
    Commercial Name(s)        Not available.    
    CI# Not available.
    Synonym        Not available.    
    IN CASE OF EMERGENCY
    Not available.
    Chemical Name
    Chemical Family        Not available.        CALL (310) 516-8000    
    Bi(OH)3
    Chemical Formula
    SPECTRUM QUALITY PRODUCTS INC.

Section 2.Composition and Information on Ingredients
    Exposure Limits
    TWA (mg/m3)        STEL (mg/m3) CEIL (mg/m3)    
    Name        CAS #        % by Weight    
    1) Bismuth hydroxide        10361-43-0        100    
    Toxicological Data        Not applicable.    
    on Ingredients

Section 3. Hazards Identification
    Potential Acute Health Effects Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of
    inhalation.
    Potential Chronic Health        Hazardous in case of ingestion.    
    Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.
    Effects
    CARCINOGENIC EFFECTS: Not available.
    MUTAGENIC EFFECTS: Not available.
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    Bismuth hydroxide

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at    
    least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention if irritation
    occurs.
    Skin Contact        Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.    
    Serious Skin Contact        Not available.    
    Inhalation        If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get    
    medical attention.
    Serious Inhalation        Not available.    
    Ingestion        Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an    
    unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
    clothing such as a collar, tie, belt or waistband.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Not available.
    Products of Combustion
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by    
    spreading water on the contaminated surface and dispose of according to local and regional authority
    requirements.
    Large Spill
    Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water
    on the contaminated surface and allow to evacuate through the sanitary system.
    Bismuth hydroxide

Section 7. Handling and Storage
    Precautions        No specific safety phrase has been found applicable for this product.    
    Storage        Keep container tightly closed. Keep container in a cool, well-ventilated area.    

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.    
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        Not available.    

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid.        Odor        Not available.    
    Taste        Not available.    
    Molecular Weight        260.02 g/mole    
    Not available.
    Color
    Not available.
    pH (1% soln/water)
    Boiling Point        Not available.    
    Decomposes.
    Melting Point
    Critical Temperature        Not available.    
    Specific Gravity        4.36 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Not available.
    Water/Oil Dist. Coeff.
    Ionicity (in Water)        Not available.    
    Dispersion Properties        Not available.    
    Solubility        Very slightly soluble in cold water.    

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Not available.
    Instability Temperature
    Conditions of Instability        Not available.    
    Incompatibility with various        Not available.    
    substances
    Corrosivity        Non-corrosive in presence of glass.    
    Bismuth hydroxide
    Not available.
    Special Remarks on
    Reactivity
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        Will not occur.    

Section 11. Toxicological Information
    Routes of Entry        Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans Not available.
    Other Toxic Effects on
    Hazardous in case of ingestion.
    Humans        Slightly hazardous in case of skin contact (irritant), of inhalation.    
    Special Remarks on
    Not available.
    Toxicity to Animals
    Special Remarks on        Due to the presence of dark line on gums, chronic bismuth toxicity may complicate diagnosis of chronic lead    
    Chronic Effects on Humans        toxicity.    
    Special Remarks on other        Not available.    
    Toxic Effects on Humans

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    Not available.
    BOD5 and COD
    Possibly hazardous short term degradation products are not likely. However, long term degradation products may
    Products of Biodegradation
    arise.
    Toxicity of the Products        The products of degradation are more toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation

Section 13. Disposal Considerations
    Waste Disposal

Section 14. Transport Information
    DOT Classification        Not a DOT controlled material (United States).    
    Identification        Not applicable.    
    Not applicable.
    Special Provisions for
    Transport
    DOT (Pictograms)
    Bismuth hydroxide

Section 15. Other Regulatory Information and Pictograms
    TSCA 8(b) inventory: Bismuth hydroxide
    Federal and State
    Regulations
    California
    Proposition 65
    Warnings
    Other Regulations        Not available.    
    WHMIS (Canada) Not controlled under WHMIS (Canada).
    Other Classifications
    DSCL (EEC)        This product is not classified according    
    to the EU regulations.
    Health Hazard
    HMIS (U.S.A.)        1 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    1 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent.
    Safety glasses.


SECTION 16 - ADDITIONAL INFORMATION
N/A

氢氧化铋 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:259.988619 Da

8、标称质量:260 Da

9、平均质量:260.0024 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:3

3.氢键受体数量:3

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积3

7.重原子数量:4

8.表面电荷:0

9.复杂度:0

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

氢氧化铋 表征图谱

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