高氯酸铅(2+)

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

高氯酸铅(2+) 基本信息

中文名称:
高氯酸铅(2+) 
中文别名:
高氯酸铅(2+);
高氯酸铅(Ⅱ)三水 
英文名称:
Perchloric acid,lead(2+) salt (2:1)
英文别名:
lead(2+),diperchlorate;
Lead diperchlorate;
Lead perchlorate;
UN1470;
EINECS 237-125-7;
Lead perchlorate,solid or solution 
CAS No.:
13637-76-8
分 子 式:
ClHO4.1/2Pb
分 子 量:
406.1012
精确分子量:
405.87400
PSA:
148.54000
EINECS:
237-125-7
危险品标志:
OxidizingOToxicTDangerousN
风险术语:
61-8-20/22-33-50/53-62
安全术语:
53-45-60-61
分子结构式:
SDS:
查看

高氯酸铅(2+) 制备方法及用途

制备方法

制法:将72%的HClO4加到Pb(NO3)2溶液中,反应后除去过量的HClO4。将高氯酸铅溶液在125℃以下蒸发,直至只含有比生成三水化物的水稍多一点,然后将溶液在大约160℃加热3h。

合成制备方法

制法:将72%的HClO4加到Pb(NO3)2溶液中,反应后除去过量的HClO4。将高氯酸铅溶液在125℃以下蒸发,直至只含有比生成三水化物的水稍多一点,然后将溶液在大约160℃加热3h。

用途简介

用作涂料中的耐腐蚀颜料,制造蓄电池、化学药品。

用途

用作涂料中的耐腐蚀颜料,制造蓄电池、化学药品。[12]

高氯酸铅(2+) 物化性质

存储条件/存储方法:

储存注意事项[11]  储存于阴凉、通风的库房。库温不超过30℃,相对湿度不超过80%。远离火种、热源。包装必须密封,切勿受潮。应与易(可)燃物、还原剂、食用化学品分开存放,切忌混储。储区应备有合适的材料收容泄漏物。

稳定性相关:

1.稳定性[6]   稳定

2.禁配物[7]  还原剂、易燃或可燃物

3.避免接触的条件[8]  受热

4.聚合危害[9]   不聚合

5.分解产物[10]  氧化铅

其它信息:

1.性状:白色斜方结晶,有潮解性。[1]

2.熔点(分解,℃):100[2]

3.相对密度(水=1):2.6[3]

4.溶解性:易溶于冷水,溶于乙醇。[4]

高氯酸铅(2+) 安全信息

包装等级:
II
风险类别:
5.1
危险类别码:
R61
安全说明:
53-45-60-61
安全标志:
S45:出现意外或者感到不适,立刻到医生那里寻求帮助(最好带去产品容器标签)。
S53:避免暴露——使用前先阅读专门的说明。
S60:本物质残余物和容器必须作为危险废物处理。
S61:避免排放到环境中。参考专门的说明/安全数据表。
危险标志:
O: Oxidizing agent;T: Toxic;N: Dangerous for the environment;

高氯酸铅(2+) 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SC8100000
CHEMICAL NAME :
Perchloric acid, lead(2+) salt
CAS REGISTRY NUMBER :
13637-76-8
LAST UPDATED :
199712
DATA ITEMS CITED :
23
MOLECULAR FORMULA :
Cl2-O8.Pb
毒理学数据:

1.急性毒性  暂无资料

2.刺激性  暂无资料

3.致癌性[5]  IARC致癌性评论:IARC将铅的无机化合物列为G2A,可疑人类致癌物。

生态数据:

1.生态毒性  暂无资料

2.生物降解性  暂无资料

3.非生物降解性  暂无资料

高氯酸铅(2+) MSDS


Section 1. Chemical Product and Company Identification
    Lead perchlorate        Catalog    
    Common Name/
    Number(s).
    Trade Name
    CAS#        13637-76-8    
    Manufacturer
    RTECS        SC8100000    
    SPECTRUM CHEMICAL MFG. CORP.
    TSCA        TSCA 8(b) inventory: Lead    
    perchlorate
    Commercial Name(s)        Not available.    
    CI# Not available.
    Synonym        Not available.    
    IN CASE OF EMERGENCY
    Chemical Name
    Chemical Family        Not available.        CALL (310) 516-8000    
    Pb(ClO4)2.3H2O
    Chemical Formula
    SPECTRUM CHEMICAL MFG. CORP.

