3-氨基-N-Cbz-吡咯烷

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 下游产品

3-氨基-N-Cbz-吡咯烷 基本信息

中文名称:
3-氨基-N-Cbz-吡咯烷 
中文别名:
3-氨基-N-Cbz-吡咯烷;
1-苄氧羰基-3-氨基吡咯烷;
3-氨基吡咯烷-1-甲酸苄酯;
N-CBZ-3-氨基吡咯烷;
3-氨基-N-CBZ-吡咯烷盐酸盐 
英文名称:
1-Pyrrolidinecarboxylicacid, 3-amino-, phenylmethyl ester
英文别名:
Benzyl 3-Aminopyrrolidine-1-carboxylate;
3-AMINO-1-N-CBZ-PYRROLIDINE;
3-Amino-1-Cbz-pyrrolidine;
N-Cbz-3-aminopyrrolidine;
(^+)-3-AMino-1-(benzyloxycarbonyl)pyrrolidine;
benzyl 3-amino-pyrrolidine-1-carboxylate,phenylmethyl ester;
1-Benzyloxycarbonyl-3-aminopyrrolidine;
N-Cbz-3-Aminopyrrolidine HCl;
(S)-3-Amino-1-pyrrolidinecarboxylic acid,phenylmethyl ester;
1-Cbz-3-amino-pyrrolidine;
N-Cbz-3-AMinopyrrolidine HCl;
(S)-benzyl 3-aminopyrrolidine-1-carboxylate;
3-AMINO-PYRROLIDINE-1-CARBOXYLIC ACID BENZYL ESTER;
1-N-Cbz-3-Aminopyrrolidine 
CAS No.:
185057-50-5
分 子 式:

C12H16N2O2

分 子 量:
220.27
精确分子量:
220.12100
PSA:
55.56000
InChI:
InChI=1/C12H16N2O2/c13-11-6-7-14(8-11)12(15)16-9-10-4-2-1-3-5-10/h1-5,11H,6-9,13H2
危险品标志:

 

风险术语:

 

安全术语:
分子结构式:
SDS:
查看

3-氨基-N-Cbz-吡咯烷 物化性质

密度:
1.186g/cm3
沸点:
351.7ºC at 760mmHg
闪点:
166.5ºC
折射率:
1.571
蒸汽压:
4.04E-05mmHg at 25°C
存储条件/存储方法:

保存方法:密闭,阴凉,通风干燥处

稳定性相关:

避氧化物、空气

其它信息:

1.      性状:棕色粘性液体

2.      密度(g/mL20 ºC):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):未确定

5.      沸点(ºC,常压):未确定

6.      沸点(ºC12mmHg):未确定

7.      折射率:未确定

8.      闪点(ºF):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,):未确定

12.   饱和蒸气压(kPa,60ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:未确定

3-氨基-N-Cbz-吡咯烷 安全信息

海关代码:
2933990090

3-氨基-N-Cbz-吡咯烷 毒理性

生态数据:

1、其它有害作用:通常对水是稍微危害的,若无政府许可,勿将材料排入周围环境。

3-氨基-N-Cbz-吡咯烷 MSDS

  Material Safety Data Sheet

Section 1. Identification of the substance
    Product Name:      benzyl 3-aminopyrrolidine-1-carboxylate    
    Synonyms:

Section 2. Hazards identification
    Harmful by inhalation, in contact with skin, and if swallowed.
    H302:        Harmful if swallowed    
    H315:        Causes skin irritation    
    H319:        Causes serious eye irritation    
    H335:        May cause respiratory irritation    
    Avoid breathing dust/fume/gas/mist/vapours/spray
    P261:
    P280:        Wear protective gloves/protective clothing/eye protection/face protection    
    P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
    and easy to do – continue rinsing
    P304+P340:        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing    
    P405:        Store locked up    

Section 3. Composition/information on ingredients.
    Ingredient name:        benzyl 3-aminopyrrolidine-1-carboxylate    
    CAS number:        185057-50-5    

Section 4. First aid measures
    Skin contact:        Immediately wash skin with copious amounts of water for at least 15 minutes while removing    
    contaminated clothing and shoes. If irritation persists, seek medical attention.
    Eye contact:        Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate    
    flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
    attention.
    Inhalation:        Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.    
    Ingestion:        Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.    

Section 5. Fire fighting measures
    In the event of a fire involving this material, alone or in combination with other materials, use dry
    powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
    should be worn.

Section 6. Accidental release measures
    Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
    standards.
    Respiratory precaution:        Wear approved mask/respirator    
    Hand precaution:        Wear suitable gloves/gauntlets    
    Skin protection:        Wear suitable protective clothing    
    Eye protection:        Wear suitable eye protection    
    Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
    for disposal. See section 12.
    Environmental precautions: Do not allow material to enter drains or water courses.

Section 7. Handling and storage
    Handling:        This product should be handled only by, or under the close supervision of, those properly qualified    
    in the handling and use of potentially hazardous chemicals, who should take into account the fire,
    health and chemical hazard data given on this sheet.
    Storage:        Store in closed vessels.    

Section 8. Exposure Controls / Personal protection
    Engineering Controls: Use only in a chemical fume hood.
    Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
    General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section 9. Physical and chemical properties
    Appearance:        Not specified    
    Boiling point:        No data    
    Melting point:        No data    
    Flash point:        No data    
    Density:        No data    
    Molecular formula:        C12H16N2O2    
    Molecular weight:        220.3    

Section 10. Stability and reactivity
    Conditions to avoid: Heat, flames and sparks.
    Materials to avoid: Oxidizing agents.
    Possible hazardous combustion products: Carbon monoxide, nitrogen oxides.

Section 11. Toxicological information
    No data.

Section 12. Ecological information
    No data.

Section 13. Disposal consideration
    Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
    disposal authority, in accordance with national and regional regulations.

Section 14. Transportation information
    Non-harzardous for air and ground transportation.

Section 15. Regulatory information
    No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
    302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
    Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

3-氨基-N-Cbz-吡咯烷 海关数据

中国海关编码:2933990090

概述:
2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
申报要素:
品名, 成分含量, 用途, 乌洛托品请注明外观, 6-己内酰胺请注明外观, 签约日期
摘要/Summary:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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