2-羟基-2-丙烷磺酸单钠盐

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

2-羟基-2-丙烷磺酸单钠盐 基本信息

中文名称:
2-羟基-2-丙烷磺酸单钠盐 
中文别名:
2-羟基-2-丙烷磺酸单钠盐;
丙酮合硫酸;
2-羟基-2-丙烷磺酸一钠盐 
英文名称:
2-Propanesulfonic acid,2-hydroxy-, sodium salt (1:1)
英文别名:
ACETONE SODIUM BISULFITE;
2-Hydroxy-propan-2-sulfonsaeure,Natrium-Salz;
Acetone sodium bisulphite;
2-hydroxy-2-propanesulfonicacimonosodiumsalt;
2-hydroxy-2-propanesulfonic acid,monosodium salt;
Aceton-Natriumdisulfit;
2-Propanesulfonicacid,2-hydroxy-,monosodiumsalt;
Acetone sodium bi;
SODIUM ACETONE BISULFITE;
2-hydroxy-propane-2-sulfonic acid,sodium-salt;
2-HYDROXY-2-PROPANESULFONIC ACID SODIUM SALT;
sodium 2-hydroxypropane-2-sulfonate;
sodium 2-hydroxypropane-2-sulphonate 
CAS No.:
540-92-1
分 子 式:
C3H8O4S.Na
分 子 量:
162.14
精确分子量:
161.99600
PSA:
85.81000
MDL:
MFCD00031395
EINECS:
208-761-2
InChI:
InChI=1/C3H8O4S/c1-3(2,4)8(5,6)7/h4H,1-2H3,(H,5,6,7)/p-1
风险术语:
R36/37/38
安全术语:
S26S37/S39
分子结构式:
SDS:
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2-羟基-2-丙烷磺酸单钠盐 物化性质

外观与性状:
晶体有淡二氧化硫气味
密度:
1.488 g/cm3
熔点:
300ºC
存储条件/存储方法:

密封储存,储存于阴凉、干燥的库房。

稳定性相关:

与酸,氧化物反应。

其它信息:

1.      性状:白色晶体

2.      密度(g/mL,25):未确定

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):>300

5.      沸点(ºC,常压):未确定

6.      沸点(ºC,11mmHg):未确定

7.      折射率(n20/D):未确定

8.      闪点(ºF):未确定

9.      比旋光度(º):未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,25 ºC):未确定

12.   饱和蒸气压(kPa,25ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:溶于水

2-羟基-2-丙烷磺酸单钠盐 安全信息

海关代码:
2905590090
危险类别码:
R36/37/38
安全说明:
37/39-26
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
:
危险标志:
Xi: Irritant;Xi: Irritant;

2-羟基-2-丙烷磺酸单钠盐 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ6550000
CHEMICAL NAME :
2-Propanesulfonic acid, 2-hydroxy-, monosodium salt
CAS REGISTRY NUMBER :
540-92-1
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C3-H7-O4-S.Na
MOLECULAR WEIGHT :
162.15

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1521 No. of Facilities: 44 (estimated) No. of Industries: 2 No. of Occupations: 9 No. of Employees: 15536 (estimated) No. of Female Employees: 12757 (estimated)
生态数据:

对水稍微危害,避免未稀释或大量的产品接触地下水、水道或污水系统。

2-羟基-2-丙烷磺酸单钠盐 MSDS

Name: Acetone sodium bisulfite 97%(titr.) Material Safety Data Sheet
Synonym: 2-Hydroxy-2-propanesulfonic acid sodium sal
CAS: 540-92-1
Section 1 - Chemical Product   MSDS Name:Acetone sodium bisulfite 97%(titr.) Material Safety Data Sheet
Synonym:2-Hydroxy-2-propanesulfonic acid sodium sal

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
540-92-1 Acetone sodium bisulfite 97 208-761-2
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4C/39F.)

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 540-92-1: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: sulfurous odor - weak odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: freely soluble
Specific Gravity/Density:
Molecular Formula: C3H7NaO4S
Molecular Weight: 162.14

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, acids.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 540-92-1: TZ6550000 LD50/LC50:
Not available.
Carcinogenicity:
Acetone sodium bisulfite - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 540-92-1: No information available.
Canada
CAS# 540-92-1 is listed on Canada's NDSL List.
CAS# 540-92-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 540-92-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

2-羟基-2-丙烷磺酸单钠盐 海关数据

中国海关编码:2905590090

概述:
2905590090 其他无环醇的卤化、磺化等衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%
申报要素:
品名, 成分含量, 用途, 包装
摘要/Summary:
2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

2-羟基-2-丙烷磺酸单钠盐 分子结构与计算化学数据

计算化学数据

1、   疏水参数计算参考值(XlogP):

2、   氢键供体数量:2

3、   氢键受体数量:4

4、   可旋转化学键数量:1

5、   互变异构体数量:

6、   拓扑分子极性表面积(TPSA):74.6

7、   重原子数量:9

8、   表面电荷:0

9、   复杂度:160

10、同位素原子数量:0

11、确定原子立构中心数量:0

12、不确定原子立构中心数量:0

13、确定化学键立构中心数量:0

14、不确定化学键立构中心数量:0

15、共价键单元数量:2

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