4-甲基苯丙酮

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

4-甲基苯丙酮 基本信息

中文名称:
4-甲基苯丙酮 
中文别名:
4-甲基苯丙酮;
4-甲基苯基乙酮 
英文名称:
2-Propanone,1-(4-methylphenyl)-
英文别名:
1-(4-methylphenyl)propan-2-one;
methyl 4-methylbenzyl ketone;
p-tolunylacetone;
4-Methylphenylacetone;
1-p-tolylpropan-2-one;
p-Methylphenyl acetone 
CAS No.:
2096-86-8
分 子 式:

C10H12O

分 子 量:
148.2
精确分子量:
148.08900
PSA:
17.07000
MDL:
MFCD00017250
BRN:
2074049
InChI:
InChI=1/C10H12O/c1-8-3-5-10(6-4-8)7-9(2)11/h3-6H,7H2,1-2H3
危险品标志:

 

风险术语:

 

安全术语:
S24/25;
分子结构式:
SDS:
查看

4-甲基苯丙酮 物化性质

密度:
0.974g/cm3
沸点:
132 °C
闪点:
97.1ºC
折射率:
1.507
蒸汽压:
0.0982mmHg at 25°C
存储条件/存储方法:

储存的地方避免与氧化剂接触,将容器密封,储存密封的储藏器内,并放在阴凉,干爽的地方

稳定性相关:

1. 避免与氧化物接触,危险分解产品为一氧化碳和二氧化碳。

2. 存在于主流烟气中。

其它信息:

1.      性状:液体

2.      密度(g/mL,25/4 ºC):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压);132

6.      沸点(ºC, 9mm Hg ):未确定

7.       折射率(n20D):1.5068

8.      闪点(ºC/1mm): 未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,0ºC):未确定

12.   饱和蒸气压(kPa,20ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

4-甲基苯丙酮 安全信息

海关代码:
2914399090
安全说明:
S24/25
安全标志:
S24/25:防止皮肤和眼睛接触。

4-甲基苯丙酮 毒理性

生态数据:

对水是稍微有害的,不要让未稀释或大量的产品接触地下水,水道或者污水系统,若无政府许可,勿将材料排入周围环境

4-甲基苯丙酮 MSDS

Name: 4-Methylphenylacetone 98% Material Safety Data Sheet
Synonym: None Known
CAS: 2096-86-8
Section 1 - Chemical Product   MSDS Name:4-Methylphenylacetone 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
2096-86-8 4-Methylphenylacetone 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2096-86-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: clear light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C10H12O
Molecular Weight: 148.21

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not currently available.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 2096-86-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Methylphenylacetone - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 2096-86-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2096-86-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2096-86-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-甲基苯丙酮 海关数据

中国海关编码:2914399090

概述:
2914399090. 其他不含其他含氧基的芳香酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 丙酮报明包装
摘要/Summary:
2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

4-甲基苯丙酮 分子结构与计算化学数据

分子结构数据

1、   摩尔折射率:45.28

2、   摩尔体积(cm3/mol):152.1

3、   等张比容(90.2K):366.3

4、   表面张力(dyne/cm):33.6

5、 极化率(10-24cm3):17.95

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:1

4.可旋转化学键数量:2

5.互变异构体数量:3

6.拓扑分子极性表面积17.1

7.重原子数量:11

8.表面电荷:0

9.复杂度:132

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

湖北万得化工有限公司

产品介绍:
产品名称:4'-甲基苯基丙-2-酮 Cas号:2096-86-8 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:王念 电话:027-59210159 手机:15172311821

湖北齐飞医药化工有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:汪军蕊(微信同号) 电话:027-59322506 手机:18071128683

湖北永阔科技有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄蓉 电话:027-59223108 手机:15107166787

湖北实顺生物科技有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:付经理 电话:027-59223025 手机:15107168801

湖北广奥生物科技有限公司

产品介绍:
产品名称:4'-甲基苯基丙-2-酮 Cas号:2096-86-8 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:付玉 电话:027-59223056 手机:15271829679

天门恒昌化工有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:25kg纸板桶/编织袋/塑料桶 价格:25.0元
联系方式:
联系人:黄湘迪 电话:027-59322316 手机:15827039378

淄博航宇生物科技发展有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:100kg 价格:洽谈
联系方式:
联系人:张经理 电话:15666366704 手机:15666366704

湖北鑫红利化工有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:99% 包装信息:1kg铝箔袋/氟化瓶,10kg铝听/纸箱,25kg纸板桶/编织袋/塑料桶,200kg镀锌铁桶/塑料桶,1t吨袋 价格:1.0元 - 1,000.0元
联系方式:
联系人:李经理 电话:027-59106151 手机:18871490254

上海吉至生化科技有限公司

产品介绍:
产品名称:4-甲基苯丙酮 Cas号:2096-86-8 纯度:- 包装信息:1gea,5gea 价格:368.0元 - 688.0元
联系方式:
联系人:Shirley张 电话:021-57520831 手机:18116052675

湖北拓邦化工有限公司

产品介绍:
产品名称:4''-甲基苯基丙-2-酮 Cas号:2096-86-8 纯度:99% 包装信息:10kg 价格:洽谈
联系方式:
联系人:胡雯丽 电话:027-59106185 手机:13986181695
QQ: 2241752642
微信二维码
电话: 19906633110