六水高氯酸锶

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

六水高氯酸锶 基本信息

中文名称:
六水高氯酸锶 
中文别名:
六水高氯酸锶;
过氯酸锶 
英文名称:
Perchloric acid,strontium salt (2:1)
英文别名:
strontium,diperchlorate;
strontium diperchlorate;
AC1L1VKH;
Perchloric acid,strontium salt;
AC1NB6KI;
strontium(2+) diperchlorate ion;
Strontium perchlorate;
EINECS 236-614-2;
CTK4B9218;
UN1508 
CAS No.:
13450-97-0
分 子 式:
ClHO4.1/2Sr
分 子 量:
286.52
精确分子量:
285.80300
PSA:
148.54000
EINECS:
236-614-2
风险术语:
R8R34
安全术语:
S17S26S36/S37/S39
分子结构式:
SDS:
查看

六水高氯酸锶 制备方法及用途

制备方法

将水合高氯酸锶置于真空干燥器中,加热到250℃脱水,保持压力为133.3~1333.2Pa或用固态SrCO3与NH4ClO4一起研磨之后,在133.3~1333.2Pa压力下加热到250℃制取。

合成制备方法

将水合高氯酸锶置于真空干燥器中,加热到250℃脱水,保持压力为133.3~1333.2Pa或用固态SrCO3与NH4ClO4一起研磨之后,在133.3~1333.2Pa压力下加热到250℃制取。

用途简介

氧化剂。

用途

氧化剂。

六水高氯酸锶 物化性质

熔点:
<100ºC
稳定性相关:

吸湿溶解性mol/kg H2O:816(0℃),1067(25℃),1270(40℃)。溶于乙醇。不溶于乙醚。ΔfH=-763kJ/mol。S=248J/(K·mol)。

其它信息:

1.       性状:无色晶体。

2.       密度(g/mL,25/4℃):未确定

3.       相对蒸汽密度(g/mL,空气=1):未确定

4.       熔点(ºC):100

5.       沸点(ºC,常压):未确定

6.       沸点(ºC,5.2kPa):未确定

7.       折射率:未确定

8.       闪点(ºC):未确定

9.       比旋光度(º):未确定

10.    自燃点或引燃温度(ºC):不适用的

11.    蒸气压(kPa,25ºC):未确定

12.    饱和蒸气压(kPa,60ºC):未确定

13.    燃烧热(KJ/mol):未确定

14.    临界温度(ºC):未确定

15.    临界压力(KPa):未确定

16.    油水(辛醇/水)分配系数的对数值:未确定

17.    爆炸上限(%,V/V):未确定

18.    爆炸下限(%,V/V):未确定

19.    溶解性:可溶解的

六水高氯酸锶 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
8-34
安全说明:
S17-S26-S36/37/39
安全标志:
S17:远离可燃物质。
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:

六水高氯酸锶 毒理性

毒理学数据:

1、急性毒性:主要的刺激性影响:

六水高氯酸锶 MSDS


Section 1: Product Identification
   Chemical Name:       Strontium perchlorate dihydrate (99.9%-Sr)    
   CAS Registry Number:       13450-97-0    
   Formula:       Sr(ClO4)2.2H2O    
   EINECS Number:       none    
   Chemical Family:       metal perchlorate salt    
   Synonym:       Perchloric acid, Strontium(II) salt, hexahydrate    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13450-97-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes moderate irritation of the eyes.    
   Skin Contact:       Causes moderate irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   No specific information is available on the physiological effects of ingestion. May cause gastrointestinal
   Ingestion:
   irritation, nausea, and vomiting.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Perchlorates reversibly inhibit thyroid iodine uptake. Kidney function may be affected.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       Water spray    
   Spray closed containers with water until fire is out. Avoid contact with combustible material. Fire fighters
   Special Fire Fighting Procedures:
   should be equipped with a NIOSH approved self-contained breathing apparatus.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen chloride fumes.    
   Decomposion Products:
   Releases oxygen on heating. May decompose explosively under fire fighting conditions. Do not mix with
   Unusual Fire or Explosion Hazards:
   combustibles.

SECTION 6: Accidental Release Measures
   Do not mix spilled powder with any combustible materials, such as sawdust. Sweep up the solid and dilute
   Spill and Leak Procedures:
   with water.

SECTION 7: Handling and Storage
   Store in a tightly sealed container in a cool dry place away from combustible and flammable materials. If the
   Handling and Storage:
   container is left open, salt may adsorb moisture from the atmosphere

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl.    
   Molecular Weight:       286.52 (394.61)    
   Melting Point:       100°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:

SECTION 10: Stability and Reactivity
   Stability:       Hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       Any contact with combustible matter.    
   Incompatibility:       Reducing agents, organic matter, active metals, phosphorus, sulfur, hydrazine, hydroxylamine, strong acids    
   Decomposition Products:       Oxygen, Strontium oxide, hydrogen chloride,    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Strontium perchlorate    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1508    
   Shipping Name (IATA):       Strontium perchlorate    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1508    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

六水高氯酸锶 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:285.802639 Da

8、标称质量:286 Da

9、平均质量:286.5212 Da

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:8

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积149

7.重原子数量:11

8.表面电荷:0

9.复杂度:95.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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