Section 2.Composition and Information on Ingredients
    Exposure Limits
    TWA (mg/m3)        STEL (mg/m3) CEIL (mg/m3)    
    Name        CAS #        % by Weight    
    1) Lead perchlorate        13637-76-8        0.15 0.45 100    
    Toxicological Data        Lead perchlorate    
    on Ingredients        LD50: Not available.    
    LC50: Not available.

Section 3. Hazards Identification
    Potential Acute Health Effects Extremely hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of
    inhalation. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause
    respiratory irritation. Severe over-exposure can result in death.
    Extremely hazardous in case of ingestion.
    Potential Chronic Health
    Effects        Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation.    
    CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC.
    MUTAGENIC EFFECTS: Not available.
    TERATOGENIC EFFECTS: Not available.
    DEVELOPMENTAL TOXICITY: Not available.
    The substance is toxic to blood, kidneys, the nervous system.
    Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an
    Lead perchlorate
    highly toxic material may produce general deterioration of health by an accumulation in one or many human
    organs.

Section 4. First Aid Measures
    Eye Contact        Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,    
    keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
    Skin Contact        After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin    
    with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
    Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
    Wash contaminated clothing before reusing.
    Serious Skin Contact        Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate    
    medical attention.
    Inhalation        Allow the victim to rest in a well ventilated area. Seek immediate medical attention.    
    Serious Inhalation        Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or    
    waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation
    when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.
    Ingestion        Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible    
    indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen
    tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
    resuscitation. Seek immediate medical attention.
    Serious Ingestion        Not available.    

Section 5. Fire and Explosion Data
    Flammability of the Product Non-flammable.
    Auto-Ignition Temperature Not applicable.
    Flash Points        Not applicable.    
    Flammable Limits        Not applicable.    
    Products of Combustion        Not available.    
    Fire Hazards in Presence of Not applicable.
    Various Substances
    Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
    of Various Substances        Risks of explosion of the product in presence of static discharge: Not available.    
    Fire Fighting Media        Not applicable.    
    and Instructions
    Special Remarks on        Not available.    
    Fire Hazards
    Special Remarks on Explosion Not available.
    Hazards
    Lead perchlorate

Section 6. Accidental Release Measures
    Small Spill        Use appropriate tools to put the spilled solid in a convenient waste disposal container.    
    Large Spill
    Oxidizing material.
    Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
    damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
    above TLV. Check TLV on the MSDS and with local authorities.

Section 7. Handling and Storage
    Precautions        Keep locked up Keep away from heat. Keep away from sources of ignition. Keep away from combustible    
    material Do not ingest. Do not breathe dust. Wear suitable protective clothing In case of insufficient ventilation,
    wear suitable respiratory equipment If ingested, seek medical advice immediately and show the container or the
    label. Avoid contact with skin and eyes Keep away from incompatibles such as reducing agents, combustible
    materials, organic materials.
    Storage        Keep container tightly closed. Keep in a cool, well-ventilated place. Highly toxic or infectious materials should be    
    stored in a separate locked safety storage cabinet or room.

Section 8. Exposure Controls/Personal Protection
    Engineering Controls        Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below    
    recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Personal Protection        Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.    
    Gloves.
    Personal Protection in Case of Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
    a Large Spill        to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist    
    BEFORE handling this product.
    Exposure Limits        TWA: 0.15 CEIL: 0.45 (mg/m3)    
    Consult local authorities for acceptable exposure limits.

Section 9. Physical and Chemical Properties
    Physical state and appearance Solid. (Crystalline solid.)        Odor        Not available.    
    Taste        Not available.    
    Molecular Weight        406.09 g/mole    
    White.
    Color
    Not available.
    pH (1% soln/water)
    Boiling Point        Not available.    
    Decomposes. (100°C or 212°F)
    Melting Point
    Critical Temperature        Not available.    
    Specific Gravity        2.6 (Water = 1)    
    Vapor Pressure        Not applicable.    
    Vapor Density        Not available.    
    Volatility        Not available.    
    Odor Threshold        Not available.    
    Water/Oil Dist. Coeff.        Not available.    
    Ionicity (in Water)        Not available.    
    Dispersion Properties        See solubility in water, methanol.    
    Lead perchlorate
    Easily soluble in cold water.
    Solubility
    Soluble in methanol.

