四正丙基锡

  • 基本信息
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 海关数据
  • 结构与计算化学
  • 上游产品
  • 下游产品

四正丙基锡 基本信息

中文名称:
四正丙基锡 
中文别名:
四丙基锡;
四正丙基锡 
英文名称:
Stannane, tetrapropyl-
英文别名:
tetrapropylstannane;
Tetrapropyltin;
STANNANE,TETRAPROPYL;
Tetrapropyl-stannan;
EINECS 218-536-0;
Tin,tetrapropyl;
Tetrapropylzinn;
tetra-n-propyltin;
Tetra-n-propyltin 
CAS No.:
2176-98-9
分 子 式:
C12H28Sn
分 子 量:
291.05
精确分子量:
292.12100
PSA:
0.00000
EINECS:
218-536-0
InChI:
The Key: OIQCWAIEHVRCCG-UHFFFAOYSA-N
风险术语:
R23/24/25
安全术语:
S26S27S36/S37/S39
分子结构式:
SDS:
查看

四正丙基锡 物化性质

密度:
1.1
熔点:
-109ºC
沸点:
222ºC
闪点:
115.3ºC
折射率:
1.4745
蒸汽压:
0.017mmHg at 25°C
存储条件/存储方法:

储存的地方必须远离氧化剂,保持容器密封,放入紧密的出藏器内,储存在阴凉,干燥的地方

稳定性相关:

避免氧化物接触,危险分解产品为一氧化碳和二氧化碳  ,有毒的金属氧化物

其它信息:

1.      性状:无色液体

2.      密度(g/ml,20ºC):1.1065

3.      相对蒸汽密度(g/mL,空气=1):未确定

4.      熔点(ºC):-109

5.      沸点(ºC,常压):222

6.      沸点(ºC,50mmHg):未确定

7.      折射率nD20):1.4745

8.      闪点(ºC222

9.      比旋光度(): 未确定

10.   自燃点或引燃温度(ºC):未确定

11.   蒸气压(kPa,100ºC):未确定

12.   饱和蒸气压(kPa,20ºC):未确定

13.   燃烧热(KJ/mol):未确定

14.   临界温度(ºC):未确定

15.   临界压力(KPa):未确定

16.   油水(辛醇/水)分配系数的对数值:未确定

17.   爆炸上限(%,V/V):未确定

18.   爆炸下限(%,V/V):未确定

19.   溶解性:不能拌和的或难以拌和

四正丙基锡 安全信息

海关代码:
2931900090
危险类别码:
R23/24/25
安全说明:
26-27-36/37/39
安全标志:
S26:万一接触眼睛,立即使用大量清水冲洗并送医诊治。
S27:立刻除去所有污染衣物。
:

四正丙基锡 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WH8636500
CHEMICAL NAME :
Stannane, tetrapropyl-
CAS REGISTRY NUMBER :
2176-98-9
BEILSTEIN REFERENCE NO. :
3600574
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C12-H28-Sn
MOLECULAR WEIGHT :
291.09

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Parenteral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
73 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage)
REFERENCE :
COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 239,1091,1954
毒理学数据:

1、急性毒性:小鼠肠外LDLo73mg/kg

生态数据:

通常对水是不危害的,若无政府许可,勿将材料排入周围环境。

四正丙基锡 MSDS


Section 1: Product Identification
   Chemical Name:       Tetra-n-propyltin, min. 97%    
   CAS Registry Number:       2176-98-9    
   Formula:       Sn(C3H7)4    
   EINECS Number:       218-536-0    
   Chemical Family:       organotin compound    
   Synonym:       Tin, tetrapropyl-, Tetrapropylstannane    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       2176-98-9       100%       0.1mg/m3       0.1mg/m3    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes severe irritation of the eyes.    
   Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
   Skin Contact:
   severe irritation.
   Inhalation:       Irritating to skin, eyes and respiratory tract.    
   Delayed and permanent psycho-neurological disturbances; impairment of vision, unsteadiness, nausea and
   Ingestion:
   vomiting.
   Irritating to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause delayed
   Acute Health Affects:
   poisoning (4 days) with cerebral edema causing damage to the central nervous system.
   Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory
   Chronic Health Affects:
   system, central nervous system, liver, kidneys, urinary tract, and blood.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
   Special Fire Fighting Procedures:
   and full protective clothing.
   Hazardous Combustion and       carbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, ground limestone, sodium carbonate or other suitable
   Spill and Leak Procedures:
   noncombustible adsorbent and swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Work with this product in a well-ventilated area, preferably a fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       colorless liq.    
   Molecular Weight:       291.05    
   Melting Point:       no data    
   Boiling Point:       222°C    
   Vapor Pressure:       no data    
   Specific Gravity:       1.1065(20°)    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       strong oxidizing agents and halogens    
   Decomposition Products:       carbon monoxide, carbon dioxide, tin oxide, and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       Parenteral (mouse); LDLo: 73 mg/kg.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to federal, state, and local regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

四正丙基锡 海关数据

中国海关编码:2931900090

概述:
2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
摘要/Summary:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

四正丙基锡 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:0

4.可旋转化学键数量:8

5.互变异构体数量:无

6.拓扑分子极性表面积0

7.重原子数量:13

8.表面电荷:0

9.复杂度:80.2

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:1

推荐供应商更多供应商>>

淄博航宇生物科技发展有限公司

产品介绍:
产品名称:四正丙基锡 Cas号:2176-98-9 纯度:99% 包装信息:100kg 价格:洽谈
联系方式:
联系人:张经理 电话:15666366704 手机:15666366704

上海吉至生化科技有限公司

产品介绍:
产品名称:四丙基锡 Cas号:2176-98-9 纯度:分析标准试剂 包装信息:100mgea 价格:938.0元
联系方式:
联系人:Shirley张 电话:021-57520831 手机:18116052675

北京百灵威科技有限公司

产品介绍:
产品名称:四正丙基氯化锡内标套标 Cas号:2176-98-9 纯度:2000 μg/mL in CH2Cl2 包装信息:1ml 价格:洽谈
联系方式:
联系人:翟先生 电话:18210857532 手机:18210857532

上海倍卓生物科技有限公司

产品介绍:
产品名称:四丙基锡 Cas号:2176-98-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:张烁 电话:021-60548335 手机:18721011993

郑州希派克化工有限公司

产品介绍:
产品名称:四丙基锡 Cas号:2176-98-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:王丹 电话:0371-55695890 手机:13526885213

研峰科技(北京)有限公司

产品介绍:
产品名称:四正丙基锡, Cas号:2176-98-9 纯度: 包装信息:洽谈 价格:洽谈
联系方式:
联系人:赵小姐 电话:4001062016 手机:
QQ: 2241752642
微信二维码
电话: 19906633110