(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS

(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 基本信息

中文名称:
(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 
中文别名:
 
英文名称:
4-Piperidinepropanoicacid, 1-[(1,1-dimethylethoxy)carbonyl]-a-[[(9H-fluoren-9-ylmethoxy)carbonyl]amino]-
英文别名:
N-α-FMOC-β-(1-BOC-PIPERIDIN-4-YL)-D,L-ALANINE;
N-ALPHA-FMOC-BETA-(1-BOC-PIPERIDIN-4-YL)-D,L-ALANINE;
FMOC-D, L-ALA-4PIP(BOC);
2-N-FMOC-AMINO-3-(4-N-BOC-PIPERIDINYL) PROPIONIC ACID;
2-N-FMOC-AMINO-3-(N-BOC-4-PIPERIDINYL)PROPIONIC ACID;
2-N-(9-FLUORENYLMETHOXYCARBONYL)-AMINO-3-(4-N-(TERT-BUTOXYCARBONYL)-PIPERIDINYL)PROPIONIC ACID;
4-[2-CARBOXY-2-(9H-FLUOREN-9-YLMETHOXYCARBONYLAMINO)-ETHYL]-PIPERIDINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER;
2-N-FMOC-AMINO-3-(4-N-BOC-PIPERIDINYL) PROPIONIC ACID 95%;
2-N-FMOC-Amino-3-(4-N-BOC-piperidinyl)propionic acid,95% 
CAS No.:
313052-02-7
分 子 式:
C28H34N2O6
分 子 量:
494.58
精确分子量:
494.24200
PSA:
105.17000
危险品标志:
风险术语:
36/37/38
安全术语:
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
分子结构式:
SDS:
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(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 物化性质

沸点:
676.6ºC at 760mmHg
闪点:
363ºC

(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 安全信息

危险类别码:
R36/37/38
安全说明:
S26-S37/39
危险标志:
Xi: Irritant;

(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 MSDS

Name: 2-N-FMOC-Amino-3-(4-N-BOC-Piperidinyl)Propionic Acid 95% Material Safety Data Sheet
Synonym:
CAS: 313052-02-7
Section 1 - Chemical Product   MSDS Name:2-N-FMOC-Amino-3-(4-N-BOC-Piperidinyl)Propionic Acid 95% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
313052-02-7 2-N-FMOC-Amino-3-(4-N-BOC-Piperidinyl) 95% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 313052-02-7: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C28H34N2O6
Molecular Weight: 494.58

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 313052-02-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-N-FMOC-Amino-3-(4-N-BOC-Piperidinyl)Propionic Acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 313052-02-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 313052-02-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 313052-02-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

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产品介绍:
产品名称:(2S)-2-(9H-芴-9-基甲氧羰基氨基)-3-[1-[(2-甲基丙烷-2-基)氧羰基]哌啶-4-基]丙酸 Cas号:313052-02-7 纯度:97% 包装信息:0.25gea,0.5gea,1gea 价格:1,359.0元 - 3,009.0元
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