氮化铈

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • MSDS

氮化铈 基本信息

中文名称:
氮化铈 
中文别名:
氮化铈 
英文名称:
Cerium nitride (CeN)
英文别名:
cerium(III) nitride;
CERIUM NITRIDE;
NITRIDOCERIUM;
CERIUM NITRIDE (CEN) 
CAS No.:
25764-08-3
分 子 式:
CeN
分 子 量:
154.13
精确分子量:
153.90900
PSA:
23.79000
EINECS:
247-243-0
InChI:
The Key: BCZWPKDRLPGFFZ-UHFFFAOYSA-N
安全术语:
Reaction with water or dilute acids may cause ignition and the release of toxic ammonia gas and explosive hydrogen gas. When heated to decomposition it emits toxic fumes of NOx. See also CERIUM COMPOUNDS and NITRIDES.
分子结构式:
SDS:
查看

氮化铈 制备方法及用途

制备方法

1.金属铈薄片在熔点温度下与N2发生放热反应,形成立方结构的氮化物。 2.金属铈与NH3在500℃下反应1h得到氮化物。

合成制备方法

1.金属铈薄片在熔点温度下与N2发生放热反应,形成立方结构的氮化物。

2.金属铈与NH3在500℃下反应1h得到氮化物。

用途简介

氮化铈 物化性质

其它信息:

1.性状:古铜色,NaCl型结构,a=0.501nm。

2.密度(g/cm3):7.89 。

3.熔点(℃):2557。

氮化铈 MSDS


Section 1: Product Identification
   Chemical Name:       Cerium nitride (99.9%-Ce)    
   CAS Registry Number:       25764-08-3    
   Formula:       CeN    
   EINECS Number:       247-243-0    
   Chemical Family:       metal nitride    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       25764-08-3       100%       no data       no data    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. May evolve ammonia, a choking gas, if exposed to water. May be
   Emergency Overview:
   harmful if swallowed.
   Primary Routes of Exposure:       Inhalation, skin, eyes    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information available on the physiological effects of ingestion. May be harmful if swallowed.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container away from moisture. Keep in a cool, dry, well-ventilated area.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       -60 mesh pwdr.    
   Molecular Weight:       154.12    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air stable. May evolve ammonia gas if wet.    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       exposure to moisture    
   Incompatibility:       water, mineral acids    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory    
   SARA (Title 313):       Not reportable under SARA 313    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A

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