硝酸铋

  • 基本信息
  • 制备方法及用途
  • 物化性质
  • 安全信息
  • 毒理性
  • MSDS
  • 结构与计算化学

硝酸铋 基本信息

中文名称:
硝酸铋 
中文别名:
硝酸铋;
五水合硝酸铋(III) 
英文名称:
Nitric acid,bismuth(3+) salt (3:1)
英文别名:
Bismuth nitrate;
Trinitric acid bismuth salt;
Nitric acid bismuth salt;
Nitricacid,bismuth(3+)salt;
Bismuthternitrate;
Trinitric acid bismuth(III) salt;
BISMUTH (III) NITRATE;
Bismuth(III) nitrate hydrate,Puratronic(R),99.9 (metals basis) 
CAS No.:
10361-44-1
分 子 式:

Bi.3HNO3

分 子 量:
394.99
精确分子量:
394.94400
PSA:
206.64000
EINECS:
233-791-8
危险品标志:

 

风险术语:

 

安全术语:
分子结构式:
SDS:
查看

硝酸铋 制备方法及用途

制备方法

原料药。

用途简介

用途

用于药物和铋盐制造,用作各种触媒原料。[14]

硝酸铋 物化性质

外观与性状:
透明,无色晶体
密度:
2.83 g/cm3
熔点:
30ºC
沸点:
83ºC
存储条件/存储方法:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物分开存放
稳定性相关:

1.稳定性[8]  稳定

2.禁配物[9]  还原剂、易燃或可燃物、活性金属粉末、硫、磷

3.避免接触的条件[10]  潮湿空气

4.聚合危害[11]  不聚合

5.分解产物[12]  氮氧化物

其它信息:

1.性状:无色透明有光泽结晶,有吸湿性。[1]

2.熔点(℃):75~80(分解)[2]

3.沸点(℃):分解[3]

4.相对密度(水=1):2.83[4]

5.溶解性:溶于稀硝酸、乙醇、丙酮。[5]

硝酸铋 安全信息

包装等级:
II
风险类别:
5.1
海关代码:
2834299090

硝酸铋 毒理性

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EB2984400
CHEMICAL NAME :
Bismuth nitrate
CAS REGISTRY NUMBER :
10361-44-1
LAST UPDATED :
199701
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
N3-O9.Bi
MOLECULAR WEIGHT :
395.01
WISWESSER LINE NOTATION :
.BI..N-O3*3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 34,173,1976
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
21 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
APFRAD Annales Pharmaceutiques Francaises. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1943- Volume(issue)/page/year: 34,173,1976 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intratesticular
DOSE :
31601 ug/kg
SEX/DURATION :
male 1 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 7,21,1964
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
DOSE :
31601 ug/kg
SEX/DURATION :
male 30 day(s) pre-mating
TOXIC EFFECTS :
Reproductive - Paternal Effects - spermatogenesis (incl. genetic material, sperm morphology, motility, and count) Reproductive - Paternal Effects - testes, epididymis, sperm duct
REFERENCE :
JRPFA4 Journal of Reproduction and Fertility. (Biochemical Soc. Book Depot, POB 32, Commerce Way, Colchester, Essex CO2 8HP, UK) V.1- 1960- Volume(issue)/page/year: 7,21,1964 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81728 No. of Facilities: 78 (estimated) No. of Industries: 3 No. of Occupations: 4 No. of Employees: 430 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81728 No. of Facilities: 156 (estimated) No. of Industries: 4 No. of Occupations: 6 No. of Employees: 921 (estimated) No. of Female Employees: 89 (estimated)
毒理学数据:

1.急性毒性[6]

LD50:4042mg/kg(大鼠经口);3710mg/kg(小鼠经口)

2.刺激性  暂无资料

生态数据:

1.生态毒性  暂无资料

2.生物降解性  暂无资料

3.非生物降解性  暂无资料

4.其他有害作用[7]  该物质对环境有危害,应特别注意对水体的污染。

硝酸铋 MSDS

Name: Bismuth Nitrate Material Safety Data Sheet
Synonym: Nitric acid, bismuth (+3) salt
CAS: 10361-44-1
Section 1 - Chemical Product   MSDS Name:Bismuth Nitrate Material Safety Data Sheet
Synonym:Nitric acid, bismuth (+3) salt

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
10361-44-1 Bismuth nitrate 100 % 233-791-8
Hazard Symbols: XI O
Risk Phrases: 36/38 8

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Irritating to eyes and skin. Contact with combustible material may cause fire.Corrosive.Hygroscopic.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
May cause reproductive and fetal effects.

Section 4 - FIRST AID MEASURES
  Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Appearance: white
Odor: Pungent odor.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 30 deg C (decomposes)
Decomposition Temperature: Not available.
Solubility: Decomposed by water.
Specific Gravity/Density: 2.83
Molecular Formula: BiN3O9
Molecular Weight: 394.9987

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, combustible materials, heating to decomposition.
Incompatibilities with Other Materials:
Heat, cumbustible materials, and water.
Hazardous Decomposition Products:
Oxides of nitrogen, irritating and toxic fumes and gases, bismuth oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 10361-44-1: EB2984400 LD50/LC50:
Not available.
Carcinogenicity:
Bismuth nitrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  For further information, contact Fisher Scientific.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
CDG/CPL
Shipping Name: NITRATES, INORGANIC, NOS
Hazard Class: 5.1
UN Number: 1477
Packing Group: II
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
No information available.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately with
plenty of ... (to be specified by the manufacturer).
WGK (Water Danger/Protection)
CAS# 10361-44-1:
Canada
CAS# 10361-44-1 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 10361-44-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 10361-44-1 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

硝酸铋 分子结构与计算化学数据

计算化学数据

1.疏水参数计算参考值(XlogP):无

2.氢键供体数量:0

3.氢键受体数量:9

4.可旋转化学键数量:0

5.互变异构体数量:无

6.拓扑分子极性表面积189

7.重原子数量:13

8.表面电荷:0

9.复杂度:18.8

10.同位素原子数量:0

11.确定原子立构中心数量:0

12.不确定原子立构中心数量:0

13.确定化学键立构中心数量:0

14.不确定化学键立构中心数量:0

15.共价键单元数量:4

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产品介绍:
产品名称:硝酸铋 Cas号:10361-44-1 纯度:0-99% 包装信息:1kg,25kg,200kg,400kg,500kg 价格:洽谈
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