rac-二甲基硅基双(1-茚基)二氯化锆

  • 基本信息
  • 物化性质
  • 安全信息
  • MSDS
  • 结构与计算化学
  • 下游产品

rac-二甲基硅基双(1-茚基)二氯化锆 基本信息

中文名称:
rac-二甲基硅基双(1-茚基)二氯化锆 
中文别名:
rac-二甲基硅基双(1-茚基)二氯化锆;
RAC-二甲基硅基双(1-茚基)二氯化锆 
英文名称:
Zirconium,dichloro[rel-(1R,1'R)-(dimethylsilylene)bis[(1,2,3,3a,7a-h)-1H-inden-1-ylidene]]-
英文别名:
dichlorozirconium,di(inden-1-yl)-dimethylsilane;
Eurocen(R) 5037;
RAC-DIMETHYLSILYLBIS(INDENYL)ZIRCONIUMDICHLORIDE;
rac-dimethylbis(indenyl)zirconocene dichloride;
[(CH3)2Si(indenyl)2]ZrCl2;
dimethylsilylbis(1-indenyl)zirconium dichloride;
dimethylsilanediylbis(indenyl)zirconium dichloride;
rac-dimethylsilylenebis(indenyl)zirconium dichloride;
RAC-DIMETHYLSILYLBIS(1-INDENYL)ZIRCONIUM DICHLORIDE 
CAS No.:
121009-93-6
分 子 式:
C20H18Cl2SiZr
分 子 量:
448.57
精确分子量:
445.96000
PSA:
0.00000
InChI:
The Key: ORVHEJRHZZNVBE-UHFFFAOYSA-L
风险术语:
R36/37/38
安全术语:
S26S36/S37/S39
分子结构式:
SDS:
查看

rac-二甲基硅基双(1-茚基)二氯化锆 物化性质

其它信息:

1.        性状:未确定

2.         密度(g/mL,20):未确定

3.         相对蒸汽密度(g/mL,空气=1):未确定

4.         熔点(ºC):未确定

5.         沸点(ºC,常压):未确定

6.         沸点(ºC,KPa):未确定

7.         折射率:未确定

8.         闪点(ºC):未确定

9.         比旋光度(º):未确定

10.      自燃点或引燃温度(ºC):未确定

11.      蒸气压(Pa,20ºC):未确定

12.      饱和蒸气压(KPa,20ºC):未确定

13.      燃烧热(KJ/mol):未确定

14.      临界温度(ºC):未确定

15.      临界压力(KPa):未确定

16.      油水(辛醇/水)分配系数的对数值:未确定

17.      爆炸上限(%,V/V):未确定

18.      爆炸下限(%,V/V):未确定

19.     溶解性:未确定

rac-二甲基硅基双(1-茚基)二氯化锆 安全信息

安全说明:
S26-S36-S37-S39

rac-二甲基硅基双(1-茚基)二氯化锆 MSDS


Section 1: Product Identification
   Chemical Name:       rac-Dimethylsilylbis(1-indenyl)zirconium dichloride, min. 97%    
   CAS Registry Number:       121009-93-6    
   Formula:       (CH3)2Si(C9H6)2ZrCl2    
   EINECS Number:       none    
   Chemical Family:       organometallic complexes    
   Synonym:       None    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       121009-93-6       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes and skin. May be harmful if swallowed or inhaled.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes mild irritation of the eyes.    
   Skin Contact:       Causes slight irritation of the skin.    
   Inhalation:       Inhalation of dust may lead to irritation of the respiratory tract.    
   Ingestion:       No information is available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to eyes and skin. May be harmful if swallowed or inhaled.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       none    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep away from heat and
   Handling and Storage:
   direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Proram to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       orange powder    
   Molecular Weight:       448.53    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       moisture sensitive    
   Hazardous Polymerization:       none    
   Conditions to Avoid:       prolonged exposure to moisture    
   Incompatibility:       strong oxidizing agents    
   Decomposition Products:       carbon dioxide, carbon monoxide, hydrogen chloride, organic fumes and zirconium oxide    

SECTION 11: Toxicological Information
   RTECS Data:       No information available from the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       not listed on the TSCA inventory    
   SARA (Title 313):       not reportable under SARA Title (313)    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

rac-二甲基硅基双(1-茚基)二氯化锆 分子结构与计算化学数据

分子结构数据

1、摩尔折射率:无可用的

2、摩尔体积(cm3/mol):无可用的

3、等张比容(90.2K):无可用的

4、表面张力(dyne/cm):无可用的

5、介电常数:无可用的

6、极化率(10-24cm3):无可用的

7、单一同位素质量:445.96084 Da

8、标称质量:446 Da

9、平均质量:448.5724 Da

rac-二甲基硅基双(1-茚基)二氯化锆 下游产品

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