4-乙酰氧基-7-甲基茚满

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学

4-乙酰氧基-7-甲基茚满 基本信息

中文名称:
4-乙酰氧基-7-甲基茚满 
中文别名:
4-乙酰氧基-7-甲基茚满;
4-乙酰氧基-7-甲基茚 
英文名称:
1H-Inden-4-ol,2,3-dihydro-7-methyl-, 4-acetate
英文别名:
(7-methyl-2,3-dihydro-1H-inden-4-yl) acetate;
7-methylindan-4-yl acetate;
4-Acetoxy-7-methylindane;
7-methyl-2,3-dihydro-1H-inden-4-yl acetate;
2,3-Dihydro-7-Methyl-1H-Inden-4-Ol 4-Acetate 
CAS No.:
175136-12-6
分 子 式:
C12H14O2
分 子 量:
190.24
精确分子量:
190.09900
PSA:
26.30000
MDL:
MFCD00173682
安全术语:
S23;S24/25
分子结构式:
SDS:
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4-乙酰氧基-7-甲基茚满 物化性质

密度:
1.103g/cm3
沸点:
113ºC
折射率:
1.545
蒸汽压:
0.00125mmHg at 25°C
存储条件/存储方法:

保存方法:密闭,阴凉,干燥处

稳定性相关:

避氧化物

其它信息:

1.      性状:未确定

2.      密度(g/mL,20):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):113

6.      沸点(ºC 4 mmHg):未确定

7.      折射率:未确定

8.      闪点(ºF):113-114

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25ºC):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

4-乙酰氧基-7-甲基茚满 安全信息

海关代码:
2915390090
安全说明:
S23
安全标志:
S23:不要吸入蒸汽。
S24/25:防止皮肤和眼睛接触。

4-乙酰氧基-7-甲基茚满 毒理性

生态数据:

其它有害作用:对水稍有危害的,不要让未稀释或大量的产品接触地下水、水道或污水系统

4-乙酰氧基-7-甲基茚满 MSDS

Name: 7-Methyl-2 3-dihydro-1h-inden-4-yl acetate 97% Material Safety Data Sheet
Synonym: 4-Acetoxy-7-methylindan
CAS: 175136-12-6
Section 1 - Chemical Product   MSDS Name:7-Methyl-2 3-dihydro-1h-inden-4-yl acetate 97% Material Safety Data Sheet
Synonym:4-Acetoxy-7-methylindan

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
175136-12-6 7-Methyl-2,3-dihydro-1H-inden-4-yl ace 97% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
  Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 175136-12-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Liquid
Color: colorless - pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 113 - 114 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H14O2
Molecular Weight: 190

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 175136-12-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
7-Methyl-2,3-dihydro-1H-inden-4-yl acetate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 175136-12-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 175136-12-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 175136-12-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

4-乙酰氧基-7-甲基茚满 海关数据

中国海关编码:2915390090

概述:
2915390090. 其他乙酸酯. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%
申报要素:
品名, 成分含量, 用途
监管条件:
A.入境货物通关单B.出境货物通关单
检验检疫:
R.进口食品卫生监督检验S.出口食品卫生监督检验M.进口商品检验N.出口商品检验
摘要/Summary:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

4-乙酰氧基-7-甲基茚满 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):2.9

2.氢键供体数量:0

3.氢键受体数量:2

4.可旋转化学键数量:2

5.互变异构体数量:无

6.拓扑分子极性表面积26.3

7.重原子数量:14

8.表面电荷:0

9.复杂度:224

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

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