Section 10. Stability and Reactivity Data
    Stability        The product is stable.    
    Instability Temperature        Not available.    
    Conditions of Instability        Not available.    
    Extremely reactive or incompatible with combustible materials, organic materials.
    Incompatibility with various
    substances        Highly reactive with reducing agents.    
    Not available.
    Corrosivity
    Special Remarks on        Not available.    
    Reactivity
    Not available.
    Special Remarks on
    Corrosivity
    Polymerization        No.    

Section 11. Toxicological Information
    Routes of Entry        Eye contact. Inhalation. Ingestion.    
    Toxicity to Animals        LD50: Not available.    
    LC50: Not available.
    Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC.
    The substance is toxic to blood, kidneys, the nervous system.
    Other Toxic Effects on        Extremely hazardous in case of ingestion.    
    Humans        Hazardous in case of skin contact (irritant), of inhalation.    
    Special Remarks on        Not available.    
    Toxicity to Animals
    Special Remarks on        Not available.    
    Chronic Effects on Humans
    Special Remarks on other        Not available.    
    Toxic Effects on Humans

Section 12. Ecological Information
    Ecotoxicity        Not available.    
    BOD5 and COD        Not available.    
    Products of Biodegradation        Possibly hazardous short term degradation products are not likely. However, long term degradation products may    
    arise.
    Toxicity of the Products        The products of degradation are more toxic.    
    of Biodegradation
    Special Remarks on the        Not available.    
    Products of Biodegradation
    Lead perchlorate

Section 13. Disposal Considerations
    Waste Disposal

Section 14. Transport Information
    DOT Classification        CLASS 5.1: Oxidizing material.    
    : Lead perchlorate : UN1470 PG: II
    Identification
    Marine Pollutant
    Special Provisions for
    Transport
    DOT (Pictograms)
    OXIDIZER
    5.1

Section 15. Other Regulatory Information and Pictograms
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    Federal and State
    cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Lead
    Regulations
    perchlorate
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause reproductive harm (female) which would require a warning under the statute: Lead perchlorate
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause reproductive harm (male) which would require a warning under the statute: Lead perchlorate
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause birth defects which would require a warning under the statute: Lead perchlorate
    California prop. 65: This product contains the following ingredients for which the State of California has found to
    cause cancer which would require a warning under the statute: Lead perchlorate
    Pennsylvania RTK: Lead perchlorate
    Massachusetts RTK: Lead perchlorate
    TSCA 8(b) inventory: Lead perchlorate
    SARA 313 toxic chemical notification and release reporting: Lead perchlorate
    CERCLA: Hazardous substances.: Lead perchlorate
    California        California prop. 65: This product contains the following ingredients for which the State of California has found    
    Proposition 65        to cause cancer which would require a warning under the statute: Lead perchlorate    
    Warnings
    California prop. 65: This product contains the following ingredients for which the State of California has found
    to cause birth defects which would require a warning under the statute: Lead perchlorate
    Other Regulations
    OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
    CLASS C: Oxidizing material.
    Other Classifications        WHMIS (Canada)    
    CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
    CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
    DSCL (EEC)        R36/38- Irritating to eyes and skin.    
    R40- Possible risks of irreversible
    effects.
    Health Hazard
    HMIS (U.S.A.)        2 National Fire Protection    
    0 Flammability
    0 Association (U.S.A.)
    Fire Hazard
    2 0 Reactivity
    Health
    Reactivity
    0
    Specific hazard
    Personal Protection
    E
    Lead perchlorate
    WHMIS (Canada)
    (Pictograms)
    DSCL (Europe)
    (Pictograms)
    TDG (Canada)
    (Pictograms)
    5.1
    ADR (Europe)
    (Pictograms)
    Protective Equipment
    Gloves.
    Lab coat.
    Dust respirator. Be sure to use an
    approved/certified respirator or
    equivalent. Wear appropriate respirator
    when ventilation is inadequate.
    Lead perchlorate
    All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
    combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
    methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,


SECTION 16 - ADDITIONAL INFORMATION
N/A

高氯酸铅(2+) 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率:无可用的

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:8

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积149

7.重原子数量:11

8.表面电荷:0

9.复杂度:95.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:3

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